Temperature Dependence of the Structure of Liquid Indium

1966 ◽  
Vol 149 (1) ◽  
pp. 122-130 ◽  
Author(s):  
H. Ocken ◽  
C. N. J. Wagner
1991 ◽  
Vol 69 (9) ◽  
pp. 1394-1397 ◽  
Author(s):  
Peter J. Gardner ◽  
Steve R. Preston

The transport of gaseous In(I)Br in an argon carrier gas was studied in the temperature range 680 to 935 K by the modified entrainment method. Combination of the entrainment results with a literature equation for the total vapour pressure above the liquid gave the following expressions for the temperature dependence of the vapour pressures of the monomer (In2Br2) and dimer (In2Br2) respectively: [Formula: see text] ln T − 0.001164 ± 0.00021)T, (680 −950 K) and [Formula: see text] (680–810 K); p0 = 105 Pa. The dimer concentration is ca. 14% at 680 K and decreases to ca. 4% at 810 K. Key words: high temperature thermodynamics, indium(I) bromide, vaporization thermodynamics.


1999 ◽  
Vol 59 (2) ◽  
pp. 783-791 ◽  
Author(s):  
H. Tostmann ◽  
E. DiMasi ◽  
P. S. Pershan ◽  
B. M. Ocko ◽  
O. G. Shpyrko ◽  
...  

Author(s):  
Roman Bilyk ◽  
Uliana Liudkevych ◽  
Stepan Mudry

The structure of liquid gallium in a wide temperature range has been studied. Analysis of data obtained by diffraction method allowed us to make some conclusions about the structural features of the liquid gallium. In particular there is a clear asymmetry of the first maximum of the structure factor (SF) and existence of shoulder on its right hand side. Also the temperature dependence of structural factors for liquid gallium in terms of its heterogeneous structure was analyzed. Interpretation was carried out under the assumption that the structure of liquid gallium consists of clusters with different distribution of atoms, as well as different types of chemical bonds between atoms. The structural units are sensitive to temperature. Splitting of the structure factor main maximum on the Gaussian partial curves, which corresponded to certain structural units of the melt, was also performed. Each structural component of the melt reveals a different nature of the temperature dependence. It is also assumed that the partial peaks for each cluster are described by Gaussian functions.


1987 ◽  
Vol 97-98 ◽  
pp. 1251-1254 ◽  
Author(s):  
H. Neumann ◽  
W. Hoyer ◽  
W. Matz ◽  
M. Wobst

1992 ◽  
Vol 70 (11) ◽  
pp. 2699-2703 ◽  
Author(s):  
Peter J. Gardner ◽  
Steve R. Preston

The transport of gaseous In(I)I in an argon carrier gas was studied in the temperature range 723–887 K by the modified entrainment method. Combination of the entrainment results with a literature equation for the total vapour pressure above the liquid gave the following expressions for the temperature dependence of the vapour pressures of the monomer (InI) and dimer (In2I2) respectively: [Formula: see text] and [Formula: see text]; p0 = 105 Pa. The dimer concentration is ca. 2% and nearly constant from 720 to 810 K.


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