scholarly journals Enhanced photovoltaic properties of perovskite solar cells by TiO 2 homogeneous hybrid structure

2017 ◽  
Vol 4 (10) ◽  
pp. 170942 ◽  
Author(s):  
Pengyu Su ◽  
Wuyou Fu ◽  
Huizhen Yao ◽  
Li Liu ◽  
Dong Ding ◽  
...  
Keyword(s):  
Solar Cells ◽  
High Efficiency ◽  
Power Conversion ◽  
Photovoltaic Cells ◽  
Perovskite Solar Cells ◽  
Hybrid Structure ◽  
Ambient Conditions ◽  
Photovoltaic Properties ◽  
Air Mass ◽  
Enhanced Properties

In this paper, we fabricated a TiO 2 homogeneous hybrid structure for application in perovskite solar cells (PSCs) under ambient conditions. Under the standard air mass 1.5 global (AM 1.5G) illumination, PSCs based on homogeneous hybrid structure present a maximum power conversion efficiency of 5.39% which is higher than that of pure TiO 2 nanosheets. The enhanced properties can be explained by the better contact of TiO 2 nanosheets/nanoparticles with CH 3 NH 3 PbI 3 and fewer pinholes in electron transport materials. The advent of such unique structure opens up new avenues for the future development of high-efficiency photovoltaic cells.

scholarly journals Hybrid Organic-Inorganic Perovskites Open a New Era for Low-Cost, High Efficiency Solar Cells

2015 ◽  
Vol 2015 ◽  
pp. 1-10 ◽  
Author(s):  
Guiming Peng ◽  
Xueqing Xu ◽  
Gang Xu
Keyword(s):  
Solar Cells ◽  
Solar Energy ◽  
High Efficiency ◽  
Low Cost ◽  
Power Conversion ◽  
Perovskite Solar Cells ◽  
Device Structure ◽  
New Era ◽  
High Efficiency Solar Cells ◽  
Conversion Efficiencies

The ramping solar energy to electricity conversion efficiencies of hybrid organic-inorganic perovskite solar cells during the last five years have opened new doors to low-cost solar energy. The record power conversion efficiency has climbed to 19.3% in August 2014 and then jumped to 20.1% in November. In this review, the main achievements for perovskite solar cells categorized from a viewpoint of device structure are overviewed. The challenges and prospects for future development of this field are also briefly presented.

Triethyl phosphate in an antisolvent: a novel approach to fabricate high-efficiency and stable perovskite solar cells under ambient air conditions

2021 ◽  
Vol 5 (20) ◽  
pp. 7628-7637
Author(s):  
Pengyun Zhang ◽  
Ningxia Gu ◽  
Xiang Chen ◽  
Lixin Song ◽  
Pingfan Du ◽  
...  
Keyword(s):  
Solar Cells ◽  
High Efficiency ◽  
Perovskite Solar Cells ◽  
Ambient Air ◽  
Good Stability ◽  
Triethyl Phosphate ◽  
Ambient Conditions ◽  
Novel Approach

In this contribution, PSCs with a high efficiency and good stability are fabricated under ambient conditions without a glove box via introducing triethyl phosphate (TEP) into a perovskite through an antisolvent.

scholarly journals A Review on Improving the Quality of Perovskite Films in Perovskite Solar Cells via the Weak Forces Induced by Additives

2019 ◽  
Vol 9 (20) ◽  
pp. 4393 ◽  
Author(s):  
Jien Yang ◽  
Songhua Chen ◽  
Jinjin Xu ◽  
Qiong Zhang ◽  
Hairui Liu ◽  
...  
Keyword(s):  
Solar Cells ◽  
Power Conversion Efficiency ◽  
Conversion Efficiency ◽  
High Efficiency ◽  
Power Conversion ◽  
Perovskite Solar Cells ◽  
Term Stability ◽  
Long Term Stability ◽  
Weak Forces

