Calorimetric study of an electrochemically oxidized crystal ofLa2CuO4.05:Stabilization phenomenon, phase transitions, and a glass transition due to freezing-in of the rearrangement of excess oxygen atoms

1999 ◽  
Vol 60 (9) ◽  
pp. 6821-6826 ◽  
Author(s):  
Tôru Kyômen ◽  
Masaharu Oguni ◽  
Mitsuru Itoh ◽  
Jian Ding Yu
Keyword(s):  
Glass Transition ◽  
Phase Transitions ◽  
Excess Oxygen ◽  
Calorimetric Study ◽  
Oxygen Atoms

scholarly journals Predicting the glass transition temperature and viscosity of secondary organic material using molecular composition

2018 ◽  
Vol 18 (9) ◽  
pp. 6331-6351 ◽  
Author(s):  
Wing-Sy Wong DeRieux ◽  
Ying Li ◽  
Peng Lin ◽  
Julia Laskin ◽  
Alexander Laskin ◽  
...  
Keyword(s):  
Glass Transition ◽  
Transition Temperature ◽  
Glass Transition Temperature ◽  
Chemical Composition ◽  
Organic Compounds ◽  
Molar Mass ◽  
Solid Phase ◽  
Amorphous Solid ◽  
Semi Solid ◽  
Oxygen Atoms

Abstract. Secondary organic aerosol (SOA) accounts for a large fraction of submicron particles in the atmosphere. SOA can occur in amorphous solid or semi-solid phase states depending on chemical composition, relative humidity (RH), and temperature. The phase transition between amorphous solid and semi-solid states occurs at the glass transition temperature (Tg). We have recently developed a method to estimate Tg of pure compounds containing carbon, hydrogen, and oxygen atoms (CHO compounds) with molar mass less than 450 g mol−1 based on their molar mass and atomic O : C ratio. In this study, we refine and extend this method for CH and CHO compounds with molar mass up to ∼ 1100 g mol−1 using the number of carbon, hydrogen, and oxygen atoms. We predict viscosity from the Tg-scaled Arrhenius plot of fragility (viscosity vs. Tg∕T) as a function of the fragility parameter D. We compiled D values of organic compounds from the literature and found that D approaches a lower limit of ∼ 10 (±1.7) as the molar mass increases. We estimated the viscosity of α-pinene and isoprene SOA as a function of RH by accounting for the hygroscopic growth of SOA and applying the Gordon–Taylor mixing rule, reproducing previously published experimental measurements very well. Sensitivity studies were conducted to evaluate impacts of Tg, D, the hygroscopicity parameter (κ), and the Gordon–Taylor constant on viscosity predictions. The viscosity of toluene SOA was predicted using the elemental composition obtained by high-resolution mass spectrometry (HRMS), resulting in a good agreement with the measured viscosity. We also estimated the viscosity of biomass burning particles using the chemical composition measured by HRMS with two different ionization techniques: electrospray ionization (ESI) and atmospheric pressure photoionization (APPI). Due to differences in detected organic compounds and signal intensity, predicted viscosities at low RH based on ESI and APPI measurements differ by 2–5 orders of magnitude. Complementary measurements of viscosity and chemical composition are desired to further constrain RH-dependent viscosity in future studies.

Calorimetric study of the ferroelectric phase transitions in CsLiWo4crystal

1982 ◽  
Vol 44 (1) ◽  
pp. 235-239 ◽  
Author(s):  
I. N. Flerov ◽  
I. M. Iskornev ◽  
M. V. Gorev
Keyword(s):  
Phase Transitions ◽  
Ferroelectric Phase ◽  
Calorimetric Study ◽  
Ferroelectric Phase Transitions

Calorimetric study of the glass transition occurring in aqueous glucose: Fructose solutions

1993 ◽  
Vol 63 (2) ◽  
pp. 177-188 ◽  
Author(s):  
I. Arvanitoyannis ◽  
J. M. V. Blanshard ◽  
M. J. Izzard ◽  
P. J. Lillford ◽  
S. Ablett
Keyword(s):  
Glass Transition ◽  
Calorimetric Study

scholarly journals Calorimetric study of the phase transitions in HMTTF - TCNQ

1979 ◽  
Vol 40 (7) ◽  
pp. 151-152 ◽  
Author(s):  
K. Biljaković-Franulović ◽  
S. Tomić ◽  
M. Prester ◽  
D. Djurek
Keyword(s):  
Phase Transitions ◽  
Calorimetric Study

Calorimetric Study of Phase Transitions Involving Twist-Grain-Boundary TGBA and TGBC Phases

1996 ◽  
Vol 6 (9) ◽  
pp. 1243-1258 ◽  
Author(s):  
L. Navailles ◽  
C. W. Garland ◽  
H. T. Nguyen
Keyword(s):  
Phase Transitions ◽  
Grain Boundary ◽  
Calorimetric Study
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