Ferroelastic phase transition in rutile-type germanium dioxide at high pressure

1998 ◽  
Vol 58 (6) ◽  
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J. M. Léger ◽  
C. Chateau ◽  
R. Bini ◽  
L. Ulivi
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...  

Orpiment (α-As2S3) under compression reports a strong change in the coordination of As atoms at 25 GPa, which can be ascribed to an isostructural phase transition. These changes are consistent with the formation of metavalent bonds in orpiment.


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