Perovskite solar cells (PSCs) employing organic-inorganic halide perovskite as active layers have attracted the interesting of many scientists since 2009. The power conversion efficiency (PCE) have pushed certified 25.2% in 2019 from initial 3.81% in 2009, which is much faster than that of any type of solar cell. In the process of optimization, many innovative approaches to improve the morphology of perovskite films were developed, aiming at elevate the power conversion efficiency of perovskite solar cells (PSCs) as well as long-term stability. In the context of PSCs research, the perovskite precursor solutions modified with different additives have been extensively studied, with remarkable progress in improving the whole performance. In this comprehensive review, we focus on the forces induced by additives between the cations and anions of perovskite precursor, such as hydrogen bonds, coordination or some by-product (e.g., mesophase), which will lead to form intermediate adduct phases and then can be converted into high quality films. A compact uniform perovskite films can not only upgrade the power conversion efficiency (PCE) of devices but also improve the stability of PSCs under ambient conditions. Therefore, strategies for the implementation of additives engineering in perovskites precursor solution will be critical for the future development of PSCs. How to manipulate the weak forces in the fabrication of perovskite film could help to further develop high-efficiency solar cells with long-term stability and enable the potential of future practical applications.

scholarly journals Low-Temperature Processed TiOx Electron Transport Layer for Efficient Planar Perovskite Solar Cells

Nanomaterials ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 1676
Author(s):  
Md. Shahiduzzaman ◽  
Daiki Kuwahara ◽  
Masahiro Nakano ◽  
Makoto Karakawa ◽  
Kohshin Takahashi ◽  
...  
Keyword(s):  
Solar Cells ◽  
High Temperature ◽  
Electron Transport ◽  
Low Temperature ◽  
High Efficiency ◽  
Low Cost ◽  
Perovskite Solar Cells ◽  
Transport Layer ◽  
Electron Transport Layer ◽  
Photovoltaic Properties

The most frequently used n-type electron transport layer (ETL) in high-efficiency perovskite solar cells (PSCs) is based on titanium oxide (TiO2) films, involving a high-temperature sintering (>450 °C) process. In this work, a dense, uniform, and pinhole-free compact titanium dioxide (TiOx) film was prepared via a facile chemical bath deposition process at a low temperature (80 °C), and was applied as a high-quality ETL for efficient planar PSCs. We tested and compared as-deposited substrates sintered at low temperatures (< 150 °C) and high temperatures (> 450 °C), as well as their corresponding photovoltaic properties. PSCs with a high-temperature treated TiO2 compact layer (CL) exhibited power conversion efficiencies (PCEs) as high as 15.50%, which was close to those of PSCs with low-temperature treated TiOx (14.51%). This indicates that low-temperature treated TiOx can be a potential ETL candidate for planar PSCs. In summary, this work reports on the fabrication of low-temperature processed PSCs, and can be of interest for the design and fabrication of future low-cost and flexible solar modules.

scholarly journals Triple-cation low-bandgap perovskite thin-films for high-efficiency four-terminal all-perovskite tandem solar cells

2020 ◽  
Vol 8 (46) ◽  
pp. 24608-24619 ◽  
Author(s):  
Somayeh Moghadamzadeh ◽  
Ihteaz M. Hossain ◽  
The Duong ◽  
Saba Gharibzadeh ◽  
Tobias Abzieher ◽  
...  
Keyword(s):  
Thin Films ◽  
Solar Cells ◽  
Power Conversion Efficiency ◽  
Conversion Efficiency ◽  
High Efficiency ◽  
Power Conversion ◽  
Perovskite Solar Cells ◽  
Tandem Solar Cells ◽  
Low Bandgap ◽  
Photo Stability

Incorporating 2.5% Cs in FA0.8MA0.2Sn0.5Pb0.5I3 improves the photo-stability of the low-bandgap perovskite solar cells. The champion device with power conversion efficiency of 18.9% maintain 92% of its initial efficiency after 120 min MPP tracking.

