Effects of temperature and hydrostatic pressure on the magnetoelasticity of a commensurate spin-density-wave antiferromagnetic Cr–3.5 at. % Al alloy single crystal

1995 ◽  
Vol 51 (21) ◽  
pp. 15146-15155 ◽  
Author(s):  
H. L. Alberts ◽  
P. Smit
Keyword(s):  
Hydrostatic Pressure ◽  
Single Crystal ◽  
Spin Density ◽  
Density Wave ◽  
Spin Density Wave ◽  
Alloy Single Crystal ◽  
Al Alloy ◽  
Effects Of Temperature

Ultrafast quasiparticle dynamics in spin-density-wave LaOFeAs single crystal

2013 ◽  
Vol 56 (12) ◽  
pp. 2395-2398 ◽  
Author(s):  
RongYan Chen ◽  
Tao Dong ◽  
HaiPeng Wang ◽  
NanLin Wang
Keyword(s):  
Single Crystal ◽  
Spin Density ◽  
Density Wave ◽  
Spin Density Wave ◽  
Quasiparticle Dynamics

Galvanomagnetic properties in the spin-density-wave phase of (TMTSF)2PF6

1999 ◽  
Vol 09 (PR10) ◽  
pp. Pr10-247-Pr10-249 ◽  
Author(s):  
B. Korin-Hamzic ◽  
M. Basletić ◽  
N. Francetić ◽  
A. Hamzić ◽  
K. Bechgaard
Keyword(s):  
Spin Density ◽  
Density Wave ◽  
Spin Density Wave ◽  
Wave Phase ◽  
Galvanomagnetic Properties

scholarly journals Old Donors for New Molecular Conductors: Combining TMTSF and BEDT-TTF with Anionic (TaF6)1−x/(PF6)x Alloys

Crystals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 386
Author(s):  
Magali Allain ◽  
Cécile Mézière ◽  
Pascale Auban-Senzier ◽  
Narcis Avarvari
Keyword(s):  
Single Crystal ◽  
Room Temperature ◽  
Density Wave ◽  
Spin Density Wave ◽  
Orthorhombic Phase ◽  
Molecular Conductors ◽  
Bechgaard Salts ◽  
Temperature Conductivity ◽  
Room Temperature Conductivity ◽  
Resistivity Measurements

Tetramethyl-tetraselenafulvalene (TMTSF) and bis(ethylenedithio)-tetrathiafulvalene (BEDT-TTF) are flagship precursors in the field of molecular (super)conductors. The electrocrystallization of these donors in the presence of (n-Bu4N)TaF6 or mixtures of (n-Bu4N)TaF6 and (n-Bu4N)PF6 provided Bechgaard salts formulated as (TMTSF)2(TaF6)0.84(PF6)0.16, (TMTSF)2(TaF6)0.56(PF6)0.44, (TMTSF)2(TaF6)0.44(PF6)0.56 and (TMTSF)2(TaF6)0.12(PF6)0.88, together with the monoclinic and orthorhombic phases δm-(BEDT-TTF)2(TaF6)0.94(PF6)0.06 and δo-(BEDT-TTF)2(TaF6)0.43(PF6)0.57, respectively. The use of BEDT-TTF and a mixture of (n-Bu4N)TaF6/TaF5 afforded the 1:1 phase (BEDT-TTF)2(TaF6)2·CH2Cl2. The precise Ta/P ratio in the alloys has been determined by an accurate single crystal X-ray data analysis and was corroborated with solution 19F NMR measurements. In the previously unknown crystalline phase (BEDT-TTF)2(TaF6)2·CH2Cl2 the donors organize in dimers interacting laterally yet no organic-inorganic segregation is observed. Single crystal resistivity measurements on the TMTSF based materials show typical behavior of the Bechgaard phases with room temperature conductivity σ ≈ 100 S/cm and localization below 12 K indicative of a spin density wave transition. The orthorhombic phase δo-(BEDT-TTF)2(TaF6)0.43(PF6)0.57 is semiconducting with the room temperature conductivity estimated to be σ ≈ 0.16–0.5 S/cm while the compound (BEDT-TTF)2(TaF6)2·CH2Cl2 is also a semiconductor, yet with a much lower room temperature conductivity value of 0.001 to 0.0025 S/cm, in agreement with the +1 oxidation state and strong dimerization of the donors.

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