scholarly journals Metal–organic frameworks of the MIL-101 family as heterogeneous single-site catalysts

2012 ◽  
Vol 468 (2143) ◽  
pp. 2017-2034 ◽  
Author(s):  
Nataliya V. Maksimchuk ◽  
Olga V. Zalomaeva ◽  
Igor Y. Skobelev ◽  
Konstantin A. Kovalenko ◽  
Vladimir P. Fedin ◽  
...  
Keyword(s):  
Review Paper ◽  
Metal Organic Frameworks ◽  
Coupling Reaction ◽  
Short Review ◽  
Single Site ◽  
Oxidation Of Hydrocarbons ◽  
Metal Organic ◽  
Catalytic Applications ◽  
Single Site Catalysts ◽  
Mesoporous Metal

In this short review paper, we survey our recent findings in the catalytic applications of mesoporous metal–organic frameworks of the MIL-101 family (Fe- and Cr-MIL-101) and demonstrate their potential in two types of liquid-phase processes: (i) selective oxidation of hydrocarbons with green oxidants—O 2 and tert -butyl hydroperoxide—and (ii) coupling reaction of organic oxides with CO 2 . A comparison with conventional single-site catalysts is made with special attention to issues of the catalyst's resistance to metal leaching and the nature of catalysis.

scholarly journals Metal–organic and covalent organic frameworks as single-site catalysts

2017 ◽  
Vol 46 (11) ◽  
pp. 3134-3184 ◽  
Author(s):  
S. M. J. Rogge ◽  
A. Bavykina ◽  
J. Hajek ◽  
H. Garcia ◽  
A. I. Olivos-Suarez ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Single Site ◽  
Covalent Organic Frameworks ◽  
Metal Organic ◽  
Single Site Catalysts

The potential of metal–organic frameworks (MOFs) and covalent organic frameworks (COFs) as platforms for the development of heterogeneous single-site catalysts is reviewed thoroughly.

S,O-Functionalized Metal–Organic Frameworks as Heterogeneous Single-Site Catalysts for the Oxidative Alkenylation of Arenes via C–H activation

ACS Catalysis ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 5077-5085 ◽  
Author(s):  
Niels Van Velthoven ◽  
Mickaël Henrion ◽  
Jesse Dallenes ◽  
Andraž Krajnc ◽  
Aram L. Bugaev ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Single Site ◽  
Metal Organic ◽  
Single Site Catalysts

scholarly journals Post‐synthetic Modification of DUT‐5‐based Metal Organic Frameworks for the Generation of Single‐site Catalysts and their Application in Selective Epoxidation Reactions

ChemCatChem ◽  
2020 ◽  
Vol 12 (4) ◽  
pp. 1134-1142 ◽  
Author(s):  
Ceylan Yildiz ◽  
Ksenia Kutonova ◽  
Simon Oßwald ◽  
Alba Titze‐Alonso ◽  
Johannes Bitzer ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Single Site ◽  
Metal Organic ◽  
Single Site Catalysts

ChemInform Abstract: Metal-Organic Frameworks of the MIL-101 Family as Heterogeneous Single-Site Catalysts

ChemInform ◽  
2012 ◽  
Vol 43 (43) ◽  
pp. no-no
Author(s):  
Nataliya V. Maksimchuk ◽  
Olga V. Zalomaeva ◽  
Igor Y. Skobelev ◽  
Konstantin A. Kovalenko ◽  
Vladimir P. Fedin ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Single Site ◽  
Metal Organic ◽  
Single Site Catalysts

scholarly journals Carbon Support Tuned Electrocatalytic Activity of Single-Site Metal-organic Framework toward Oxygen Reduction Reaction

2021 ◽  
Author(s):  
Wenjie Ma ◽  
Fei Wu ◽  
Ping Yu ◽  
Lanqun Mao
Keyword(s):  
Electrocatalytic Activity ◽  
Active Sites ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Structural Diversity ◽  
Carbon Support ◽  
Reduction Reaction ◽  
Single Site ◽  
Metal Organic ◽  
Single Site Catalysts

Metal-organic frameworks (MOFs) possess fantastic features such as structural diversity, tunable accessible pores and atomically dispersed active sites, holding tremendous potentials as high versatile platforms for fabricating single-site catalysts. The...

scholarly journals Metal-Organic Frameworks in Oxidation Catalysis with Hydrogen Peroxide

Catalysts ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 283
Author(s):  
Oxana Kholdeeva ◽  
Nataliya Maksimchuk
Keyword(s):  
Hydrogen Peroxide ◽  
Liquid Phase ◽  
Selective Oxidation ◽  
Metal Organic Frameworks ◽  
Short Review ◽  
Catalytic Performance ◽  
Oxidation Catalysis ◽  
Catalyst Stability ◽  
Aqueous Hydrogen Peroxide ◽  
Metal Organic

In recent years, metal–organic frameworks (MOFs) have received increasing attention as selective oxidation catalysts and supports for their construction. In this short review paper, we survey recent findings concerning use of MOFs in heterogeneous liquid-phase selective oxidation catalysis with the green oxidant–aqueous hydrogen peroxide. MOFs having outstanding thermal and chemical stability, such as Cr(III)-based MIL-101, Ti(IV)-based MIL-125, Zr(IV)-based UiO-66(67), Zn(II)-based ZIF-8, and some others, will be in the main focus of this work. The effects of the metal nature and MOF structure on catalytic activity and oxidation selectivity are analyzed and the mechanisms of hydrogen peroxide activation are discussed. In some cases, we also make an attempt to analyze relationships between liquid-phase adsorption properties of MOFs and peculiarities of their catalytic performance. Attempts of using MOFs as supports for construction of single-site catalysts through their modification with heterometals will be also addressed in relation to the use of such catalysts for activation of H2O2. Special attention is given to the critical issues of catalyst stability and reusability. The scope and limitations of MOF catalysts in H2O2-based selective oxidation are discussed.

Micro and mesoporous metal–organic frameworks for catalysis applications

2010 ◽  
Vol 39 (7) ◽  
pp. 1692-1694 ◽  
Author(s):  
Praveen K. Thallapally ◽  
Carlos A. Fernandez ◽  
Radha Kishan Motkuri ◽  
Satish K. Nune ◽  
Jun Liu ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Mesoporous Metal
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