Isostructural transition coupled with spin ordering inCsCuCl3: A spatially frustrated spiral crystal lattice

2009 ◽  
Vol 79 (1) ◽  
Author(s):  
V. P. Plakhty ◽  
J. Wosnitza ◽  
N. Martin ◽  
Ya. Marchi ◽  
O. P. Smirnov ◽  
...  
Keyword(s):  
Crystal Lattice ◽  
Spin Ordering

scholarly journals Enhancement of anisotropy energy of SmCo5 by ceasing the coupling at 2c sites in the crystal lattice with Cu substitution

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Syed Kamran Haider ◽  
Hieu Minh Ngo ◽  
Dongsoo Kim ◽  
Young Soo Kang
Keyword(s):  
Crystal Lattice ◽  
Energy Efficient ◽  
Magnetic Particles ◽  
Anisotropy Energy ◽  
Ternary Alloys ◽  
Total Cost ◽  
Additional Weight ◽  
Cu Substitution ◽  
Decoupling Effect ◽  
Co Precipitation

AbstractSmCo5 and SmCo5−xCux magnetic particles were produced by co-precipitation followed by reduction diffusion. HRTEM confirmed the Cu substitution in the SmCo5 lattice. Non-magnetic Cu was substituted at “2c” site in the SmCo5 crystal lattice and effectively stopped the coupling in its surroundings. This decoupling effect decreased magnetic moment from SmCo5 (12.86 μB) to SmCo4Cu (10.58 μB) and SmCo3Cu2 (7.79 μB) and enhanced anisotropy energy from SmCo5 (10.87 Mega erg/cm3) to SmCo4Cu (14.05 Mega erg/cm3) and SmCo3Cu2 (14.78 Mega erg/cm3). Enhancement of the anisotropy energy increased the coercivity as its values for SmCo5, SmCo4Cu and SmCo3Cu2 were recorded as 4.5, 5.97 and 6.99 kOe respectively. Being six times cheaper as compared to Co, substituted Cu reduced the price of SmCo3Cu2 up to 2%. Extra 15% Co was added which not only enhanced the Mr value but also reduced the 5% of the total cost because of additional weight added to the SmCo3Cu2. Method reported in this work is most energy efficient method on the synthesis of Sm–Co–Cu ternary alloys until now.

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