scholarly journals The thermal conductivities of certain liquids

The determination of the thermal conductivity of liquids and the variation with temperature has received the attention of a number of workers in the past, notably, Lees in 1898, R. Weber in 1903, and Goldschmidt in 1911. In general, however, the temperature ranges explored were somewhat restricted, and the present work was accordingly directed to determining the conductivities of a number of the more common liquids up to the highest temperatures feasible. In measuring the thermal conductivity of a liquid it is, of course, essential that convection effects should be reduced to a minimum. This may be effected by employing small temperature differences across a thin horizontal layer of the liquid, the heat flow being directed downwards.

1982 ◽  
Vol 22 (04) ◽  
pp. 558-562 ◽  
Author(s):  
P.C. Rawat ◽  
S.L. Agarwal

Abstract An important parameter required for computing heat loss through buried submarine pipelines transporting crude oil is the thermal conductivity of soils. This paper describes an apparatus designed for determination of the thermal conductivity of soils at the desired moisture/ density condition in the laboratory under steady-state conditions. Experimental results on the three soils studied show that thermal conductivity increases as dry density increases at a constant moisture content and that it increases as water content increases at constant dry density. These results confirm the trends isolated earlier by Kersten. The experimental results are compared with the available empirical relationships. Kersten's relation is observed to predict the thermal conductivity of these soils reasonably. The predictions from Makowski and Mochlinski's relation (quoted by Szilas) are not good but improve if the sum of silt and clay fractions is treated as a clay fraction in the computation. Introduction Submarine pipelines are used extensively for transporting crude oil from offshore to other pipelines offshore or onshore. These pipelines usually are steel pipes covered with a coating of concrete. They often are buried some depth below the mudline. The rheological properties of different crude oils vary, and their viscosities increase with a decrease in temperature. Below some temperature, the liquid oil tends to gel. Therefore, for efficient transportation, the crude must be at a relatively high temperature so that it has a low viscosity. The temperature of the soil/water system surrounding a submarine pipeline is usually lower than that of oil. This temperature difference induces heat to flow from the oil to the environment, and the temperature of the oil decreases as it travels along the length of the pipeline. One must ensure that this temperature reduction does not exceed desirable limits dictated by the rheological properties of oil and by the imperatives of efficient economic properties of oil and by the imperatives of efficient economic transportation. Thus the analytical problem is to predict the temperature of crude in the pipeline some distance away from the input station. To do so, knowledge of the overall heat transfer coefficient for the pipeline is required, for which, in turn, it is necessary to know the thermal conductivities of the oil, the pipeline materials and its coating, and the soil. This paper presents thermal conductivities of soils determined in the laboratory under steady-state conditions and also presents a comparison of the test results of three soils with values determined from existing empirical relationships. Literature Review Heat moves spontaneously from higher to lower temperatures. In a completely dry porous body, transmission of heat can take place not only by conduction through the solid framework of the body and the air in the pores but also by convection and radiation between the walls of a pore and by macro- and microdistillation. In soils, however, it can be ascribed essentially to conduction, a molecular phenomenon that can be expressed in terms of experimentally determined coefficients of conductivity or resistivity, although these actually may include microdistillation and other mechanisms. SPEJ p. 558


The analysis of the dynamic theory of gases has indicated an interesting relation between the viscosity η , the thermal conductivity K, and the specific heat at constant volume C c of a gas. This relation is represented by the expression K = f . C c . η , in which the factor f depends upon the law of force operative in molecular collision, and is known if K, C c , and η can be determined experimentally. In view of its importance in this respect, and also from the fact that great accuracy and consistency of measurement are possible in modern determinations of the viscosity of gases, the importance of the development of a method by which the conductivity can be measured with the same order of accuracy demands increasing attention.


