scholarly journals Hummingbird iridescence: an unsuspected structural diversity influences colouration at multiple scales

2019 ◽  
Author(s):  
Hugo Gruson ◽  
Marianne Elias ◽  
Christine Andraud ◽  
Chakib Djediat ◽  
Serge Berthier ◽  
...  
Keyword(s):  
Multiple Scales ◽  
Interdisciplinary Approach ◽  
Structural Diversity ◽  
Structural Features ◽  
Optical Systems ◽  
Evolutionary Transitions ◽  
Layer Width ◽  
Novel Approach ◽  
Single Colour ◽  
Angular Dependency

AbstractIridescent colours are colours that change depending on the angle of illumination or observation. They are produced when light is reflected by multilayer structures or diffracted by gratings. While this phenomenon is well understood for simple optical systems, it remains unclear how complex biological structures interact with light to produce iridescence. There are very few comparative studies at interspecific level (often focusing on a single colour patch for each species), resulting in an underestimation of structure diversity. Using an interdisciplinary approach combining physics and biology, we here quantify the colour and structure of 36 hummingbirds species evenly distributed across the phylogeny. We explore at least 2 patches per species, which are assumed to be under different selective regimes. For each patch, we measure structural features (number of layers, layer width, irregularity, spacing, etc.) of the feathers at different scales using both optical and electronic microscopy and we measure colour using a novel approach we developed to encompass the full complexity of iridescence, including its angular dependency. We discover an unsuspected diversity of structures producing iridescence in hummingbirds. We also study the effect of several structural features on the colour of the resulting signal, using both an empirical and modelling approach. Our findings demonstrate the need to take into account multiple patches per species and suggest possible evolutionary pressures causing the evolutionary transitions from one melanosome type to another.

scholarly journals Copper(II) 2,2-Bis(Hydroxymethyl)Propionate Coordination Compounds with Hexamethylenetetramine: From Mononuclear Complex to One-Dimensional Coordination Polymer

Molecules ◽  
2021 ◽  
Vol 26 (11) ◽  
pp. 3358
Author(s):  
Sadaf Rauf ◽  
Agata Trzesowska-Kruszynska ◽  
Tomasz Sierański ◽  
Marcin Świątkowski
Keyword(s):  
Coordination Polymer ◽  
Coordination Compounds ◽  
Structural Diversity ◽  
Structural Features ◽  
Mononuclear Complex ◽  
Molar Ratio ◽  
One Dimensional ◽  
1D Coordination Polymer ◽  
Copper Coordination ◽  
Stretching Vibrations

Three new copper coordination compounds derived from 2,2-bis(hydroxymethyl)propionic acid (dmpa) and hexamethylenetetramine (hmta) were obtained and their crystal structures were determined. The stoichiometry of the reagents applied in the syntheses reflects the metal to ligand molar ratio in the formed solid products. Due to the multiple coordination modes of the used ligands, wide structural diversity was achieved among synthesized compounds, i.e., mononuclear [Cu(dmp)2(hmta)2(H2O)] (1), dinuclear [Cu2(dmp)4(hmta)2] (2), and 1D coordination polymer [Cu2(dmp)4(hmta)]n (3). Their supramolecular structures are governed by O—H•••O and O—H•••N hydrogen bonds. The compounds were characterized in terms of absorption (UV-Vis and IR) and thermal properties. The relationships between structural features and properties were discussed in detail. Owing to discrepancies in the coordination mode of a dmp ligand, bidentate chelating in 1, and bidentate bridging in 2 and 3, there is a noticeable change in the position of the bands corresponding to the stretching vibrations of the carboxylate group in the IR spectra. The differences in the structures of the compounds are also reflected in the nature and position of the UV-Vis absorption maxima, which are located at lower wavelengths for 1.

scholarly journals Emulating Software-Defined Disaggregated Optical Networks in a Containerized Framework

2021 ◽  
Vol 11 (5) ◽  
pp. 2081
Author(s):  
Francisco-Javier Moreno-Muro ◽  
Miquel Garrich ◽  
Ignacio Iglesias-Castreño ◽  
Safaa Zahir ◽  
Pablo Pavón-Mariño
Keyword(s):  
Optical Networks ◽  
Transport Infrastructure ◽  
Optical Systems ◽  
Traffic Demand ◽  
Novel Approach ◽  
Infrastructure Project ◽  
Optical Layer ◽  
Optical Domain ◽  
Control And Management ◽  
Remote Communications

