Role of structural disorder in optical absorption in silicon

2010 ◽  
Vol 82 (11) ◽  
Author(s):  
Robert J. Bondi ◽  
Sangheon Lee ◽  
Gyeong S. Hwang
Author(s):  
N. Narasimha Rao, P. Raghava Rao, B. J.R.S.N. Swamy A. Chitti Babu, T.Sambasiva rao and N.Ch.Ramesh Babu

Spectroscopic investigations of V2O5 doped ZnO–Sb2O3–B2O3glass system was prepared by melt-quenching technique. ZnO–Sb2O3–B2O3 glasses containing varying concentrations of V2O5 ranging from 0.1 to 1.0 mol% were prepared, here spectroscopic studies such as Optical absorption, IR and ESR spectra have been carried out as a function of vanadium ion concentration. The optical absorption spectrum of glasses has exhibited two broad absorption bands corresponding to 2B2→2B1 and 2B2→2E transitions of VO2+ ions. The appearances of vibration bands in IR spectra are characteristic for B-O-B and V-O-V linkages, showing the network former role of V2O5. Vanadium ions are believed to be present in two possible valence states, namely V4+and V5+. Here with increasing presence of V2 O5 in the glass network, vanadium ions mostly exist in V4+state and occupy modifying positions. Such increase obviously suggests most structural disorder in the network as the concentration of V2 O5 is increased.


2021 ◽  
Vol 867 ◽  
pp. 159148
Author(s):  
Yu. Hizhnyi ◽  
V. Borysyuk ◽  
V. Chornii ◽  
S. Nedilko ◽  
P.O. Tesel’ko ◽  
...  

2001 ◽  
Vol 226-230 ◽  
pp. 1206-1212 ◽  
Author(s):  
G Bertotti ◽  
V Basso ◽  
C Beatrice ◽  
M LoBue ◽  
A Magni ◽  
...  

RSC Advances ◽  
2015 ◽  
Vol 5 (75) ◽  
pp. 61218-61229 ◽  
Author(s):  
A. M. Banerjee ◽  
M. R. Pai ◽  
A. Arya ◽  
S. R. Bharadwaj

Role of Ni substitution in modifying the crystal structure, optical absorption properties and electronic properties of indium titanate, In2(1−x)Ni2xTiO5−δ (0.0 ≤ 2x ≤ 0.4) and its consequent effect on the photocatalytic properties for H2 generation.


2012 ◽  
Vol 112 (12) ◽  
pp. 123105 ◽  
Author(s):  
L. Lever ◽  
Z. Ikonić ◽  
A. Valavanis ◽  
R. W. Kelsall ◽  
M. Myronov ◽  
...  

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