X-ray Studies of the Thermal Expansion of Bismuth Single Crystals

1932 ◽  
Vol 40 (5) ◽  
pp. 643-661 ◽  
Author(s):  
Alexander Goetz ◽  
Rudolf C. Hergenrother
2019 ◽  
Vol 33 (23) ◽  
pp. 1950271 ◽  
Author(s):  
Y. I. Aliyev ◽  
Y. G. Asadov ◽  
A. O. Dashdemirov ◽  
R. D. Aliyeva ◽  
T. G. Naghiyev ◽  
...  

The Ag[Formula: see text]Cu[Formula: see text]Se and Ag[Formula: see text]Cu[Formula: see text]Se compounds have been synthesized and grown as single crystals. High-temperature X-ray diffraction method was used to study polymorphic transformations. It is shown that the Ag[Formula: see text]Cu[Formula: see text]Se crystals of high-temperature FCC modification are decomposed into Ag2Se and AgCuSe when the temperature decreases below T = 488 K and Ag[Formula: see text]Cu[Formula: see text]Se is decomposed into Cu2Se and AgCuSe when the temperature decreases below T = 540 K. Transformations in both compounds are reversible. Crystalline parameters are obtained and the temperature dependence of the lattice parameters for each phase is built.


Author(s):  
Eiken Haussühl ◽  
Siegfried Haussühl ◽  
Ekkehart Tillmanns

AbstractSingle crystals of the title compounds having optical quality and dimensions up to 60 mm have been grown from aqueous solutions. X-ray crystal structure analyses of K


X-ray measurements recently carried out by the author on the lattice expansion of silver and quartz showed that the coefficients of thermal expansion, over the ranges investigated, are the same as those observed for the specimen as a whole using optical methods. Goetz and Hergenrother, on the other hand, from X-ray measurements on the coefficients of thermal expansion of single crystals of bismuth, claimed to have found a large difference between values obtained by the two methods of measurement. A possible explanatiion of this that their accuracy is not sufficient to establish definitely the deviation of the X-ray measurements from the optical expansion curve. The author has since made X-ray measurements on the expansion of the bismuth lattice from room temperature to just below the melting point, and finds no evidence of such a discrepancy as Goetz and Hergenrother record.


Author(s):  
S. Haussühl ◽  
J. Schreuer

AbstractLarge single crystals of optical quality of betaine hydrogen dihydrogen iodate have been grown from aqueous solutions. An X-ray structure analysis yields space group


Author(s):  
J. Schreuer ◽  
T. Münch

AbstractLarge single crystals of optical quality of monoclinic ethylenediammonium bis(hydrogensuccinate) were grown from aqueous solutions. An X-ray structure analysis yielded space group


Author(s):  
S. Haussühl ◽  
J. Schreuer

AbstractLarge single crystals of optical quality of betaine hydrogen ammonium sulfate have been grown from aqueous solutions. An X-ray structure analysis yielded space group


Author(s):  
S. Haussühl ◽  
J. Schreuer

AbstractLarge single crystals of optical quality of (±)-tris(ethylenediamine)cobalt(III) nitrate have been grown from aequeous solutions. An X-ray structure analysis yielded space groupPyroelectric, dieletric, piezoelectric and elastic constants have been determined at room temperature. Additionally, we have studied the coefficients of thermal expansion and the thermoelastic constants in the range between 270 K and 350 K. The structure exhibits a nearly trigonal symmetry around the [unk]


Author(s):  
Armin Kirfel ◽  
H. Euler ◽  
B. Barbier ◽  
E. Hägele ◽  
Helmut Klapper

Single crystals of KLiCO


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