Moiré pattern in scanning tunneling microscopy of monolayer graphite

1994 ◽  
Vol 50 (7) ◽  
pp. 4749-4755 ◽  
Author(s):  
Katsuyoshi Kobayashi
Nano Research ◽  
2013 ◽  
Vol 7 (1) ◽  
pp. 154-162 ◽  
Author(s):  
Nicolas Reckinger ◽  
Eloise Van Hooijdonk ◽  
Frédéric Joucken ◽  
Anastasia V. Tyurnina ◽  
Stéphane Lucas ◽  
...  

2012 ◽  
Vol 19 (04) ◽  
pp. 1250041 ◽  
Author(s):  
Q. LIAO ◽  
H. J. ZHANG ◽  
K. WU ◽  
H. Y. LI ◽  
S. N. BAO ◽  
...  

Scanning tunneling microscopy is used to study intercalation of cobalt underneath a graphene layer on Ru(0001) . Deposition of cobalt on graphene/ Ru(0001) at 873 K leads to the intercalation of cobalt between the graphene layer and the Ru(0001) substrate, and the intercalation is associated with Co diffusion at steps and defects. The morphology of graphene/ Co/Ru(0001) shows moiré pattern, as same as that of graphene/ Ru(0001) . The bright areas where Co islands exist are hcp regions of graphene/ Ru(0001) . The intercalated Co islands have a pseudomorphic structure superimposed on Ru(0001) .


2017 ◽  
Vol 204 ◽  
pp. 331-348 ◽  
Author(s):  
Saskia Spitzer ◽  
Oliver Helmle ◽  
Oliver Ochs ◽  
Joshua Horsley ◽  
Natalia Martsinovich ◽  
...  

Self-assembly of benzene-1,3,5-tricarboxylic acid (trimesic acid – TMA) monolayers at the alkanoic acid–graphite interface is revisited. Even though this archetypal model system for hydrogen bonded porous networks is particularly well studied, the analysis of routinely observed superperiodic contrast modulations known as moiré patterns lags significantly behind. Fundamental questions remain unanswered such as, are moiré periodicity and orientation always the same, i.e. is exclusively only one specific moiré pattern observed? What are the geometric relationships (superstructure matrices) between moiré, TMA, and graphite lattices? What affects the moiré pattern formation? Is there any influence from solvent, concentration, or thermal treatment? These basic questions are addressed via scanning tunneling microscopy experiments at the liquid–solid interface, revealing a variety of different moiré patterns. Interestingly, TMA and graphite lattices were always found to be ∼5° rotated with respect to each other. Consequently, the observed variation in the moiré patterns is attributed to minute deviations (<2°) from this preferred orientation. Quantitative analysis of moiré periods and orientations facilitates the determination of the TMA lattice parameter with picometer precision.


Author(s):  
H.-J. Cantow ◽  
H. Hillebrecht ◽  
S. Magonov ◽  
H. W. Rotter ◽  
G. Thiele

From X-ray analysis, the conclusions are drawn from averaged molecular informations. Thus, limitations are caused when analyzing systems whose symmetry is reduced due to interatomic interactions. In contrast, scanning tunneling microscopy (STM) directly images atomic scale surface electron density distribution, with a resolution up to fractions of Angstrom units. The crucial point is the correlation between the electron density distribution and the localization of individual atoms, which is reasonable in many cases. Thus, the use of STM images for crystal structure determination may be permitted. We tried to apply RuCl3 - a layered material with semiconductive properties - for such STM studies. From the X-ray analysis it has been assumed that α-form of this compound crystallizes in the monoclinic space group C2/m (AICI3 type). The chlorine atoms form an almost undistorted cubic closed package while Ru occupies 2/3 of the octahedral holes in every second layer building up a plane hexagon net (graphite net). Idealizing the arrangement of the chlorines a hexagonal symmetry would be expected. X-ray structure determination of isotypic compounds e.g. IrBr3 leads only to averaged positions of the metal atoms as there exist extended stacking faults of the metal layers.


Author(s):  
I. H. Musselman ◽  
R.-T. Chen ◽  
P. E. Russell

Scanning tunneling microscopy (STM) has been used to characterize the surface roughness of nonlinear optical (NLO) polymers. A review of STM of polymer surfaces is included in this volume. The NLO polymers are instrumental in the development of electrooptical waveguide devices, the most fundamental of which is the modulator. The most common modulator design is the Mach Zehnder interferometer, in which the input light is split into two legs and then recombined into a common output within the two dimensional waveguide. A π phase retardation, resulting in total light extinction at the output of the interferometer, can be achieved by changing the refractive index of one leg with respect to the other using the electrooptic effect. For best device performance, it is essential that the NLO polymer exhibit minimal surface roughness in order to reduce light scattering. Scanning tunneling microscopy, with its high lateral and vertical resolution, is capable of quantifying the NLO polymer surface roughness induced by processing. Results are presented below in which STM was used to measure the surface roughness of films produced by spin-coating NLO-active polymers onto silicon substrates.


Author(s):  
D. R. Denley

Scanning tunneling microscopy (STM) has recently been introduced as a promising tool for analyzing surface atomic structure. We have used STM for its extremely high resolution (especially the direction normal to surfaces) and its ability for imaging in ambient atmosphere. We have examined surfaces of metals, semiconductors, and molecules deposited on these materials to achieve atomic resolution in favorable cases.When the high resolution capability is coupled with digital data acquisition, it is simple to get quantitative information on surface texture. This is illustrated for the measurement of surface roughness of evaporated gold films as a function of deposition temperature and annealing time in Figure 1. These results show a clear trend for which the roughness, as well as the experimental deviance of the roughness is found to be minimal for evaporation at 300°C. It is also possible to contrast different measures of roughness.


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