Dynamical mechanism of the ferroelectric phase transition ofSrTi18O3studied by light scattering

2003 ◽  
Vol 68 (1) ◽  
Author(s):  
Hiroki Hasebe ◽  
Yuhji Tsujimi ◽  
Ruiping Wang ◽  
Mitsuru Itoh ◽  
Toshirou Yagi
2015 ◽  
Vol 05 (02) ◽  
pp. 1550011
Author(s):  
Seonhyeop Shin ◽  
Jae-Hyeon Ko ◽  
Shinya Tsukada ◽  
Yukikuni Akishige ◽  
Krystian Roleder ◽  
...  

The elastic properties of KF-substituted perovskite lead titanate ( PbTiO 3) were investigated by dielectric measurements and Brillouin light scattering. The ferroelectric phase transition occurred at substantially lower temperature due to KF substitution, which was attributed to the modification of the covalency in Pb – O and Ti – O bonds. The longitudinal acoustic (LA) mode of KF-substituted PbTiO 3 showed a frequency softening in the paraelectric phase, which was accompanied by increasing acoustic damping. This indicated that polarization fluctuations responsible for the acoustic anomalies were enhanced by KF substitution.


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