scholarly journals Crucial effects of intramolecular charge distribution on the neutral-ionic transition of tetrathiafulvalene–p-chloranil

2001 ◽  
Vol 64 (20) ◽  
Author(s):  
Tohru Kawamoto ◽  
Takako Iizuka-Sakano ◽  
Yukihiro Shimoi ◽  
Shuji Abe
Keyword(s):  
Charge Distribution ◽  
Ionic Transition

Study of charge transfer in FeTi

1983 ◽  
Vol 41 ◽  
pp. 296-297
Author(s):  
J. Taft∅
Keyword(s):  
Charge Transfer ◽  
Charge Distribution ◽  
Electron Scattering ◽  
Periodic System ◽  
Electron Distribution ◽  
Scattering Amplitude ◽  
Transition Elements ◽  
Hartree Fock ◽  
Cscl Structure ◽  
The Right

It is well known that for reflections corresponding to large interplanar spacings (i.e., sin θ/λ small), the electron scattering amplitude, f, is sensitive to the ionicity and to the charge distribution around the atoms. We have used this in order to obtain information about the charge distribution in FeTi, which is a candidate for storage of hydrogen. Our goal is to study the changes in electron distribution in the presence of hydrogen, and also the ionicity of hydrogen in metals, but so far our study has been limited to pure FeTi. FeTi has the CsCl structure and thus Fe and Ti scatter with a phase difference of π into the 100-ref lections. Because Fe (Z = 26) is higher in the periodic system than Ti (Z = 22), an immediate “guess” would be that Fe has a larger scattering amplitude than Ti. However, relativistic Hartree-Fock calculations show that the opposite is the case for the 100-reflection. An explanation for this may be sought in the stronger localization of the d-electrons of the first row transition elements when moving to the right in the periodic table. The tabulated difference between fTi (100) and ffe (100) is small, however, and based on the values of the scattering amplitude for isolated atoms, the kinematical intensity of the 100-reflection is only 5.10-4 of the intensity of the 200-reflection.

Charge distribution on dust particles of space plasma

2003 ◽  
Vol 9 (4) ◽  
pp. 67-72 ◽  
Author(s):  
Yu.O. Klymenko ◽  
◽  
О.К. Cheremnykh ◽  
Keyword(s):  
Charge Distribution ◽  
Space Plasma ◽  
Dust Particles

Space Charge Distribution Measurement in FEP Film Irradiated by Proton

2020 ◽  
Vol 140 (10) ◽  
pp. 504-505
Author(s):  
Kaisei Enoki ◽  
Ushio Chiba ◽  
Hiroaki Miyake ◽  
Yasuhiro Tanaka
Keyword(s):  
Space Charge ◽  
Charge Distribution ◽  
Distribution Measurement ◽  
Space Charge Distribution

Charge distribution inY1−xPrxBa2Cu3O7: A valency model for the depression ofTc

1995 ◽  
Vol 52 (1) ◽  
pp. 85-88 ◽  
Author(s):  
Shigenori Tanaka ◽  
Yuichi Motoi
Keyword(s):  
Charge Distribution

scholarly journals Mapping Surface Charge Distribution of Single-Cell via Charged Nanoparticle

Cells ◽  
2021 ◽  
Vol 10 (6) ◽  
pp. 1519
Author(s):  
Leixin Ouyang ◽  
Rubia Shaik ◽  
Ruiting Xu ◽  
Ge Zhang ◽  
Jiang Zhe
Keyword(s):  
Cell Surface ◽  
Charge Density ◽  
Surface Charge ◽  
Charge Distribution ◽  
Surface Charge Density ◽  
Single Cells ◽  
Fluorescent Light ◽  
Fluorescent Nanoparticles ◽  
Cell Surface Charge ◽  
Surface Charge Distribution

Many bio-functions of cells can be regulated by their surface charge characteristics. Mapping surface charge density in a single cell’s surface is vital to advance the understanding of cell behaviors. This article demonstrates a method of cell surface charge mapping via electrostatic cell–nanoparticle (NP) interactions. Fluorescent nanoparticles (NPs) were used as the marker to investigate single cells’ surface charge distribution. The nanoparticles with opposite charges were electrostatically bonded to the cell surface; a stack of fluorescence distribution on a cell’s surface at a series of vertical distances was imaged and analyzed. By establishing a relationship between fluorescent light intensity and number of nanoparticles, cells’ surface charge distribution was quantified from the fluorescence distribution. Two types of cells, human umbilical vein endothelial cells (HUVECs) and HeLa cells, were tested. From the measured surface charge density of a group of single cells, the average zeta potentials of the two types of cells were obtained, which are in good agreement with the standard electrophoretic light scattering measurement. This method can be used for rapid surface charge mapping of single particles or cells, and can advance cell-surface-charge characterization applications in many biomedical fields.

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