Volume Dependence of the Grüneisen Parameter of Alkali Halides

1971 ◽  
Vol 4 (6) ◽  
pp. 2041-2046 ◽  
Author(s):  
R. W. Roberts ◽  
R. Ruppin
Keyword(s):  
Alkali Halides ◽  
Grüneisen Parameter ◽  
Gruneisen Parameter ◽  
Volume Dependence

Theoretical Determination of Pressure-Volume-Temperature Relationship of Some Alkali Halides

2008 ◽  
Vol 272 ◽  
pp. 107-116
Author(s):  
Quan Liu
Keyword(s):  
Alkali Halides ◽  
Temperature Relationship ◽  
Grüneisen Parameter ◽  
Gruneisen Parameter ◽  
Volume Dependence ◽  
Compression Data ◽  
Experimental Values ◽  
Relationship Of ◽  
Good Agreement

The Chopelas-Boehler approximation for the volume dependence of the Anderson-Gruneisen parameter along isotherms and the new approximation for the volume dependence of the Anderson-Gruneisen parameter along isobars have been used to study the pressure-volume-temperature relationship for LiF, NaF and CsCl crystals up to a pressure of 90kbar and in the temperature range 298-1073K. The calculated values of compression data and experimental values are found to be in good agreement.

Volume dependence of superconducting state parameters of bismuth-based binary alloys: A pseudopotential approach

2019 ◽  
Vol 33 (32) ◽  
pp. 1950394
Author(s):  
Hiral Patel ◽  
Priyank Kumar ◽  
N. K. Bhatt ◽  
P. R. Vyas ◽  
V. B. Gohel
Keyword(s):  
Transition Temperature ◽  
Effective Interaction ◽  
Interaction Strength ◽  
Grüneisen Parameter ◽  
Phonon Coupling ◽  
Gruneisen Parameter ◽  
Volume Dependence ◽  
Electron Phonon Coupling ◽  
Strength Formula ◽  
Coulomb Pseudopotential

A comprehensive and systematic study of superconducting state parameters (SSPs) of Bi-based binary alloys of the form [Formula: see text] has been carried out in the framework of pseudopotential theory at different concentrations ([Formula: see text]) of impurity atom-[Formula: see text] in host atom Bi which varies from 0 to 1. Impurity atom [Formula: see text] has been replaced by In, Tl, Sb and Pb to form four alloy systems. The density-based local form of the pseudopotential proposed by Fiolhais et al. has been used in this study to compute SSPs such as electron–phonon coupling strength ([Formula: see text]), Coulomb pseudopotential ([Formula: see text]), transition temperature ([Formula: see text]), effective interaction strength ([Formula: see text] and isotopic effect parameter ([Formula: see text]) of Bi-based binary alloy systems. Computed results of SSPs of alloys under study are in good agreement with available experimental and other theoretical results. In order to investigate the effect of pressure on SSPs of alloys under study, a theoretical calculation of SSPs as a function of compressed volume is reported. The volume dependence of Debye temperature has been accounted by using Debye–Gruneisen model which involves the Gruneisen parameter. Thus, to describe the effect of pressure on SSPs accurately, the value of Gruneisen parameter should be as accurate as possible. But reported results of Gruneisen parameter in the literature are highly scattered. Due to this reason, we have used two sets of Gruneisen parameter obtained by different methods to understand its role in the computation of SSPs as a function of compressed volume. Further, critical volumes for all alloys at different concentration have been predicted at which electron–phonon coupling strength and Coulomb pseudopotential are equal ([Formula: see text]). At critical volume, superconductivity quenches where transition temperature, [Formula: see text], and effective interaction strength, [Formula: see text], become zero. It is observed that critical volumes predicted by all approaches used in this study are in excellent agreement with each other.

Pressure derivative of the melting temperature for some alkali halides

2010 ◽  
Vol 88 (3) ◽  
pp. 175-179
Author(s):  
Chuanhui Nie
Keyword(s):  
High Temperature ◽  
Melting Temperature ◽  
Close Agreement ◽  
Ambient Pressure ◽  
Alkali Halides ◽  
Grüneisen Parameter ◽  
Pressure Derivative ◽  
Gruneisen Parameter ◽  
Theory And Experiment

Assuming that the Anderson–Grüneisen parameter δT and the Grüneisen parameter γ are constant at high temperature and ambient pressure, we calculate the pressure derivative of melting temperature for some alkali halides (NaCl, NaBr, NaI, KCl, KBr, KI), and compare them with the results of other models. A close agreement between theory and experiment reveals the validity of the present work.

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