Model of transient photoinduced absorption with an exciton polaron in conjugated polymers

1998 ◽  
Vol 57 (11) ◽  
pp. 6386-6390 ◽  
Author(s):  
V. A. Shakin ◽  
S. Abe ◽  
Y. Shimoi
1989 ◽  
Vol 173 ◽  
Author(s):  
R. Zamboni ◽  
C. Taliani ◽  
G. Ruani ◽  
A. J. Pal ◽  
F. Kajzar

ABSTRACTNonlinear optical properties of two thiophene-based conjugated polymers (PTT and PDTB) were studied by the photoinduced absorption spectroscopy and the third harmonic generation spectroscopy. The results obtained with these two methods are used to estimate the value of χ(3) in these materials. Resonant χ(3) are (2.0 ± 0.2) × 10−11 e.s.u. and (1.0 ± 0.1) × 10−11 e.s.u. for PTT and PDTB, respectively. χ(3) is shown to be related to the width of the optical gap through a sixth-power law. In PTT a vibronic structure due to the C = C stretching mode appears in the χ(3) spectrum.


1993 ◽  
Vol 328 ◽  
Author(s):  
F. Guo ◽  
M. Chandross ◽  
S. Mazumdar

ABSTRACTTwo photon absorptions (TPA) in conjugated polymers with large bond alternation are reinterpreted. TPA to the 2Ag in long chains should be tiny due to cancellation effects, and therefore the observed strong, narrow TPA is to a higher even parity state. We also present the first theoretical evidence for bound biexcitons, and explain recent photoinduced absorption data.


1991 ◽  
Vol 41 (1-2) ◽  
pp. 579-582 ◽  
Author(s):  
A.J. Pal ◽  
G. Ruani ◽  
R. Zamboni ◽  
R. Danieli ◽  
C. Taliani

1995 ◽  
Vol 69 (1-3) ◽  
pp. 441-442 ◽  
Author(s):  
R.A.J. Janssen ◽  
N.S. Sariciftci ◽  
K. Pakbaz ◽  
J.J. McNamara ◽  
S. Schricker ◽  
...  

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