Telecom operators’ infrastructure is undergoing high pressure to keep the pace with the traffic demand generated by the societal need of remote communications, bandwidth-hungry applications, and the fulfilment of 5G requirements. Software-defined networking (SDN) entered in scene decoupling the data-plane forwarding actions from the control-plane decisions, hence boosting network programmability and innovation. Optical networks are also capitalizing on SDN benefits jointly with a disaggregation trend that holds the promise of overcoming traditional vendor-locked island limitations. In this work, we present our framework for disaggregated optical networks that leverages on SDN and container-based management for a realistic emulation of deployment scenarios. Our proposal relies on Kubernetes for the containers’ control and management, while employing the NETCONF protocol for the interaction with the light-weight software entities, i.e., agents, which govern the emulated optical devices. Remarkably, our agents’ structure relies on components that offer high versatility for accommodating the wide variety of components and systems in the optical domain. We showcase our proposal with the emulation of an 18-node European topology employing Cassini-compliant optical models, i.e., a state-of-the-art optical transponder proposed in the Telecom Infrastructure Project. The combination of our versatile framework based on containerized entities, the automatic creation of agents and the optical-layer characteristics represents a novel approach suitable for operationally complex carrier-grade transport infrastructure with SDN-based disaggregated optical systems.

scholarly journals 1,3-Diketone Calix[4]arene Derivatives—A New Type of Versatile Ligands for Metal Complexes and Nanoparticles

Molecules ◽  
2021 ◽  
Vol 26 (5) ◽  
pp. 1214
Author(s):  
Sergey N. Podyachev ◽  
Rustem R. Zairov ◽  
Asiya R. Mustafina
Keyword(s):  
Structural Diversity ◽  
Building Blocks ◽  
Structural Features ◽  
Structure Property ◽  
One Pot ◽  
Arene Ligands ◽  
Structure Property Relationships ◽  
New Type ◽  
Synthetic Routes ◽  
Magnetic Resonance Imaging Mri

The present review is aimed at highlighting outlooks for cyclophanic 1,3-diketones as a new type of versatile ligands and building blocks of the nanomaterial for sensing and bioimaging. Thus, the main synthetic routes for achieving the structural diversity of cyclophanic 1,3-diketones are discussed. The structural diversity is demonstrated by variation of both cyclophanic backbones (calix[4]arene, calix[4]resorcinarene and thiacalix[4]arene) and embedding of different substituents onto lower or upper macrocyclic rims. The structural features of the cyclophanic 1,3-diketones are correlated with their ability to form lanthanide complexes exhibiting both lanthanide-centered luminescence and magnetic relaxivity parameters convenient for contrast effect in magnetic resonance imaging (MRI). The revealed structure–property relationships and the applicability of facile one-pot transformation of the complexes to hydrophilic nanoparticles demonstrates the advantages of 1,3-diketone calix[4]arene ligands and their complexes in developing of nanomaterials for sensing and bioimaging.

scholarly journals Three-Dimensional Structures of Carbohydrates and Where to Find Them

2020 ◽  
Vol 21 (20) ◽  
pp. 7702 ◽  
Author(s):  
Sofya I. Scherbinina ◽  
Philip V. Toukach
Keyword(s):  
Experimental Data ◽  
Molecular Modeling ◽  
Computational Methods ◽  
Three Dimensional ◽  
Structural Diversity ◽  
Structural Data ◽  
Structural Features ◽  
Data Validation ◽  
Data Generation ◽  
Efficient Treatment

Analysis and systematization of accumulated data on carbohydrate structural diversity is a subject of great interest for structural glycobiology. Despite being a challenging task, development of computational methods for efficient treatment and management of spatial (3D) structural features of carbohydrates breaks new ground in modern glycoscience. This review is dedicated to approaches of chemo- and glyco-informatics towards 3D structural data generation, deposition and processing in regard to carbohydrates and their derivatives. Databases, molecular modeling and experimental data validation services, and structure visualization facilities developed for last five years are reviewed.

A Micro-Architectural Based Structural Model for Elastomeric Electrospun Scaffolds

2010 ◽  
Author(s):  
Antonio D’Amore ◽  
John A. Stella ◽  
David E. Schmidt ◽  
William R. Wagner ◽  
Michael S. Sacks
Keyword(s):  
Tissue Engineering ◽  
Structural Model ◽  
Mechanical Response ◽  
Multiple Scales ◽  
Sem Images ◽  
Form Complex ◽  
Novel Approach ◽  
Structural Deformations ◽  
Mechanical Models ◽  
Specific Tissue

Interest in electrospun polymeric nano-microfibers for tissue engineering applications has rapidly grown during the last decade. In spite of this technique’s flexibility and ability to form complex fiber assemblies, additional studies are required to elucidate how the fibrous microstructure translates into specific tissue (or meso-scale) level mechanical behavior. Deterministic structural models can quantify how key structures contribute to the mechanical response as a function of bulk deformation across multiple scales, as well as provide a better understanding of cellular mechanical response to local micro-structural deformations. Our ultimate aim is to utilize such models to assist tissue engineering scaffold design. In the current work, we present a novel approach to automatically quantify key micro-architectural descriptors (fiber overlaps, connectivity, orientation, and diameter) from SEM images of electrospun poly (ester urethane) urea (PEUU) to recreate statistically equivalent scaffold mechanical models. An appropriate representative volume element (RVE) size was determined by quantifying the point of stabilization of the architectural descriptors over image areas of increasing size. Material models were then generated specifying: fiber overlap density, fiber orientation, connectivity and fiber diameter. Macro-meso mechanical response was predicted via FEM simulations.