2001 ◽  
Vol 16 (9) ◽  
pp. 2530-2543 ◽  
Author(s):  
Erwin R. Meinders

A scanning thermal microscope (SThM) was used to measure the thermal conductivity of thin sputter-deposited films in the thickness range of 10 nm–10 μm. The SThM method is based on a heated tip that is scanned across the surface of a sample. The heat flowing into the sample is correlated to the local thermal conductivity of the sample. Issues like the contact force, the surface roughness of the sample, and tip degradation, which determine to a great extent the contact area between tip and surface, and thus the heat flow to the sample, are addressed in the paper. A calibration curve was measured from known reference materials to quantify the sample heat flow. This calibration was used to determine the effective thermal conductivity of samples. Further, the heat diffusion through a layered sample due to a surface heat source was analyzed with an analytical and numerical model. Measurements were performed with films of aluminum, ZnS–SiO2, and GeSbTe phase change material of variable thickness and sputter-deposited on substrates of glass, silicon, or polycarbonate. It is shown in the paper that the SThM is a suitable tool to visualize relative differences in thermal structure of nanometer resolution. Determination of the thermal conductivity of thin layers is possible for layers in the micrometer range. It is concluded that the SThM is not sensitive enough to measure accurately the thermal conductivity of thin films in the nanometer range. Suggestions for improvement of the SThM method are given.


1947 ◽  
Vol 25a (6) ◽  
pp. 357-374 ◽  
Author(s):  
L. D. Armstrong ◽  
T. M. Dauphinee

An apparatus for measuring the thermal conductivity of metals in the temperature range 0° to 800 °C. is described. The method utilizes unidirectional heat flow in a cylindrical sample in a vacuum. The advantages of the method are outlined and a comprehensive analysis of possible errors in the measurements is included. Measurements on Armco iron indicate that results with an absolute error of less than 2% may be obtained. The results of measurements on a sample of Armco iron gave thermal conductivities of 0.1819 c.g.s units at 0 °C. and 0.0698 c.g.s. units at 800 °C. A change in slope of the thermal conductivity–temperature curve was found at a temperature of approximately 375 °C., and is tentatively attributed to the presence of 0.03% nickel impurity.


2021 ◽  
Vol 2069 (1) ◽  
pp. 012030
Author(s):  
A N Karim ◽  
B Adl-Zarrabi ◽  
P Johansson ◽  
A Sasic Kalagasidis

Abstract Aerogel-based plasters are composite materials with declared thermal conductivities in the range of traditional insulating materials, i.e. 30-50 mW/(m·K). Based on the results from reported field measurements, aerogel-based plasters can significantly reduce the thermal transmittance of uninsulated walls. However, the in-situ measured thermal conductivities have sometimes been higher than the declared values measured in laboratory and in the main direction of the heat flow. Meanwhile, the anisotropic thermal performance of aerogel-based plasters, i.e., deviating thermal performance in the different directions of heat flow, has not been explored yet. The objective of this study is thus to evaluate the anisotropic thermal conductivity of an aerogel-based plaster. This is done in a set of laboratory measurements using the transient plane source method. Six identical and cubic samples with the dimensions of 10×10×10 cm3 were paired two and two, creating three identical sample sets. In total, 360 measurements of thermal conductivity and thermal diffusivity, and 130 measurements for specific heat capacity were conducted. The results indicate a weak anisotropy of less than ±6.5 % between the three directions (x, y, z). Considering the accuracy of the selected measurement technique, better than ±5 %, supplementary measurements using another technique are recommended.


Author(s):  
Juekuan Yang ◽  
Scott W. Waltermire ◽  
Yang Yang ◽  
Deyu Li ◽  
Yunfei Chen

Thermal transport through carbon nanotubes (CNTs) attracted a lot of attention over the past decade. Several experimental studies have been carried out to determine the thermal conductivities of CNTs [1–3]. However, the measurements are based on an individual CNT sample between two suspended membranes and the results actually include both the intrinsic thermal resistance of the CNT and the contact thermal resistance between the CNT and the two suspended membranes that serve as a heat source and a heat sink. Hence, the effective thermal conductivity extracted from these measurements should be lower than the intrinsic thermal conductivities of the CNTs measured. To minimize the contact thermal resistance, electron beam induce deposition (EBID) of different metals has been used to increase the contact area between the CNT and the heat source and sink [3,4]. However, it is still not clear how effective this treatment is and to what level the effective thermal conductivity obtained after the EBID treatment reflects the intrinsic one.


Sign in / Sign up

Export Citation Format

Share Document