Phase stability and magnetic behavior of hexagonal phase ofN2−O2system with kagome lattice under high pressure and low temperature

2016 ◽  
Vol 94 (6) ◽  
Author(s):  
Y. Akahama ◽  
D. Ishihara ◽  
H. Yamashita ◽  
H. Fujihisa ◽  
N. Hirao ◽  
...  
2003 ◽  
Vol 288 (1) ◽  
pp. 147-158 ◽  
Author(s):  
J. Rouquette ◽  
V. Bornand ◽  
J. Haines ◽  
M. Pintard ◽  
Ph. Papet

2015 ◽  
Vol 91 (21) ◽  
Author(s):  
S. Nakamura ◽  
S. Toyoshima ◽  
N. Kabeya ◽  
K. Katoh ◽  
T. Nojima ◽  
...  

Author(s):  
Tamara Đordević ◽  
Ljiljana Karanović

The new layered title compound, barium di-μ-hydroxido-di-μ-vanadato-tricobaltate(II), was prepared under low-temperature hydrothermal conditions. Its crystal structure comprises Co2+and O2−ions in the Kagomé geometry. The octahedral Co3O6(OH)2Kagomé layers, made up of edge-shared CoO4(OH)2octahedra with Co on a site of 2/msymmetry, alternate along thecaxis with barium vanadate heteropolyhedral layers, in which Ba is on a site of \overline{3}msymmetry and V is on a site of 3msymmetry. All three O atoms and the H atom also occupy special positions: two O atoms and the H atom are on sites with 3msymmetry and one O atom is on a site withmsymmetry. Ba[Co3(VO4)2(OH)2] represents the first compound from the four-component BaO–CoO–V2O5–H2O system and its structure is topologically related to the minerals vesignieite, Ba[Cu3(VO4)2(OH)2], and bayldonite, Pb[Cu3(AsO4)2(OH)2].


Author(s):  
Markus Guido Herrmann ◽  
Ralf Peter Stoffel ◽  
Michael Küpers ◽  
Mohammed Ait Haddouch ◽  
Andreas Eich ◽  
...  

The high-pressure and low-temperature behaviour of the GeSe x Te1−x system (x = 0, 0.2, 0.5, 0.75, 1) was studied using a combination of powder diffraction measurements and first-principles calculations. Compounds in the stability field of the GeTe structure type (x = 0, 0.2, 0.5) follow the high-pressure transition pathway: GeTe-I (R3m) → GeTe-II (f.c.c.) → GeTe-III (Pnma). The newly determined GeTe-III structure is isostructural to β-GeSe, a high-pressure and high-temperature polymorph of GeSe. Pressure-dependent formation enthalpies and stability regimes of the GeSe x Te1−x polymorphs were studied by DFT calculations. Hexagonal Ge4Se3Te is stable up to at least 25 GPa. Significant differences in the high-pressure and low-temperature behaviour of the GeTe-type structures and the hexagonal phase are highlighted. The role of Ge...Ge interactions is elucidated using the crystal orbital Hamilton population method. Finally, a sketch of the high-pressure phase diagram of the system is provided.


2014 ◽  
Vol 500 (18) ◽  
pp. 182001 ◽  
Author(s):  
Y Akahama ◽  
T Maekawa ◽  
T Sugimoto ◽  
H Fujihisa ◽  
N Hirao ◽  
...  

2021 ◽  
pp. 2000126
Author(s):  
Cheng Peng ◽  
Yi‐Fan Jiang ◽  
Dong‐Ning Sheng ◽  
Hong‐Chen Jiang

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