scholarly journals Raman study of electron-phonon coupling in thin films of the spinel oxide superconductor LiTi2O4

2017 ◽  
Vol 96 (9) ◽  
Author(s):  
D. Chen ◽  
Y.-L. Jia ◽  
T.-T. Zhang ◽  
Z. Fang ◽  
K. Jin ◽  
...  
2017 ◽  
Vol 95 (5) ◽  
Author(s):  
Ge He ◽  
Yanli Jia ◽  
Xingyuan Hou ◽  
Zhongxu Wei ◽  
Haidong Xie ◽  
...  

2017 ◽  
Vol 3 (2) ◽  
Author(s):  
Milan Allan ◽  
Mark H Fischer ◽  
Oliver Ostojic ◽  
Arjo Andringa

The quest to create superconductors with higher transition temperatures is as old as superconductivity itself. One strategy, popular after the realization that (conventional) superconductivity is mediated by phonons, is to chemically combine different elements within the crystalline unit cell to maximize the electron-phonon coupling. This led to the discovery of NbTi and Nb_33Sn, to name just the most technologically relevant examples. Here, we propose a radically different approach to transform a ‘pristine’ material into a better (meta-) superconductor by making use of modern fabrication techniques: designing and engineering the electronic properties of thin films via periodic patterning on the nanoscale. We present a model calculation to explore the key effects of different supercells that could be fabricated using nanofabrication or deliberate lattice mismatch, and demonstrate that specific pattern will enhance the coupling and the transition temperature. We also discuss how numerical methods could predict the correct design parameters to improve superconductivity in materials including Al, NbTi, and MgB_22.


Author(s):  
Jung Min Lee ◽  
Soon-Gil Jung ◽  
Younseok Han ◽  
Tae-Ho Park ◽  
Jae Kyung Jang ◽  
...  

Abstract We investigate the effect of disorder on the superconducting mechanism of MgB2 thin films using low-energy ion irradiation. The c-axis lattice constant and T c of MgB2 thin films change systematically as the magnitude of disorder, which corresponds to the value of average displacements per atom (dpaavg ), increases. Here, dpaavg is controlled by the amount of irradiated ions. The dpaavg dependence of the electron-phonon coupling constants (λ) is estimated using the McMillan equation. For dpaavg ≤ 0.049, λ is linearly proportional to dpaavg . On the other hand, for dpaavg > 0.049, the T c of the disordered MgB2 deviates from the linear fitting curve, and insulating behavior is observed in the normal state resistivity. These results indicate that the superconducting mechanism of MgB2 can be changed by the electronic system caused by disorder strength affecting the electron-phonon coupling constant λ.


2008 ◽  
Vol 81 (6) ◽  
pp. 67006 ◽  
Author(s):  
M. Monni ◽  
I. Pallecchi ◽  
C. Ferdeghini ◽  
V. Ferrando ◽  
A. Floris ◽  
...  

1995 ◽  
Vol 10 (6) ◽  
pp. 1362-1370 ◽  
Author(s):  
D.M. Bhusari ◽  
Alka Kumbhar ◽  
S.T. Kshirsagar

We have reported here on low-temperature Raman scattering measurements on thin films of hydrogenated amorphous silicon (α-Si:H) alloys having different H contents. The Stoke's intensity, 77KITO, scattered at 77 K by the TO-phonon is found to be several times greater than its corresponding magnitude (300KITO) at 300 K. The ratio (77KITO/300KITO) is observed to vary exponentially with an increase in H concentration of the film. After eliminating various possible contributions to the scattering cross section, and therefore to the scattered intensity, this anomalous light scattering at 77 K is attributed to the possibility of polarizability modulation, which is believed to be caused due to a possible reduction in light-induced migration of H in α-Si:H and to the charge-carrier-induced enhancement of electron phonon coupling at 77 K.


2017 ◽  
Vol 121 (9) ◽  
pp. 095308 ◽  
Author(s):  
Udai B. Singh ◽  
Compesh Pannu ◽  
Dinesh C. Agarwal ◽  
Sunil Ojha ◽  
Saif A. Khan ◽  
...  

1992 ◽  
Vol 270 ◽  
Author(s):  
J. S. Lannin ◽  
M. G. Mitch ◽  
W. Bacsa ◽  
S. J. Chase

ABSTRACTRaman scattering measurements in alkali—fullerene alloys in ultrathin and thin films provide evidence for variations in electron—phonon coupling. For x — 3similar behavior of Rb3 C60 films of different thickness support substantial electron—phonon induced damping of specific Hg(i) modes derived from intramolecular modes of C60. In 400A thick films a reduction of induced scattering from Raman inactive C60 modes substantiates the importance ofHg(2), but not Hg(3) modes for phonon—mediated superconductivity. In contrast to RbxC60 and KxC60 ultrathin film solid solutions, similar Raman spectra for NaxC60 indicate substantially reduced coupling consistent with the absence of superconductivity in this system.


Nanomaterials ◽  
2018 ◽  
Vol 8 (8) ◽  
pp. 632 ◽  
Author(s):  
Ashish Gandhi ◽  
Wei-Shan Yeoh ◽  
Ming-An Wu ◽  
Ching-Hao Liao ◽  
Dai-Yao Chiu ◽  
...  

High-quality crystalline nanostructured ZnO thin films were grown on sapphire substrates by reactive sputtering. As-grown and post-annealed films (in air) with various grain sizes (2 to 29 nm) were investigated by scanning electron microscopy, X-ray diffraction, and Raman scattering. The electron–phonon coupling (EPC) strength, deduced from the ratio of the second- to the first-order Raman scattering intensity, diminished by reducing the ZnO grain size, which mainly relates to the Fröhlich interactions. Our finding suggests that in the spatially quantum-confined system the low polar nature leads to weak EPC. The outcome of this study is important for the development of nanoscale high-performance optoelectronic devices.


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