scholarly journals Electronic thermal conductivity at high temperatures: Violation of the Wiedemann-Franz law in narrow-band metals

2006 ◽  
Vol 74 (23) ◽  
Author(s):  
K. Vafayi ◽  
M. Calandra ◽  
O. Gunnarsson
1954 ◽  
Vol 7 (1) ◽  
pp. 57 ◽  
Author(s):  
PG Klemens

Makinson's (1938) theory of the lattice component of the thermal conductivity of metals and alloys, when limited at low temperatures by interaction with the conduction electrons, is re-examined, and the magnitude of the lattice conductivity is related to the electronic thermal conductivity at low temperatures, thus avoiding uncertainties in the theory at high temperatures. The result depends on whether transverse lattice waves can interact with the electrons.


2009 ◽  
Vol 24 (2) ◽  
pp. 430-435 ◽  
Author(s):  
D. Li ◽  
H.H. Hng ◽  
J. Ma ◽  
X.Y. Qin

The thermoelectric properties of Nb-doped Zn4Sb3 compounds, (Zn1–xNbx)4Sb3 (x = 0, 0.005, and 0.01), were investigated at temperatures ranging from 300 to 685 K. The results showed that by substituting Zn with Nb, the thermal conductivities of all the Nb-doped compounds were lower than that of the pristine β-Zn4Sb3. Among the compounds studied, the lightly substituted (Zn0.995Nb0.005)4Sb3 compound exhibited the best thermoelectric performance due to the improvement in both its electrical resistivity and thermal conductivity. Its figure of merit, ZT, was greater than the undoped Zn4Sb3 compound for the temperature range investigated. In particular, the ZT of (Zn0.995Nb0.005)4Sb3 reached a value of 1.1 at 680 K, which was 69% greater than that of the undoped Zn4Sb3 obtained in this study.


1961 ◽  
Vol 39 (7) ◽  
pp. 1029-1039 ◽  
Author(s):  
M. J. Laubitz

A method is given for exact mathematical analysis of linear heat flow systems used in measuring thermal conductivity at high temperatures. It is shown that a popular version of such a system is very sensitive to the alignment of its components, which seriously limits the temperature range of its satisfactory use.


1965 ◽  
Vol 48 (1) ◽  
pp. 31-34 ◽  
Author(s):  
TORAJI NISHIJIMA ◽  
TOSHIYUKI KAWADA ◽  
AKIRA ISHIHATA

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