Magnetic structure ofβ−ErD2: Long-range and short-range order from powder neutron diffraction

2005 ◽  
Vol 71 (5) ◽  
Author(s):  
P. Vajda ◽  
G. André ◽  
T. J. Udovic ◽  
R. W. Erwin ◽  
Q. Huang
1985 ◽  
Vol 46 (C8) ◽  
pp. C8-87-C8-92 ◽  
Author(s):  
R. Bellissent ◽  
J. Bigot ◽  
Y. Calvayrac ◽  
S. Lefebvre ◽  
A. Quivy

1997 ◽  
Vol 12 (8) ◽  
pp. 2117-2126 ◽  
Author(s):  
Hyun M. Jang ◽  
Su-Chan Kim

The limitation of the long-range order parameter and the necessity of the short-range order parameter for the thermodynamic description of Pb()O3-type perovskites are discussed. Based on the discussion, a statistical thermodynamic model that takes into account the configuration of the neighboring B-site ions (B′ and B″ cations) was developed. A pair-correlation approximation was used in the calculation of the configurational entropy and the long-range coulombic interaction energy between the nearest B-site ions. The theoretical calculations using Pb(Sc1/2Ta1/2)O3 (PST) and Pb(Sc1/2Nb1/2)O3 (PSN) systems indicate that the short-range order parameter persists over a wide range of temperatures examined (0–1800 K) and that there possibly occur consecutive long-range order-disorder transitions in the configuration of B-site cations. The possibility of the existence of short-range ordering above the long-range order-disorder transition temperature was also examined using the annealed PSN specimen as a typical example of Pb()O3-type perovskites.


1978 ◽  
Vol 34 (6) ◽  
pp. 1025-1027 ◽  
Author(s):  
M. Gasgnier ◽  
P. Caro

Kaul & Saxena [Acta Cryst. (1977), A33, 992-996] have reported the existence of long-range and short-range order in a non-stoichiometric phase 'LnO x ' (Ln = rare earth). It is shown that the experiments they are describing are indeed the oxidation of the rare-earth hydride LnH2 into the rare-earth cubic C-type sesquioxide. The interpretation they give of their experiments is to be discarded entirely.


1998 ◽  
Vol 46 (3) ◽  
pp. 881-892 ◽  
Author(s):  
Satoshi Hata ◽  
Syo Matsumura ◽  
Noriyuki Kuwano ◽  
Kensuke Oki

1990 ◽  
Vol 126 (3) ◽  
pp. 255-258 ◽  
Author(s):  
S. Neov ◽  
V. Kozhukharov ◽  
I. Gerasimova ◽  
B. Sidzhimov

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