scholarly journals Oxidation of polycrystalline Ni studied by spectromicroscopy: Phase separation in the early stages of crystallite growth

2010 ◽  
Vol 81 (8) ◽  
Author(s):  
A. Cornish ◽  
T. Eralp ◽  
A. Shavorskiy ◽  
R. A. Bennett ◽  
G. Held ◽  
...  
Keyword(s):  
Phase Separation ◽  
Crystallite Growth ◽  
Early Stages

scholarly journals On the Role of Poly-Glutamic Acid in the Early Stages of Iron(III) (Oxy)(hydr)oxide Formation

Minerals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 715
Author(s):  
Miodrag J. Lukić ◽  
Felix Lücke ◽  
Teodora Ilić ◽  
Katharina Petrović ◽  
Denis Gebauer
Keyword(s):  
Fourier Transform ◽  
Infrared Spectroscopy ◽  
Phase Separation ◽  
Fourier Transform Infrared Spectroscopy ◽  
Fourier Transform Infrared ◽  
Nucleation Theory ◽  
Classical Nucleation Theory ◽  
Oxide Formation ◽  
Early Stages ◽  
Titration Assay

Nucleation of minerals in the presence of additives is critical for achieving control over the formation of solids in biomineralization processes or during syntheses of advanced hybrid materials. Herein, we investigated the early stages of Fe(III) (oxy)(hydr)oxide formation with/without polyglutamic acid (pGlu) at low driving force for phase separation (pH 2.0 to 3.0). We employed an advanced pH-constant titration assay, X-ray diffraction, thermal analysis with mass spectrometry, Fourier Transform infrared spectroscopy, and scanning electron microscopy. Three stages were observed: initial binding, stabilization of Fe(III) pre-nucleation clusters (PNCs), and phase separation, yielding Fe(III) (oxy)(hydr)oxide. The data suggest that organic–inorganic interactions occurred via binding of olation Fe(III) PNC species. Fourier Transform Infrared Spectroscopy (FTIR) analyses revealed a plausible interaction motif and a conformational adaptation of the polypeptide. The stabilization of the aqueous Fe(III) system against nucleation by pGlu contrasts with the previously reported influence of poly-aspartic acid (pAsp). While this is difficult to explain based on classical nucleation theory, alternative notions such as the so-called PNC pathway provide a possible rationale. Developing a nucleation theory that successfully explains and predicts distinct influences for chemically similar additives like pAsp and pGlu is the Holy Grail toward advancing the knowledge of nucleation, early growth, and structure formation.

Early stages ofα−α′phase separation in Fe-Cr alloys: An atomistic study

2009 ◽  
Vol 79 (10) ◽  
Author(s):  
G. Bonny ◽  
D. Terentyev ◽  
L. Malerba ◽  
D. Van Neck
Keyword(s):  
Phase Separation ◽  
Early Stages ◽  
Α Phase ◽  
Atomistic Study

Phase separation during the early stages of ordering in Mi3Mo

1988 ◽  
Vol 36 (2) ◽  
pp. 413-424 ◽  
Author(s):  
U.D. Kulkarni ◽  
S. Banerjee
Keyword(s):  
Phase Separation ◽  
Early Stages

Viscoelastic Effects on the Early Stages of Phase Separation in Polymer Blends

1997 ◽  
Vol 30 (15) ◽  
pp. 4459-4463 ◽  
Author(s):  
N. Clarke ◽  
T. C. B. McLeish ◽  
S. Pavawongsak ◽  
J. S. Higgins
Keyword(s):  
Phase Separation ◽  
Polymer Blends ◽  
Early Stages ◽  
Viscoelastic Effects

The Measurement of Composition During the Early Stages of the Spinodal Decomposition of Fe-Cr Alloys

1990 ◽  
Vol 186 ◽  
Author(s):  
M.G. Hetherington ◽  
J.M. Hyde ◽  
M.K. Miller
Keyword(s):  
Monte Carlo ◽  
Phase Separation ◽  
Spinodal Decomposition ◽  
Atom Probe ◽  
Statistical Techniques ◽  
Fine Scale ◽  
Monte Carlo Calculations ◽  
Early Stages ◽  
Non Linear

AbstractThe properties of many advanced alloys are derived from extremely fine-scale microstructures. This poses interesting questions about the measurement of composition on this scale. The phase separation of model Fe-Cr alloys has been been studied with the atom-probe. Statistical techniques have been used to estimate the composition and compare the results with the predictions of linear and non-linear theories of spinodal decomposition and the distributions obtained from Monte-Carlo calculations.

scholarly journals Revealing the early stages of carbamazepine crystallization by cryoTEM and 3D electron diffraction

IUCrJ ◽  
2021 ◽  
Vol 8 (6) ◽  
Author(s):  
Edward T. Broadhurst ◽  
Hongyi Xu ◽  
Simon Parsons ◽  
Fabio Nudelman
Keyword(s):  
Phase Separation ◽  
Electron Diffraction ◽  
Early Stage ◽  
Active Pharmaceutical Ingredient ◽  
Time Resolved ◽  
Carbamazepine Dihydrate ◽  
Early Stages ◽  
3D Electron

Time-resolved carbamazepine crystallization from wet ethanol has been monitored using a combination of cryoTEM and 3D electron diffraction. Carbamazepine is shown to crystallize exclusively as a dihydrate after 180 s. When the timescale was reduced to 30 s, three further polymorphs could be identified. At 20 s, the development of early stage carbamazepine dihydrate was observed through phase separation. This work reveals two possible crystallization pathways present in this active pharmaceutical ingredient.

Early Stages of Crystallite Growth of ZnO Obtained from an Oxalate Precursor

1995 ◽  
Vol 78 (2) ◽  
pp. 323-328 ◽  
Author(s):  
Jean-Paul Auffrédic ◽  
All Boultif ◽  
J. Ian Langford ◽  
Daniel Louër
Keyword(s):  
Crystallite Growth ◽  
Oxalate Precursor ◽  
Early Stages

Kinetics At Early Stages of Phase Separation And Ordering in Alloys

1996 ◽  
pp. 191-195
Author(s):  
S. V. Beiden ◽  
V. Yu. Dobretsov ◽  
G. Martin ◽  
F. Soisson ◽  
V. G. Vaks
Keyword(s):  
Phase Separation ◽  
Early Stages

Early stages of phase separation using three-dimensional atom probe and atomistic modelling

2007 ◽  
Vol 39 (2-3) ◽  
pp. 178-183 ◽  
Author(s):  
Mattias Slabanja ◽  
Johan Angenete ◽  
Krystyna Stiller ◽  
Karin M. Carling ◽  
Göran Wahnström ◽  
...  
Keyword(s):  
Phase Separation ◽  
Three Dimensional ◽  
Atom Probe ◽  
Early Stages ◽  
Atomistic Modelling
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