scholarly journals A 2D Metal Compound Shows a Superconducting Surprise

Physics ◽  
2020 ◽  
Vol 13 ◽  
Author(s):  
Rachel Berkowitz
Keyword(s):  
Metal Compound

Modeling fine particles and alkali metal compound behavior in a kraft recovery boiler

TAPPI Journal ◽  
2012 ◽  
Vol 11 (7) ◽  
pp. 9-14 ◽  
Author(s):  
AINO LEPPÄNEN ◽  
ERKKI VÄLIMÄKI ◽  
ANTTI OKSANEN
Keyword(s):  
Alkali Metal ◽  
Computational Models ◽  
Fine Particles ◽  
Black Liquor ◽  
Melting Behavior ◽  
Metal Compound ◽  
Effect Of Temperature ◽  
Particle Model ◽  
Boiler Furnace ◽  
Recovery Boiler

Under certain conditions, ash in black liquor forms a locally corrosive environment in a kraft recovery boiler. The ash also might cause efficiency losses and even boiler shutdown because of plugging of the flue gas passages. The most troublesome compounds in a fuel such as black liquor are potassium and chlorine because they change the melting behavior of the ash. Fouling and corrosion of the kraft recovery boiler have been researched extensively, but few computational models have been developed to deal with the subject. This report describes a computational fluid dynamics-based method for modeling the reactions between alkali metal compounds and for the formation of fine fume particles in a kraft recovery boiler furnace. The modeling method is developed from ANSYS/FLUENT software and its Fine Particle Model extension. We used the method to examine gaseous alkali metal compound and fine fume particle distributions in a kraft recovery boiler furnace. The effect of temperature and the boiler design on these variables, for example, can be predicted with the model. We also present some preliminary results obtained with the model. When the model is developed further, it can be extended to the superheater area of the kraft recovery boiler. This will give new insight into the variables that increase or decrease fouling and corrosion

Catalytic Activity of Binary and Triple Systems Based on Redox Inactive Metal Compound, LiSt and Additives of Monodentate Ligands-Modifiers: DMF, HMPA and PhOH, in Selective Ethylbenzene Oxidation with Dioxygen

2016 ◽  
Vol 10 (3) ◽  
pp. 259-270
Author(s):  
Ludmila Matienko ◽  
◽  
Larisa Mosolova ◽  
Vladimir Binyukov ◽  
Gennady Zaikov ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Triple System ◽  
Metal Compound ◽  
Ethylbenzene Oxidation ◽  
Catalytic Systems ◽  
Triple Systems ◽  
Lithium Compound ◽  
Mechanism Of Catalysis ◽  
Monodentate Ligands

Mechanism of catalysis with binary and triple catalytic systems based on redox inactive metal (lithium) compound {LiSt+L2} and {LiSt+L2+PhOH} (L2=DMF or HMPA), in the selective ethylbenzene oxidation by dioxygen into -phenylethyl hydroperoxide is researched. The results are compared with catalysis by nickel-lithium triple system {NiII(acac)2+LiSt+PhOH} in selective ethylbenzene oxidation to PEH. The role of H-bonding in mechanism of catalysis is discussed. The possibility of the stable supramolecular nanostructures formation on the basis of triple systems, {LiSt+L2+PhOH}, due to intermolecular H-bonds, is researched with the AFM method.

Polymers contamination by heavy metal compounds

2002 ◽  
Vol 56 (11) ◽  
pp. 483-488
Author(s):  
Sasa Jovanic ◽  
Dragoslav Stoiljkovic ◽  
Ivanka Popovic
Keyword(s):  
Heavy Metal ◽  
Aqueous Medium ◽  
Metal Compound ◽  
Medium Temperature ◽  
Metal Compounds ◽  
Metal Type ◽  
Copper Manganese ◽  
Increasing Temperature

The contamination of important synthetic (surface unmodified) polymers by various heavy metal compounds (such as copper, manganese and lead) in aqueous medium was investigated in this study. The influence of the pH of the aqueous medium, temperature and metal type on contamination was investigated during a 10 day period. It was found that increasing pH contributed to higher polymer contamination (at higher pH 100 times for copper and up to 400 times for lead), as well as contact with easily penetrable substances. Increasing temperature decreased contamination by the metal compound for PELD and PET which was not the case for PEHD and PR.

