scholarly journals On the effect of carbon nanotubes on properties of liquid crystals

Author(s):  
Stefan Schymura ◽  
Giusy Scalia

Liquid crystals (LCs), with their fluidity and self-organization, are attractive hosts for the dispersion and manipulation of macro- and nanoparticles, allowing the realization of their ordered assemblies. In addition, new functional materials can be created owing to the particle properties. Among the nanoparticles, carbon nanotubes (CNTs) stand out for their exceptional electrical, thermal and mechanical properties. While LCs can be used for manipulating CNTs, the nanotube properties are attractive also for influencing and tuning LC properties. In this paper, we discuss different aspects of the CNT–LC combination, briefly introducing their dispersion and interaction and then, more extensively, evaluating the CNT effect on selected properties of LCs relevant to display-related applications. We show that some previously reported improvements cannot be considered an intrinsic feature of CNT-doped LCs. In addition, we are also able to follow locally the Frederiks transition of CNT-doped LCs by Raman spectroscopy, revealing the direct effect of bundles of CNTs on LC reorientation.

2007 ◽  
Vol 49 (6) ◽  
pp. 702-707 ◽  
Author(s):  
A. V. Okotrub ◽  
N. F. Yudanov ◽  
V. M. Aleksashin ◽  
L. G. Bulusheva ◽  
O. A. Komarova ◽  
...  

2011 ◽  
Vol 528 (13-14) ◽  
pp. 4318-4324 ◽  
Author(s):  
Marcos N. dos Santos ◽  
Carlos V. Opelt ◽  
Fernando H. Lafratta ◽  
Carlos M. Lepienski ◽  
Sérgio H. Pezzin ◽  
...  

Materials ◽  
2020 ◽  
Vol 13 (18) ◽  
pp. 4149
Author(s):  
Laura M. Echeverry-Cardona ◽  
Natalia Álzate ◽  
Elisabeth Restrepo-Parra ◽  
Rogelio Ospina ◽  
Jorge H. Quintero-Orozco

This study shows the energy optimization and stabilization in the time of solutions composed of H2O + TX-100 + Multi-Wall Carbon Nanotubes (MWCNTs), used to improve the mechanical properties of Portland cement pastes. For developing this research, sonication energies at 90, 190, 290, 340, 390, 440, 490 and 590 J/g are applied to a colloidal substance (MWCNTs/TX-100 + H2O) with a molarity of 10 mM. Raman spectroscopy analyses showed that, for energies greater than 440 J/g, there are ruptures and fragmentation of the MWCNTs; meanwhile at energies below 390 J/g, better dispersions are obtained. The stability of the dispersion over time was evaluated over 13 weeks using UV-vis spectroscopy and Zeta Potential. With the most relevant data collected, sonication energies of 190, 390 and 490 J/g, at 10 mM were selected at the first and the fourth week of storage to obtain Portland cement specimens. Finally, we found an improvement of the mechanical properties of the samples built with Portland cement and solutions stored for one and four weeks; it can be concluded that the MWCNTs improved the hydration period.


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