scholarly journals Electrical conductivity relaxation and nuclear magnetic resonance of Li conductingLi0.5La0.5TiO3

1996 ◽  
Vol 54 (1) ◽  
pp. 184-189 ◽  
Author(s):  
C. León ◽  
M. L. Lucía ◽  
J. Santamaría ◽  
M. A. París ◽  
J. Sanz ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Nuclear Magnetic Resonance ◽  
Magnetic Resonance ◽  
Conductivity Relaxation ◽  
Electrical Conductivity Relaxation ◽  
Nuclear Magnetic

Reactions of Sodium N,N-Diethyldithiocarbamate with the Chlorides and Bromides of Niobium(V), Tantalum(V), and Protactinium(V)

1971 ◽  
Vol 49 (8) ◽  
pp. 1151-1160 ◽  
Author(s):  
P. R. Heckley ◽  
D. G. Holah ◽  
D. Brown
Keyword(s):  
Electrical Conductivity ◽  
Molecular Weight ◽  
Nuclear Magnetic Resonance ◽  
Magnetic Resonance ◽  
Organic Solvents ◽  
Conductivity Measurements ◽  
Nuclear Magnetic

Reactions between niobium(V), tantalum(V), and protactinium(V) chlorides and bromides and sodium N,N-diethyldithiocarbamate (Nadtc) have been examined in non-aqueous, non-oxygenated organic solvents. Complexes obtained are of the types Mdtc4X, Mdtc3X2, Mdtc3S, Mdtc2X3, and Mdtc2X3.nC6H6 (n = 0.7–1.0); not all complexes have been isolated for each metal. Within each group the niobium(V) and tantalum(V) complexes are isostructural; possible structures are discussed in the light of results from infrared (i.r.) and nuclear magnetic resonance (n.m.r.) spectra, molecular weight, and electrical conductivity measurements.

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