Research on high-temperature oxidation resistance, hot forming ability, and microstructure of Al–Si–Cu coating for 22MnB5 steel

2021 ◽  
Vol 40 (1) ◽  
pp. 397-409
Author(s):  
Ziliu Xiong ◽  
Zhangguo Lin ◽  
Jianjun Qi ◽  
Li Sun ◽  
Guangxin Wu ◽  
...  
Keyword(s):  
Surface Layer ◽  
High Temperature ◽  
Oxidation Resistance ◽  
High Temperature Oxidation ◽  
Hot Stamping ◽  
Optical Microscope ◽  
Hot Forming ◽  
Metal Compound ◽  
Temperature Oxidation ◽  
Substrate Steel

Abstract High-temperature oxidation resistance, hot formability, element distribution, and microstructure of Al-10% Si-(0.5–3.0%)Cu coating were investigated by means of glow discharge spectroscopy, optical microscope, scanning electron microscope, and energy-dispersive spectroscopy. Results show that the addition of Cu can increase high-temperature oxidation resistance above 950°C and improve hot formability so that no crack spreads into substrate steel as hot forming at 33.3% strain. Oxidation film structure is continual and compacting, and Si highly concentrates in the surface layer. The distribution of Cu has skin effect with peaking content 8.2% in the surface layer. After hot stamping, Al and Si diffuse into substrate steel, and Cu diffuses from inner to outer coating. Al–Si–Cu coating has smoother surface, straighter diffusion layer, and finer metal compound than Al–Si coating. Surface and diffusion layers are identified as aluminum oxide, Si-rich, and Cu phase and Al7SiFe2, Al3Fe, and CuAl3, respectively. Al-rich phase and the metal compound are composed of α-Al dissolving Fe, Si, and Cu and Al–Si matrix, Cu3Al, respectively.

Actuation of Model Phalanges by Ion Polymer Metal Compound

2012 ◽  
Vol 79 ◽  
pp. 69-74
Author(s):  
Tadashi Ihara ◽  
Taro Nakamura ◽  
Kinji Asaka
Keyword(s):  
Artificial Muscle ◽  
Fast Response ◽  
Metal Compound ◽  
Opening Angle ◽  
Prototype Model ◽  
Small Force ◽  
Polymer Metal ◽  
Function Generators ◽  
And Function ◽  
Contraction And Expansion

We have fabricated a prototype model artificial muscle that drives model phalanges in water with ion polymer metal compound (IPMC) which generates relatively large displacement with fast response but generates relatively small force. We have developed IPMC of greater thickness of up to 600 µm than conventional Nafion 117 based IPMC of 200 µm which enabled to generate greater force. In fabricating IPMC Nafion R-1100 resin was heat-pressed at 185 °C with 20-30 MPa. The thickness of IPMC could be adjusted by changing the amount of resin, pressure, and time to heat-press. Fabricated IPMC was then cut in shapes and an electrode was attached on the surface of IPMC. The device was used as an artificial muscle type actuator which was fabricated in a shape that bridges two conjoining bones, and controls opening angle of the bones that mimics contraction and expansion motion of the muscle. Bipolar power supply and function generators were used to drive IPMC membranes attached to the model phalanges.

Mechanism of Alkali Metal Compound-Promoted Growth of Monolayer MoS2: Eutectic Intermediates

2019 ◽  
Vol 31 (3) ◽  
pp. 873-880 ◽  
Author(s):  
Peng Wang ◽  
Jiayu Lei ◽  
Jiafan Qu ◽  
Shengyong Cao ◽  
Hu Jiang ◽  
...  
Keyword(s):  
Alkali Metal ◽  
Metal Compound ◽  
Monolayer Mos2
Sign in / Sign up

Export Citation Format

Share Document