Magnetic Study of the Lighter Rare-Earth Ions in the Iron Garnets

1963 ◽  
Vol 131 (3) ◽  
pp. 1080-1082 ◽  
Author(s):  
S. Geller ◽  
H. J. Williams ◽  
R. C. Sherwood ◽  
J. P. Remeika ◽  
G. P. Espinosa
1962 ◽  
Vol 33 (3) ◽  
pp. 1259-1260 ◽  
Author(s):  
B. A. Calhoun ◽  
M. J. Freiser ◽  
R. F. Penoyer

1965 ◽  
Vol 137 (3A) ◽  
pp. A1034-A1038 ◽  
Author(s):  
S. Geller ◽  
J. P. Remeika ◽  
R. C. Sherwood ◽  
H. J. Williams ◽  
G. P. Espinosa

2014 ◽  
Vol 43 (15) ◽  
pp. 5893-5898 ◽  
Author(s):  
Rina Murakami ◽  
Takeshi Nakamura ◽  
Takayuki Ishida

The X-ray crystal structure of TEMPO-coordinated lanthanide compounds was determined for the first time. The magnetic study clarified that [Gd(hfac)3(TEMPO)2] behaved as a ground Stotal = 7/2 species. The La and Y analogues showed the superexchange interactions across the diamagnetic ions.


1964 ◽  
Vol 11 (3) ◽  
pp. 195-196 ◽  
Author(s):  
M.E. Caspari ◽  
A. Koicki ◽  
S. Koicki ◽  
G.T. Wood

Author(s):  
N. M. P. Low ◽  
L. E. Brosselard

There has been considerable interest over the past several years in materials capable of converting infrared radiation to visible light by means of sequential excitation in two or more steps. Several rare-earth trifluorides (LaF3, YF3, GdF3, and LuF3) containing a small amount of other trivalent rare-earth ions (Yb3+ and Er3+, or Ho3+, or Tm3+) have been found to exhibit such phenomenon. The methods of preparation of these rare-earth fluorides in the crystalline solid form generally involve a co-precipitation process and a subsequent solid state reaction at elevated temperatures. This investigation was undertaken to examine the morphological features of both the precipitated and the thermally treated fluoride powders by both transmission and scanning electron microscopy.Rare-earth oxides of stoichiometric composition were dissolved in nitric acid and the mixed rare-earth fluoride was then coprecipitated out as fine granules by the addition of excess hydrofluoric acid. The precipitated rare-earth fluorides were washed with water, separated from the aqueous solution, and oven-dried.


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