Magnetic-susceptibility and specific-heat studies of spin-glass-like ordering in the pyrochlore compoundsR2Mo2O7(R=Y, Sm, or Gd)

1992 ◽  
Vol 46 (9) ◽  
pp. 5405-5411 ◽  
Author(s):  
N. P. Raju ◽  
E. Gmelin ◽  
R. K. Kremer
Materials ◽  
2021 ◽  
Vol 14 (22) ◽  
pp. 6785
Author(s):  
Evgeniya Vavilova ◽  
Timur Salikhov ◽  
Margarita Iakovleva ◽  
Tatyana Vasilchikova ◽  
Elena Zvereva ◽  
...  

The non-stoichiometric system Li0.8Ni0.6Sb0.4O2 is a Li-deficient derivative of the zigzag honeycomb antiferromagnet Li3Ni2SbO6. Structural and magnetic properties of Li0.8Ni0.6Sb0.4O2 were studied by means of X-ray diffraction, magnetic susceptibility, specific heat, and nuclear magnetic resonance measurements. Powder X-ray diffraction data shows the formation of a new phase, which is Sb-enriched and Li-deficient with respect to the structurally honeycomb-ordered Li3Ni2SbO6. This structural modification manifests in a drastic change of the magnetic properties in comparison to the stoichiometric partner. Bulk static (dc) magnetic susceptibility measurements show an overall antiferromagnetic interaction (Θ = −4 K) between Ni2+ spins (S = 1), while dynamic (ac) susceptibility reveals a transition into a spin glass state at a freezing temperature TSG ~ 8 K. These results were supported by the absence of the λ-anomaly in the specific heat Cp(T) down to 2 K. Moreover, combination of the bulk static susceptibility, heat capacity and 7Li NMR studies indicates a complicated temperature transformation of the magnetic system. We observe a development of a cluster spin glass, where the Ising-like Ni2+ magnetic moments demonstrate a 2D correlated slow short-range dynamics already at 12 K, whereas the formation of 3D short range static ordered clusters occurs far below the spin-glass freezing temperature at T ~ 4 K as it can be seen from the 7Li NMR spectrum.


1980 ◽  
Vol 22 (7) ◽  
pp. 3331-3343 ◽  
Author(s):  
Shoichi Nagata ◽  
R. R. Galazka ◽  
D. P. Mullin ◽  
H. Akbarzadeh ◽  
G. D. Khattak ◽  
...  

1981 ◽  
Vol 23 (7) ◽  
pp. 3553-3554 ◽  
Author(s):  
Gul Dad Khattak ◽  
C. D. Amarasekara ◽  
S. Nagata ◽  
R. R. Galazka ◽  
P. H. Keesom

2005 ◽  
Vol 72 (2) ◽  
Author(s):  
R. Lortz ◽  
Y. Wang ◽  
S. Abe ◽  
C. Meingast ◽  
Yu. B. Paderno ◽  
...  

1992 ◽  
Vol 82 (4) ◽  
pp. 630-633 ◽  
Author(s):  
T. Story ◽  
R.R. Gałązka ◽  
P.J.T. Eggenkamp ◽  
H.J.M. Swagten ◽  
W.J.M. de Jonge

Sign in / Sign up

Export Citation Format

Share Document