scholarly journals Unimodal Relationships of Understory Alpha and Beta Diversity along Chronosequence in Coppiced and Unmanaged Beech Forests

Diversity ◽  
2020 ◽  
Vol 12 (3) ◽  
pp. 101 ◽  
Author(s):  
Sándor Bartha ◽  
Roberto Canullo ◽  
Stefano Chelli ◽  
Giandiego Campetella
Keyword(s):  
Beta Diversity ◽  
Management Practices ◽  
Multiple Scales ◽  
Forest Succession ◽  
Spatial Scales ◽  
Alpha Diversity ◽  
Structural Diversity ◽  
Diversity Indices ◽  
Alpha And Beta Diversity ◽  
Coppice Management

Patterns of diversity across spatial scales in forest successions are being overlooked, despite their importance for developing sustainable management practices. Here, we tested the recently proposed U-shaped biodiversity model of forest succession. A chronosequence of 11 stands spanning from 5 to 400 years since the last disturbance was used. Understory species presence was recorded along 200 m long transects of 20 × 20 cm quadrates. Alpha diversity (species richness, Shannon and Simpson diversity indices) and three types of beta diversity indices were assessed at multiple scales. Beta diversity was expressed by a) spatial compositional variability (number and diversity of species combinations), b) pairwise spatial turnover (between plots Sorensen, Jaccard, and Bray–Curtis dissimilarity), and c) spatial variability coefficients (CV% of alpha diversity measures). Our results supported the U-shaped model for both alpha and beta diversity. The strongest differences appeared between active and abandoned coppices. The maximum beta diversity emerged at characteristic scales of 2 m in young coppices and 10 m in later successional stages. We conclude that traditional coppice management maintains high structural diversity and heterogeneity in the understory. The similarly high beta diversities in active coppices and old-growth forests suggest the presence of microhabitats for specialist species of high conservation value.

Novel approach for exceeding the resolving power of optical systems

1999 ◽  
Author(s):  
Zeev Zalevsky ◽  
David Mendlovic ◽  
Adolf W. Lohmann ◽  
Gal Shabtay
Keyword(s):  
Resolving Power ◽  
Optical Systems ◽  
Novel Approach

A HYBRID SCHEME FOR HANDPRINTED NUMERAL RECOGNITION BASED ON A SELF-ORGANIZING NETWORK AND MLP ClASSIFIERS

2002 ◽  
Vol 16 (07) ◽  
pp. 845-864 ◽  
Author(s):  
UJJWAL BHATTACHARYA ◽  
TANMOY KANTI DAS ◽  
AMITAVA DATTA ◽  
SWAPAN KUMAR PARUI ◽  
BIDYUT BARAN CHAUDHURI
Keyword(s):  
Recognition Rate ◽  
Structural Features ◽  
Data Set ◽  
Novel Approach ◽  
Tree Classifier ◽  
Sample Data ◽  
Validation Set ◽  
Numeral Recognition ◽  
Correct Recognition Rate ◽  
Self Organizing

This paper proposes a novel approach to automatic recognition of handprinted Bangla (an Indian script) numerals. A modified Topology Adaptive Self-Organizing Neural Network is proposed to extract a vector skeleton from a binary numeral image. Simple heuristics are considered to prune artifacts, if any, in such a skeletal shape. Certain topological and structural features like loops, junctions, positions of terminal nodes, etc. are used along with a hierarchical tree classifier to classify handwritten numerals into smaller subgroups. Multilayer perceptron (MLP) networks are then employed to uniquely classify the numerals belonging to each subgroup. The system is trained using a sample data set of 1800 numerals and we have obtained 93.26% correct recognition rate and 1.71% rejection on a separate test set of another 7760 samples. In addition, a validation set consisting of 1440 samples has been used to determine the termination of the training algorithm of the MLP networks. The proposed scheme is sufficiently robust with respect to considerable object noise.

Construction and modulation of structural diversity in acylamide-MOFs

CrystEngComm ◽  
2014 ◽  
Vol 16 (25) ◽  
pp. 5608-5618 ◽  
Author(s):  
Shu-Yun Huang ◽  
Jian-Qiang Li ◽  
Shu-Juan Liu ◽  
Yang Ning ◽  
Li-Na Meng ◽  
...  
Keyword(s):  
Structural Diversity ◽  
Structural Features ◽  
Synthesis Conditions

Under different synthesis conditions, a series of compounds based on the L ligand are obtained. The resulting compounds, 1–7, show different structural features, involving interpenetrating, interlocked, puncturing, and pillared-layered frameworks.

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