Crystal fields of lithium rare-earth tetrafluorides and multiplet splitting of the +3 rare-earth ions

2020 ◽  
Vol 102 (4) ◽  
Author(s):  
Leila Mollabashi ◽  
S. Jalali-Asadabadi
Keyword(s):  
Rare Earth ◽  
Rare Earth Ions ◽  
Multiplet Splitting ◽  
Crystal Fields

scholarly journals Lattice Location of Rare Earth Ions in Semiconductors: Interpretation and Limitations of Using g Values

2005 ◽  
Vol 866 ◽  
Author(s):  
David Carey
Keyword(s):  
Rare Earth ◽  
Crystal Field ◽  
Field Potential ◽  
Rare Earth Ions ◽  
Lattice Location ◽  
Paramagnetic Resonance ◽  
Cubic Symmetry ◽  
Crystal Fields ◽  
Valid Comparison ◽  
G Value

AbstractThe g values of rare earth ions obtained from either paramagnetic resonance or Zeeman measurements are often used to interpret the location and/or environment surrounding rare earth ions. In the case of centres with cubic symmetry the g value can be used to distinguish between substitutional and interstitial sites. For centres with less than cubic symmetry the average g value, taken as 1/3 trace of the g tensor, is often used as an indication of the lattice location and/or a measure of the strength of the local crystal field. This approach is widely used but is based on the assumption that the non-cubic terms in the total crystal field potential are small compared with the cubic crystal field. In this paper we have explored this assumption by calculating the principal g values in axial crystal fields for the Er3+ ion. We examine the limits over which the average g value approach is valid. Comparison is made with published results.

Spectra of Rare-Earth Ions in the Crystal Fields of Double Tungstates and Molybdates

1982 ◽  
Vol 110 (2) ◽  
pp. 417-422 ◽  
Author(s):  
B. Z. Malkin ◽  
A. A. Kaminskii ◽  
N. R. Agamalyan ◽  
L. A. Bumagina ◽  
T. I. Butaeva
Keyword(s):  
Rare Earth ◽  
Rare Earth Ions ◽  
Crystal Fields ◽  
Double Tungstates

Crystal Fields at Rare‐Earth Ions

1965 ◽  
Vol 42 (1) ◽  
pp. 377-390 ◽  
Author(s):  
Gerald Burns
Keyword(s):  
Rare Earth ◽  
Rare Earth Ions ◽  
Crystal Fields

Shielding and Crystal Fields at Rare-Earth Ions

1962 ◽  
Vol 128 (5) ◽  
pp. 2121-2130 ◽  
Author(s):  
Gerald Burns
Keyword(s):  
Rare Earth ◽  
Rare Earth Ions ◽  
Crystal Fields

scholarly journals Crystal fields at light rare-earth ions in Y and Lu

1978 ◽  
Vol 17 (11) ◽  
pp. 4454-4460 ◽  
Author(s):  
P. Touborg ◽  
R. Nevald ◽  
T. Johansson
Keyword(s):  
Rare Earth ◽  
Rare Earth Ions ◽  
Light Rare Earth ◽  
Crystal Fields
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