Morphological instability in freezing colloidal suspensions

Author(s):  
Stephen S.L Peppin ◽  
M. Grae Worster ◽  
J.S Wettlaufer

We present a linear stability analysis of a planar ice interface during unidirectional solidification of a hard-sphere colloidal suspension. We find that the interface can become unstable due to constitutional supercooling, yielding a new mechanism for pattern formation in colloidal systems. The interfacial stability is shown to depend strongly on the size and concentration of the particles. Increasing the particle radius tends to stabilize the interface, while increasing the concentration has a destabilizing effect. Additional effects that may influence the stability and morphology of such a system are described.

1989 ◽  
Vol 155 ◽  
Author(s):  
Wan V. Shih ◽  
Wei-Heng Shih ◽  
Jun Liu ◽  
Ilhan A. Aksay

The stability of a colloidal suspension plays an important role in colloidal processing of materials. The stability of the colloidal fluid phase is especially vital in achieving high green densities. By colloidal fluid phase, we refer to a phase in which colloidal particles are well separated and free to move about by Brownian motion, By controlling parameters such as pH, salt concentration, and surfactants, one can achieve high packing (green) densities in the repulsive regime where the suspension is well dispersed as a colloidal fluid, and low green densities in the attractive regime where the suspensions are flocculated [1,2]. While there is increasing interest in using bimodal suspensions to improve green densities, neither the stability of a binary suspension as a colloidal fluid nor the stability effects on the green densities have been studied in depth as yet. Traditionally, the effect of using bimodal-particle-size distribution has only been considered in terms of geometrical packing developed by Furnas and others [3,4]. This model is a simple packing concept and is used and useful for hard sphere-like repulsive interparticle interactions. With the advances in powder technology, smaller and smaller particles are available for ceramic processing. Thus, the traditional consideration of geometrial packing for the green densities of bimodal suspensions may not be enough. The interaction between particles must be taken into account.


Theoretically, at least, systems of solid particles of ultra-microscopic size suspended in a gaseous medium, should show many resemblances to those analogous systems in which the dispersion medium is a liquid. It might be expected that the well-known characteristics of colloidal matter, such as coagulation, peptisation, protective action, gel formation, etc., would have their counterpart in the simpler gaseous systems. Should this prove to be the case much information should accrue from a study of these aerosols in which many complicating factors are absent. Now although the movement of individual particles (not necessarily of ultra-microscopic size), suspended in gases, has been investigated very carefully, and the study has led to experimental and theoretical results of the greatest importance, for instance, the measurement of the unit electronic charge (de Broglie (1), Ehrenhaft (2), Millikan (3)), little attention has been paid to the question of the stability of gaseous systems and the changes they undergo, and no attempt has been made to compare the properties of solid colloidal suspensions in the gaseous and liquid states. From this point of view, dusts, fumes, smokes, and clouds are colloidal systems possessing varying degrees of stability, dispersion, and concentration, which sometimes flocculate or precipitate rapidly, sometimes remain highly disperse for long periods of time, and correspond to the many types of liquid systems which vary from coarse suspensions to fine-textured sols.


2019 ◽  
Vol 1 (1) ◽  
pp. 49-60
Author(s):  
Simon Heru Prassetyo ◽  
Ganda Marihot Simangunsong ◽  
Ridho Kresna Wattimena ◽  
Made Astawa Rai ◽  
Irwandy Arif ◽  
...  

This paper focuses on the stability analysis of the Nanjung Water Diversion Twin Tunnels using convergence measurement. The Nanjung Tunnel is horseshoe-shaped in cross-section, 10.2 m x 9.2 m in dimension, and 230 m in length. The location of the tunnel is in Curug Jompong, Margaasih Subdistrict, Bandung. Convergence monitoring was done for 144 days between February 18 and July 11, 2019. The results of the convergence measurement were recorded and plotted into the curves of convergence vs. day and convergence vs. distance from tunnel face. From these plots, the continuity of the convergence and the convergence rate in the tunnel roof and wall were then analyzed. The convergence rates from each tunnel were also compared to empirical values to determine the level of tunnel stability. In general, the trend of convergence rate shows that the Nanjung Tunnel is stable without any indication of instability. Although there was a spike in the convergence rate at several STA in the measured span, that spike was not replicated by the convergence rate in the other measured spans and it was not continuous. The stability of the Nanjung Tunnel is also confirmed from the critical strain analysis, in which most of the STA measured have strain magnitudes located below the critical strain line and are less than 1%.


1996 ◽  
Vol 308 ◽  
pp. 31-62 ◽  
Author(s):  
Chi-Hwa Wang ◽  
R. Jackson ◽  
S. Sundaresan

This paper presents a linear stability analysis of a rapidly sheared layer of granular material confined between two parallel solid plates. The form of the steady base-state solution depends on the nature of the interaction between the material and the bounding plates and three cases are considered, in which the boundaries act as sources or sinks of pseudo-thermal energy, or merely confine the material while leaving the velocity profile linear, as in unbounded shear. The stability analysis is conventional, though complicated, and the results are similar in all cases. For given physical properties of the particles and the bounding plates it is found that the condition of marginal stability depends only on the separation between the plates and the mean bulk density of the particulate material contained between them. The system is stable when the thickness of the layer is sufficiently small, but if the thickness is increased it becomes unstable, and initially the fastest growing mode is analogous to modes of the corresponding unbounded problem. However, with a further increase in thickness a new mode becomes dominant and this is of an unusual type, with no analogue in the case of unbounded shear. The growth rate of this mode passes through a maximum at a certain value of the thickness of the sheared layer, at which point it grows much faster than any mode that could be shared with the unbounded problem. The growth rate of the dominant mode also depends on the bulk density of the material, and is greatest when this is neither very large nor very small.


Author(s):  
Abbas Zabihi Zonouz ◽  
Mohammad Ali Badamchizadeh ◽  
Amir Rikhtehgar Ghiasi

In this paper, a new method for designing controller for linear switching systems with varying delay is presented concerning the Hurwitz-Convex combination. For stability analysis the Lyapunov-Krasovskii function is used. The stability analysis results are given based on the linear matrix inequalities (LMIs), and it is possible to obtain upper delay bound that guarantees the stability of system by solving the linear matrix inequalities. Compared with the other methods, the proposed controller can be used to get a less conservative criterion and ensures the stability of linear switching systems with time-varying delay in which delay has way larger upper bound in comparison with the delay bounds that are considered in other methods. Numerical examples are given to demonstrate the effectiveness of proposed method.


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