Defect-induced spin disorder and magnetoresistance in single-crystal and polycrystal rare-earth manganite thin films

Author(s):  
J. E. Evetts ◽  
M. G. Blamire ◽  
N. D. Mathur ◽  
S. P. Isaac ◽  
B.-S. Teo ◽  
...  
2011 ◽  
Vol 26 (1-4) ◽  
pp. 44-55 ◽  
Author(s):  
Y. Romaguera-Barcelay ◽  
J. Agostinho Moreira ◽  
G. González-Aguilar ◽  
A. Almeida ◽  
J. P. Araujo ◽  
...  

1999 ◽  
Vol 74 (19) ◽  
pp. 2842-2844 ◽  
Author(s):  
V. Moshnyaga ◽  
I. Khoroshun ◽  
A. Sidorenko ◽  
P. Petrenko ◽  
A. Weidinger ◽  
...  

1971 ◽  
Vol 32 (C1) ◽  
pp. C1-1128-C1-1129
Author(s):  
H. R. CHILD ◽  
W. C. KOEHLER

2020 ◽  
Author(s):  
Elbruz Murat Baba ◽  
Jose Montero ◽  
Dmitrii Moldarev ◽  
Marcos V. Moro ◽  
Max Wolff ◽  
...  

<p>We report preferential orientation control in photochromic gadolinium oxyhydride (GdHO) thin films deposited by a two-step process. Gadolinium hydride (GdH<sub>2-x</sub>) films were grown by reactive magnetron sputtering, followed by oxidation in air. The preferential orientation, grain size, anion concentrations, and photochromic response of the films are strongly dependent on the deposition pressure. GdHO films show preferential orientation along the [100] direction and exhibit photochromism when synthesized at deposition pressures up to 5.8 Pa and. The photochromic contrast is larger than 20 % when the films are deposited below 2.8 Pa with 0.22 H<sub>2</sub>/Ar flow ratio. We argue that the degree of preferential orientation defines the oxygen concentration which is known to be a key parameter for photochromism in rare-earth oxyhydride thin films. The experimental observations described above are explained by the oxidation-induced decrease of the grain size as a result of the increase of the deposition pressure of the sputtering gas. </p>


2018 ◽  
Vol 10 (3) ◽  
pp. 03005-1-03005-6 ◽  
Author(s):  
Rupali Kulkarni ◽  
◽  
Amit Pawbake ◽  
Ravindra Waykar ◽  
Ashok Jadhawar ◽  
...  

2019 ◽  
Author(s):  
Xiao Han ◽  
Hoyun Won ◽  
Minyeong Choi ◽  
Liping Guo ◽  
Zhongqi Liu ◽  
...  

Coatings ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 724
Author(s):  
Sara Massardo ◽  
Alessandro Cingolani ◽  
Cristina Artini

Rare earth-doped ceria thin films are currently thoroughly studied to be used in miniaturized solid oxide cells, memristive devices and gas sensors. The employment in such different application fields derives from the most remarkable property of this material, namely ionic conductivity, occurring through the mobility of oxygen ions above a certain threshold temperature. This feature is in turn limited by the association of defects, which hinders the movement of ions through the lattice. In addition to these issues, ionic conductivity in thin films is dominated by the presence of the film/substrate interface, where a strain can arise as a consequence of lattice mismatch. A tensile strain, in particular, when not released through the occurrence of dislocations, enhances ionic conduction through the reduction of activation energy. Within this complex framework, high pressure X-ray diffraction investigations performed on the bulk material are of great help in estimating the bulk modulus of the material, and hence its compressibility, namely its tolerance toward the application of a compressive/tensile stress. In this review, an overview is given about the correlation between structure and transport properties in rare earth-doped ceria films, and the role of high pressure X-ray diffraction studies in the selection of the most proper compositions for the design of thin films.


2021 ◽  
pp. 138745
Author(s):  
Damir Dominko ◽  
Damir Starešinić ◽  
Katica Biljaković ◽  
Maja Đekić ◽  
Amra Salčinović Fetić ◽  
...  

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