Nature of empty states in superconducting CaC6and related Li-Ca ternary graphite intercalation compounds using polarized x-ray absorption near-edge structure at the CaKedge

2013 ◽  
Vol 87 (7) ◽  
Author(s):  
D. Cabaret ◽  
N. Emery ◽  
Ch. Bellin ◽  
C. Hérold ◽  
Ph. Lagrange ◽  
...  
Keyword(s):  
Intercalation Compounds ◽  
Graphite Intercalation Compounds ◽  
Edge Structure ◽  
X Ray ◽  
Graphite Intercalation ◽  
X Ray Absorption

Populations of Fluorine and Arsenic in AsF5-Graphite Intercalation Compounds

1982 ◽  
Vol 20 ◽  
Author(s):  
H. Sfihi ◽  
L. Facchini ◽  
J. Bouat ◽  
D. Bonnin ◽  
A.P. Legrand ◽  
...  
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Magnetic Resonance ◽  
Oxidation Reaction ◽  
Intercalation Compounds ◽  
Oxidation States ◽  
Graphite Intercalation Compounds ◽  
X Ray ◽  
Graphite Intercalation ◽  
X Ray Absorption ◽  
Nuclear Magnetic

ABSTRACT19F nuclear magnetic resonance and As X-ray absorption results on AsF5-graphite intercalation compounds are discussed in terms of species of the commonly used oxidation reaction of the graphitic planes. Three fluorine populations and two oxidation states of the arsenic are clearly present, but they cannot be easily related to the oxidation reaction of the graphite planes.

Symmetry of the unoccupied states in Cs graphite intercalation compounds by X-ray absorption

1991 ◽  
Vol 94 (1) ◽  
pp. 79-88 ◽  
Author(s):  
V. Codazzi ◽  
G. Loupias ◽  
S. Rabii ◽  
L. Elansari ◽  
D. Guérard ◽  
...  
Keyword(s):  
Intercalation Compounds ◽  
Graphite Intercalation Compounds ◽  
X Ray ◽  
Graphite Intercalation ◽  
X Ray Absorption

Stoichiometric Determination of Graphite Intercalation Compounds Using Rutherford Backscatiering Spectrometry

1983 ◽  
Vol 27 ◽  
Author(s):  
L. Salamanca-Riba ◽  
B.S. Elman ◽  
M.S. Dresselhaus ◽  
T. Venkatesan
Keyword(s):  
Experimental Error ◽  
Rutherford Backscattering Spectrometry ◽  
Rutherford Backscattering ◽  
Intercalation Compounds ◽  
Graphite Intercalation Compounds ◽  
X Ray ◽  
Donor And Acceptor ◽  
Graphite Intercalation ◽  
Non Destructive

ABSTRACTRutherford backscattering spectrometry (RBS) is used to characterize the stoichiometry of graphite intercalation compounds (GIC). Specific application is made to several stages of different donor and acceptor compounds and to commensurate and incommensurate intercalants. A deviation from the theoretical stoichiometry is measured for most of the compounds using this non-destructive method. Within experimental error, the RBS results agree with those obtained from analysis of the (00ℓ) x-ray diffractograms and weight uptake measurements on the same samples.

Fullerenes Doped with Thallium Alloys

1992 ◽  
Vol 270 ◽  
Author(s):  
M. Kraus ◽  
M. Baenitz ◽  
S. GÄrtner ◽  
H.M. Vieth ◽  
H. Werner ◽  
...  
Keyword(s):  
Ac Susceptibility ◽  
Intercalation Compounds ◽  
Graphite Intercalation Compounds ◽  
Dc Magnetization ◽  
X Ray ◽  
Ternary Compounds ◽  
Graphite Intercalation ◽  
Thallium Alloys

ABSTRACTPrompted by earlier work showing that graphite intercalation compounds form superconducting ternary compounds in which thallium plays an important role C60 has been doped with Tl-alloys. Results of dc-magnetization, ac-susceptibility, X-ray analysis and NMR investigations will be presented.

Graphite Intercalation Compounds with Trimethyltin Chloride

1984 ◽  
Vol 39 (6) ◽  
pp. 788-790 ◽  
Author(s):  
Robert Schlögl ◽  
Hanns-Peter Boehm
Keyword(s):  
Chemical Analysis ◽  
Uv Irradiation ◽  
Intercalation Compounds ◽  
X Ray Diffraction ◽  
Graphite Intercalation Compounds ◽  
X Ray ◽  
Graphite Intercalation ◽  
Anionic Species ◽  
Trimethyltin Chloride ◽  
Stage 1

AbstractIntercalation compounds of graphite with Sn(CH3)3Cl have been prepared by UV irradiation, in the presence of graphite, of solutions of Sn(CH3)3Cl, Sn(CH3)4, or of Sn(CH3)4 + SnCl4 in CCl4. Mixtures of stage 1, stage 2, and stage 3 compounds have been obtained. They were characterized by X-ray diffraction, 119Sn Mossbauer spectroscopy, and by chemical analysis. Apparently an oligomeric, anionic species is intercalated together with some solvent.

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