Theoretical treatment of the mixed ferro-ferrimagnets composed of ternary-metal Prussian blue analogs in a paramagnetic region

1999 ◽  
Vol 60 (18) ◽  
pp. 12820-12825 ◽  
Author(s):  
Shin-ichi Ohkoshi ◽  
Kazuhito Hashimoto
Keyword(s):  
Prussian Blue ◽  
Theoretical Treatment ◽  
Paramagnetic Region ◽  
Ternary Metal ◽  
Prussian Blue Analogs

A Dual-Insertion Type Sodium-Ion Full Cell Based on High-Quality Ternary-Metal Prussian Blue Analogs

2018 ◽  
Vol 8 (11) ◽  
pp. 1702856 ◽  
Author(s):  
Jian Peng ◽  
Jinsong Wang ◽  
Haocong Yi ◽  
WenJing Hu ◽  
Yonghui Yu ◽  
...  
Keyword(s):  
Prussian Blue ◽  
Sodium Ion ◽  
High Quality ◽  
Full Cell ◽  
Ternary Metal ◽  
Prussian Blue Analogs

scholarly journals “Green” Prussian Blue Analogues as Peroxidase Mimetics for Amperometric Sensing and Biosensing

Biosensors ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 193
Author(s):  
Galina Z. Gayda ◽  
Olha M. Demkiv ◽  
Yanna Gurianov ◽  
Roman Ya. Serkiz ◽  
Halyna M. Klepach ◽  
...  
Keyword(s):  
Prussian Blue ◽  
Noble Metals ◽  
High Sensitivity ◽  
Graphite Electrodes ◽  
Flavocytochrome B2 ◽  
Prussian Blue Analogues ◽  
Scientific Investigations ◽  
Electrochemically Active ◽  
Amperometric Sensing ◽  
Prussian Blue Analogs

Prussian blue analogs (PBAs) are well-known artificial enzymes with peroxidase (PO)-like activity. PBAs have a high potential for applications in scientific investigations, industry, ecology and medicine. Being stable and both catalytically and electrochemically active, PBAs are promising in the construction of biosensors and biofuel cells. The “green” synthesis of PO-like PBAs using oxido-reductase flavocytochrome b2 is described in this study. When immobilized on graphite electrodes (GEs), the obtained green-synthesized PBAs or hexacyanoferrates (gHCFs) of transition and noble metals produced amperometric signals in response to H2O2. HCFs of copper, iron, palladium and other metals were synthesized and characterized by structure, size, catalytic properties and electro-mediator activities. The gCuHCF, as the most effective PO mimetic with a flower-like micro/nano superstructure, was used as an H2O2-sensitive platform for the development of a glucose oxidase (GO)-based biosensor. The GO/gCuHCF/GE biosensor exhibited high sensitivity (710 A M−1m−2), a broad linear range and good selectivity when tested on real samples of fruit juices. We propose that the gCuHCF and other gHCFs synthesized via enzymes may be used as artificial POs in amperometric oxidase-based (bio)sensors.

Switchable self-assembly of Prussian blue analogs nano-tiles triggered by salt stimulus

2016 ◽  
Vol 18 (4) ◽  
pp. 3188-3196 ◽  
Author(s):  
D. Dedovets ◽  
P. Bauduin ◽  
J. Causse ◽  
L. Girard ◽  
O. Diat
Keyword(s):  
Ionic Strength ◽  
Prussian Blue ◽  
Self Assembly ◽  
Prussian Blue Analogues ◽  
Prussian Blue Analogs ◽  
Superlattice Structures

We showed fully reversible, ionic strength controlled self-assembly of Prussian blue analogues nano-tiles into large superlattice structures.

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