Water Vapour Pressure as Main Lab Parameter to Fabricate High Efficiency Perovskite Solar Cells at Ambient Conditions

2019 ◽  
Author(s):  
Lidia Contreras-Bernal ◽  
Antonio Riquelme ◽  
Juan Jesús Gallardo ◽  
Javier Navas ◽  
Jesús Idígoras ◽  
...  
Keyword(s):  
Solar Cells ◽  
Water Vapour ◽  
Vapour Pressure ◽  
High Efficiency ◽  
Perovskite Solar Cells ◽  
Water Vapour Pressure ◽  
Ambient Conditions

Tin as an emerging surrogate for Lead-free perovskite solar cells

2020 ◽  
Vol 10 ◽  
Author(s):  
Arunkumar Prabhakaran Shyma ◽  
Andrews Nirmala Grace ◽  
Vimala Raghavan ◽  
George Jacob ◽  
Raja Sellappan
Keyword(s):  
Solar Cells ◽  
High Efficiency ◽  
Perovskite Solar Cells ◽  
Oxidation Stability ◽  
Lead Toxicity ◽  
Lead Free ◽  
Photovoltaic Properties ◽  
Functional Additives ◽  
Absorber Material ◽  
Current Scenario

: Perovskite-based photovoltaic technology has gained significant attention owing to its tunable electrical and optical properties. Among them, lead-based perovskites are considered as the most efficient one that delivers maximum power conversion efficiency with ample stability. In the current scenario, the perovskite-based solar cells (PSCs) can be classified into two main categories, i.e., highly efficient lead-containing and underperforming lead-free based. Even though lead-based PSCs delivers high efficiency, it loses the charm in the context of lead toxicity. The toxicity issue related to lead stands as a barrier to the commercialization of lead-based PSCs. To date, various materials have been prepared and implemented as an alternative to lead in the absorber layer. Tin (Sn) based perovskites are explored as an alternative absorber material owing to its photovoltaic properties that are comparable to lead. Tin-based perovskites exhibit some drawbacks, such as rapid crystallization, lack of oxidation stability, etc. Many research group has addressed the problems regarding tinbased perovskites and modified its structural and morphological aspects through compositional engineering as well as functional additives and managed to obtain an efficiency of around 10 %. In this review, we portray the state of the art developments of tin-based PSCs and its future perspectives.

High-performance perovskite/Cu(In,Ga)Se2 monolithic tandem solar cells

Science ◽  
2018 ◽  
Vol 361 (6405) ◽  
pp. 904-908 ◽  
Author(s):  
Qifeng Han ◽  
Yao-Tsung Hsieh ◽  
Lei Meng ◽  
Jyh-Lih Wu ◽  
Pengyu Sun ◽  
...  
Keyword(s):  
Solar Cells ◽  
High Efficiency ◽  
Short Circuit ◽  
Critical Role ◽  
Hole Transport ◽  
Transport Layer ◽  
Hole Transport Layer ◽  
Ambient Conditions ◽  
Photovoltaic Properties ◽  
Tandem Solar Cells

The combination of hybrid perovskite and Cu(In,Ga)Se2 (CIGS) has the potential for realizing high-efficiency thin-film tandem solar cells because of the complementary tunable bandgaps and excellent photovoltaic properties of these materials. In tandem solar device architectures, the interconnecting layer plays a critical role in determining the overall cell performance, requiring both an effective electrical connection and high optical transparency. We used nanoscale interface engineering of the CIGS surface and a heavily doped poly[bis(4-phenyl)(2,4,6-trimethylphenyl)amine] (PTAA) hole transport layer between the subcells that preserves open-circuit voltage and enhances both the fill factor and short-circuit current. A monolithic perovskite/CIGS tandem solar cell achieved a 22.43% efficiency, and unencapsulated devices under ambient conditions maintained 88% of their initial efficiency after 500 hours of aging under continuous 1-sun illumination.

scholarly journals High-efficiency perovskite solar cells employing a conjugated donor–acceptor co-polymer as a hole-transporting material

RSC Advances ◽  
2017 ◽  
Vol 7 (44) ◽  
pp. 27189-27197 ◽  
Author(s):  
Ze Yu ◽  
Yuchen Zhang ◽  
Xiaoqing Jiang ◽  
Xiaoxin Li ◽  
Jianbo Lai ◽  
...  
Keyword(s):  
Solar Cells ◽  
Power Conversion Efficiency ◽  
Conversion Efficiency ◽  
High Efficiency ◽  
Power Conversion ◽  
Perovskite Solar Cells ◽  
Hole Transporting ◽  
Donor Acceptor ◽  
Hole Transporting Material

In this work, we have successfully demonstrated that molecularly p-doping of donor–acceptor co-polymer PCPDTBT as an efficient hole-transporting material in perovskite solar cells with a decent power conversion efficiency of 15.1%.

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