scholarly journals Melting curve and phase diagram of vanadium under high-pressure and high-temperature conditions

2019 ◽  
Vol 100 (9) ◽  
Author(s):  
D. Errandonea ◽  
S. G. MacLeod ◽  
L. Burakovsky ◽  
D. Santamaria-Perez ◽  
J. E. Proctor ◽  
...  
2014 ◽  
Vol 70 (a1) ◽  
pp. C979-C979
Author(s):  
Arthur Haozhe Liu ◽  
Lisa Luhong Wang ◽  
Lingping Kong

The rich phase diagrams from both relaxor and normal ferroelectrics under high pressure, stimulate us to study the pressure effect on the relaxor-PbTiO3 (PT) systems, to check whether the high pressure cubic structure will turn to low symmetry structure upon strong compression is the common behaviors for relaxor ferroelectrics materials. Furthermore, a complete phase diagram study of pressure-temperature effect on structure will allow us to explore the limitation on applications of relaxor-PT material devices under harsh environment involving in high pressure and high temperature conditions. Structure evolution and phase transition of several solid solution ferroelectrics, such as Pb(YbNb)O3-PT (PYN-PT), have been studied using in situ synchrotron X-ray diffraction (XRD) and Raman spectroscopy techniques under high pressure and high temperature conditions. XRD results show pressure induced phase transitions to a cubic phase, while the persistence of Raman spectroscopy in the full pressure range indicates its local distortion. A pressure-temperature phase diagram is further constructed to determine the stability region of the ferroelectric phase. The results provide useful guidance for the applications of this kind of high Curie temperature ferroelectric crystal under extreme conditions, and extra clue to synthesis of ferroelectric materials with tailored properties.


1998 ◽  
Vol 278-281 ◽  
pp. 612-617 ◽  
Author(s):  
Bogdan F. Palosz ◽  
Svetlana Stelmakh ◽  
Stanislaw Gierlotka ◽  
M. Aloszyna ◽  
Roman Pielaszek ◽  
...  

2005 ◽  
Vol 71 (704) ◽  
pp. 1183-1189 ◽  
Author(s):  
Hiroyuki NISHIDA ◽  
Takuma OGAWA ◽  
Eiji WAKISAKA ◽  
Takeshi TACHIBANA

2004 ◽  
Vol 24 (1) ◽  
pp. 111-116 ◽  
Author(s):  
G. Ferlat ◽  
D. Martínez-García ◽  
A. San Miguel ◽  
A. Aouizerat ◽  
V. Muñoz-Sanjosé

2004 ◽  
Vol 59 (2) ◽  
pp. 202-215 ◽  
Author(s):  
Holger Emme ◽  
Tanja Nikelski ◽  
Thomas Schleid ◽  
Rainer Pöttgen ◽  
Manfred Heinrich Möller ◽  
...  

The new orthorhombic meta-oxoborates RE(BO2)3 (≡REB3O6) (RE = Dy-Lu) have been synthesized under high-pressure and high-temperature conditions in a Walker-type multianvil apparatus at 7.5 GPa and 1100 °C. They are isotypic to the known ambient pressure phase Tb(BO2)3, space group Pnma. In contrast to Dy(BO2)3, which was also obtained in small amounts under high-temperature conditions, the preparation of the higher orthorhombic homologues RE(BO2)3 (RE = Ho-Lu) was only possible using high-pressure. The meta-oxoborates RE(BO2)3 (RE = Dy-Er) were synthesized as pure products, whereas the orthorhombic phases with RE = Tm-Lu were only obtained as byproducts. With the exception of Yb(BO2)3 it was possible to establish single crystal data for all compounds. The results of temperature-resolved in-situ powder-diffraction measurements, DTA, IR-spectroscopic investigations, and magnetic properties are also presented.


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