Temperature-dependent adsorption of hydrogen, deuterium, and neon on porous Vycor glass

1995 ◽  
Vol 52 (15) ◽  
pp. 11372-11379 ◽  
Author(s):  
T. E. Huber ◽  
D. Scardino ◽  
H. L. Tsou
1990 ◽  
Vol 80 (5-6) ◽  
pp. 315-323 ◽  
Author(s):  
T. E. Huber ◽  
C. A. Huber

2008 ◽  
Vol 80 (2) ◽  
pp. 263-269
Author(s):  
Iara F. Gimenez ◽  
Oswaldo L. Alves

Thermal behavior of the complexes Pd2(dppm)2Cl2, Pd2(dppm)2(SnCl3)Cl and Pd2(dppm)2(SnCl3)2 (dppm = bis[diphenylphosphino(methane)], ((C6H5)2PCH2P(C6H5)2) in the solid state and immobilized onto porous Vycor glass was studied. Similar decomposition mechanisms were observed for the solid and immobilized complexes, with a small thermal stabilization upon immobilization. The decomposition products were characterized by X-ray diffractometry, Raman and diffuse reflectance infrared spectroscopy, which indicated the presence of a mixture of metallic palladium and oxidized species such as PdO,condensed phosphates, SnO2 and SnP2O7. According to X-ray diffractometry, the decomposition products of the immobilized complexes presented higher amounts of PdO than the solid-state residues, probably as an effect of interactions with silanol groups present in the glass surface.


1996 ◽  
Vol 105 (1-2) ◽  
pp. 113-131 ◽  
Author(s):  
G. Beaudoin ◽  
P. Haljan ◽  
M. Paetkau ◽  
J. R. Beamish

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