scholarly journals Conductivity of multiwall carbon nanotubes: Role of multiple shells and defects

2010 ◽  
Vol 82 (11) ◽  
Author(s):  
A. Stetter ◽  
J. Vancea ◽  
C. H. Back
2013 ◽  
Vol 2013 ◽  
pp. 1-6 ◽  
Author(s):  
Martin Michálek ◽  
Michael Bredol

Functionalized and raw multiwall carbon nanotubes (MWCNTs) were investigated colloid-chemically in order to study the role of polar versus nonpolar interaction with a polyurethane (PU) matrix. Both kinds of MWCNTs were dispersed by ultrasonication in the presence of a surfactant (sodium dodecyl sulphate) in aqueous solution. Functional groups on the nanotube surface were characterized by infrared spectroscopy and by theζ-potential in aqueous suspension. Such suspensions were added to waterborne PU dispersions, drop-cast on glass substrates and cured. The percolation threshold for electrical conductivity with polar (functionalized) MWCNTs was reached at 0.24 wt.%, whereas at concentrations as high as 2 wt.%, PU films with nonpolar MWCNTs stayed below the percolation threshold. With an addition of 0.4 wt.% polar MWCNTs, the electrical conductivity increased to >10−6 S/cm in the cured coating layer. These results are interpreted with respect to the chemical nature of the PU matrix.


2014 ◽  
Vol 132 (4) ◽  
pp. n/a-n/a ◽  
Author(s):  
Leonel Matías Chiacchiarelli ◽  
Mariano Martín Escobar ◽  
José María Kenny ◽  
Luigi Torre ◽  
Analía Vazquez

Sign in / Sign up

Export Citation Format

Share Document