Resonant emission spectra ofYF3,YCl3,Y2O3and Y-metal in the YLIIIabsorption region

2000 ◽  
Vol 61 (11) ◽  
pp. 7433-7439 ◽  
Author(s):  
S. Nakai ◽  
Y. Megawa ◽  
F. Terasaki ◽  
Chen Gang ◽  
T. Ohuchi ◽  
...  
1994 ◽  
Vol 375 ◽  
Author(s):  
J. A. Carlisle ◽  
E. L. Shirley ◽  
L. J. Terminello ◽  
E. A. Hudson ◽  
J. J. Jia ◽  
...  

AbstractWe are using resonant soft x-ray fluorescence at the Advanced Light Source to probe the electronic and geometric structure of novel materials. In the resonant process, a core electron is excited by a photon whose energy is near the core binding energy. In this energy regime the absorption and emission processes are coupled, and this coupling manifests itself in several ways. In boron nitride (BN), the resonant emission spectra reflect the influence of a “spectator” electron in an unoccupied excitonic state. The resonant emission can be used to distinguish between the various bulk phases of BN, and can also be used to probe the electronic structure of a monolayer of BN buried in a bulk environment, where it is inaccessible to electron spectroscopies. For highly-oriented pyrolytic graphite (HOPG) a coherent absorption-emission process takes place in the resonant regime, whereby crystalline momentum is conserved between the core excited electron and the valence hole which remains after emission


2002 ◽  
Vol 09 (02) ◽  
pp. 871-875 ◽  
Author(s):  
Y. TAGUCHI ◽  
Y. OKABAYASHI ◽  
T. UOZUMI ◽  
K. MIMURA ◽  
K. ICHIKAWA ◽  
...  

Co 3d → 2p X-ray emission spectra of LaCoO 3 in the Co 2p photoabsorption region are measured at 40 and 300 K. The spectra mainly reveal features nearly independent of excitation photon energy. This indicates the highly covalent or strongly hybridized nature of the Co 3d state. The emission component showing resonant behavior is also observed. The temperature dependence of the resonant emission confirms that the wave function of Co 3d electrons is totally symmetric in the low-spin ground state and that for the spin state excited thermally through the magnetic transition around 100 K is not.


Author(s):  
Y. Y. Wang ◽  
H. Zhang ◽  
V. P. Dravid ◽  
H. Zhang ◽  
L. D. Marks ◽  
...  

Azuma et al. observed planar defects in a high pressure synthesized infinitelayer compound (i.e. ACuO2 (A=cation)), which exhibits superconductivity at ~110 K. It was proposed that the defects are cation deficient and that the superconductivity in this material is related to the planar defects. In this report, we present quantitative analysis of the planar defects utilizing nanometer probe xray microanalysis, high resolution electron microscopy, and image simulation to determine the chemical composition and atomic structure of the planar defects. We propose an atomic structure model for the planar defects.Infinite-layer samples with the nominal chemical formula, (Sr1-xCax)yCuO2 (x=0.3; y=0.9,1.0,1.1), were prepared using solid state synthesized low pressure forms of (Sr1-xCax)CuO2 with additions of CuO or (Sr1-xCax)2CuO3, followed by a high pressure treatment.Quantitative x-ray microanalysis, with a 1 nm probe, was performed using a cold field emission gun TEM (Hitachi HF-2000) equipped with an Oxford Pentafet thin-window x-ray detector. The probe was positioned on the planar defects, which has a 0.74 nm width, and x-ray emission spectra from the defects were compared with those obtained from vicinity regions.


1997 ◽  
Vol 7 (C2) ◽  
pp. C2-515-C2-516
Author(s):  
H. Agren ◽  
L. G.M. Pettersson ◽  
V. Carravetta ◽  
Y. Luo ◽  
L. Yang ◽  
...  

1980 ◽  
Vol 41 (12) ◽  
pp. 1431-1436 ◽  
Author(s):  
M. Larzillière ◽  
F. Launay ◽  
J.-Y. Roncin

1979 ◽  
Vol 40 (C2) ◽  
pp. C2-417-C2-419
Author(s):  
C. H.W. Jones ◽  
M. Dombsky
Keyword(s):  

1974 ◽  
Vol 35 (C6) ◽  
pp. C6-324-C6-324
Author(s):  
A. G. MADDOCK ◽  
A. F. WILLIAMS ◽  
J. FENGER ◽  
K. E. SIERKIERSKA
Keyword(s):  

1987 ◽  
Vol 48 (C9) ◽  
pp. C9-1059-C9-1062
Author(s):  
P. J. DURHAM ◽  
C. F. HAGUE ◽  
J.-M. MARIOT ◽  
W. M. TEMMERMAN

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