First-principles studies of NO chemisorption on rhodium, palladium, and platinum surfaces

M.-H. Tsai; K. C. Hass

doi:10.1103/physrevb.51.14616

First-principles studies of NO chemisorption on rhodium, palladium, and platinum surfaces

Physical Review B ◽

10.1103/physrevb.51.14616 ◽

1995 ◽

Vol 51 (20) ◽

pp. 14616-14625 ◽

Cited By ~ 38

Author(s):

M.-H. Tsai ◽

K. C. Hass

Keyword(s):

First Principles ◽

Platinum Surfaces ◽

No Chemisorption

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First-Principles-Based Kinetic Monte Carlo Simulation of the Structure Sensitivity of the Water–Gas Shift Reaction on Platinum Surfaces

The Journal of Physical Chemistry C ◽

10.1021/jp2071869 ◽

2011 ◽

Vol 115 (50) ◽

pp. 24750-24762 ◽

Cited By ~ 79

Author(s):

Michail Stamatakis ◽

Ying Chen ◽

Dionisios G. Vlachos

Keyword(s):

Monte Carlo Simulation ◽

Monte Carlo ◽

First Principles ◽

Kinetic Monte Carlo ◽

Structure Sensitivity ◽

Water Gas Shift ◽

Water Gas Shift Reaction ◽

Platinum Surfaces ◽

Shift Reaction ◽

Water Gas

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First-principles calculations of metal surfaces. II. Properties of low-index platinum surfaces toward understanding electron emission

Physical Review B ◽

10.1103/physrevb.103.195427 ◽

2021 ◽

Vol 103 (19) ◽

Author(s):

Peter A. Schultz ◽

Harold P. Hjalmarson ◽

Morgann Berg ◽

Ezra Bussmann ◽

David A. Scrymgeour ◽

...

Keyword(s):

Electron Emission ◽

First Principles ◽

Metal Surfaces ◽

First Principles Calculations ◽

Platinum Surfaces

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Ultrathin Platinum Crystal Surface Structures

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100118849 ◽

1985 ◽

Vol 43 ◽

pp. 394-395

Author(s):

R. L. Hines

Keyword(s):

Crystal Surface ◽

Surface Structures ◽

Platinum Surface ◽

Platinum Surfaces ◽

Resolution Level ◽

Experimental Facilities ◽

Carbon Backing ◽

Mesh Grid ◽

Atom Layer

The importance of atom layer terraces or steps on platinum surfaces used for catalysis as discussed by Somorjai justifies an extensive investigation of the structure of platinum surfaces through electron microscopy at the atomic resolution level. Experimental and theoretical difficulties complicate the quantitative determination of platinum surface structures but qualitative observation of surface structures on platinum crystals is now possible with good experimental facilities.Ultrathin platinum crystals with nominal 111 orientation are prepared using the procedure reported by Hines without the application of a carbon backing layer. Platinum films with thicknesses of about ten atom layers are strong enough so that they can be mounted on grids to provide ultrathin platinum crystals for examination of surface structure. Crystals as thin as possible are desired to minimize the theoretical difficulties in analyzing image contrast to determine structure. With the current preparation procedures the crystals frequently cover complete openings on a 400 mesh grid.

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