Compositional characterization of V-type candidate asteroids identified using the MOVIS catalogue

2019 ◽  
Vol 488 (3) ◽  
pp. 3866-3875 ◽  
Author(s):  
H Medeiros ◽  
J de León ◽  
D Lazzaro ◽  
M Popescu ◽  
V Lorenzi ◽  
...  
Keyword(s):  
Infrared Spectra ◽  
Near Infrared ◽  
Spectral Parameters ◽  
Optical Telescope ◽  
Isaac Newton ◽  
Infrared Telescope ◽  
Band Area ◽  
La Palma ◽  
Near Infrared Spectra ◽  
The Right

ABSTRACT The main objective of this work is to compositionally analyse the visible to near-infrared spectra of a total of six V-type candidates identified using the MOVIS (Y-J) versus (J-Ks) colour–colour plot and located outside the Vesta collisional family. We obtained visible and near-infrared spectra of these asteroids using the 2.54m Isaac Newton Telescope, the 2.5m Nordic Optical Telescope, and the 3.58m Telescopio Nazionale Galileo, all located at the El Roque de Los Muchachos Observatory (La Palma, Spain), as well as the 3.0m NASA Infrared Telescope Facility, located at the Mauna Kea Observatory in Hawaii. We computed several diagnostic spectral parameters (slopes, band centres, band depths, band area ratio, or BAR) and compared them to the ones known for HED meteorites and (4) Vesta. The taxonomic classification confirmed five out of the six candidates as V-types, leading to an identification success rate about 83 per cent. In general, the spectral parameters obtained for the five V-types are in good agreement with those of HED meteorites and (4) Vesta. The exception is asteroid (2452) Lyot, a V-type in the outer belt, located very close to (1459) Magnya, but showing distinct [Wo] and [Fs] molar contents both from Magnya and Vesta, pointing toward a diogenitic compostion. We also studied the dependency of the BAR parameter on the way it is computed (removing or not the continuum), the spectral slope, and the last point used to delimit the right wing of the absorption band at 2 μm.

scholarly journals The visible and near-infrared spectra of asteroids in cometary orbits

2018 ◽  
Vol 618 ◽  
pp. A170 ◽  
Author(s):  
J. Licandro ◽  
M. Popescu ◽  
J. de León ◽  
D. Morate ◽  
O. Vaduvescu ◽  
...  
Keyword(s):  
Near Infrared ◽  
Spectral Slope ◽  
Isaac Newton ◽  
Infrared Telescope ◽  
La Palma ◽  
Spectral Class ◽  
Telescope Facility ◽  
Hydrated Minerals ◽  
Taxonomical Classification ◽  
William Herschel

Context. Dynamical and albedo properties suggest that asteroids in cometary orbits (ACOs) are dormant or extinct comets. Their study provides new insights for understanding the end-states of comets and the size of the comet population. Aims. We intend to study the visible and near-infrared (NIR) spectral properties of different ACO populations and compare them to the independently determined properties of comets. Methods. We select our ACOs sample based on published dynamical criteria and present our own observational results obtained using the 10.4 m Gran Telescopio Canarias (GTC), the 4.2 m William Herschel Telescope (WHT), the 3.56 m Telescopio Nazionale Galileo (TNG), and the 2.5 m Isaac Newton Telescope (INT), all located at the El Roque de los Muchachos Observatory (La Palma, Spain), and the 3.0 m NASA Infrared Telescope Facility (IRTF), located at the Mauna Kea Observatory, in Hawaii. We include in the analysis the spectra of ACOs obtained from the literature. We derive the spectral class and the visible and NIR spectral slopes. We also study the presence of hydrated minerals by studying the 0.7 μm band and the UV-drop below 0.5 μm associated with phyllosilicates. Results. We present new observations of 17 ACOs, 11 of them observed in the visible, 2 in the NIR and 4 in the visible and NIR. We also discuss the spectra of 12 ACOs obtained from the literature. All but two ACOs have a primitive-like class spectrum (X or D-type). Almost 100% of the ACOs in long-period cometary orbits (Damocloids) are D-types. Those in Jupiter family comet orbits (JFC-ACOs) are ∼60% D-types and ∼40% X-types. The mean spectral slope S′ of JFC-ACOs is 9.7 ± 4.6%/1000 Å and for the Damocloids this is 12.2 ± 2.0%/1000 Å. No evidence of hydration on the surface of ACOs is found from their visible spectra. The spectral slope and spectral class distribution of ACOs is similar to that of comets. Conclusions. The spectral taxonomical classification and the spectral slope distribution of ACOs, and the lack of spectral features indicative of the presence of hydrated minerals on their surface, strongly suggest that ACOs are likely dormant or extinct comets.

Rapid Determining Contents of the Rhubarb Anthraquinones Compounds by Support Vector Machines Modeling based on Near Infrared Spectra

2020 ◽  
Vol 16 ◽  
Author(s):  
Linqi Liu ◽  
JInhua Luo ◽  
Chenxi Zhao ◽  
Bingxue Zhang ◽  
Wei Fan ◽  
...  
Keyword(s):  
Infrared Spectra ◽  
Near Infrared ◽  
Mean Squared Error ◽  
Rapid Determination ◽  
Partial Least Square ◽  
Least Square ◽  
Support Vector ◽  
Near Infrared Spectra ◽  
Aloe Emodin ◽  
Relative Differences

BACKGROUND: Measuring medicinal compounds to evaluate their quality and efficacy has been recognized as a useful approach in treatment. Rhubarb anthraquinones compounds (mainly including aloe-emodin, rhein, emodin, chrysophanol and physcion) are its main effective components as purgating drug. In the current Chinese Pharmacopoeia, the total anthraquinones content is designated as its quantitative quality and control index while the content of each compound has not been specified. METHODS: On the basis of forty rhubarb samples, the correlation models between the near infrared spectra and UPLC analysis data were constructed using support vector machine (SVM) and partial least square (PLS) methods according to Kennard and Stone algorithm for dividing the calibration/prediction datasets. Good models mean they have high correlation coefficients (R2) and low root mean squared error of prediction (RMSEP) values. RESULTS: The models constructed by SVM have much better performance than those by PLS methods. The SVM models have high R2 of 0.8951, 0.9738, 0.9849, 0.9779, 0.9411 and 0.9862 that correspond to aloe-emodin, rhein, emodin, chrysophanol, physcion and total anthraquinones contents, respectively. The corresponding RMSEPs are 0.3592, 0.4182, 0.4508, 0.7121, 0.8365 and 1.7910, respectively. 75% of the predicted results have relative differences being lower than 10%. As for rhein and total anthraquinones, all of the predicted results have relative differences being lower than 10%. CONCLUSION: The nonlinear models constructed by SVM showed good performances with predicted values close to the experimental values. This can perform the rapid determination of the main medicinal ingredients in rhubarb medicinal materials.

Discrimination of transgenic tomatoes based on visible/near-infrared spectra

2007 ◽  
Vol 584 (2) ◽  
pp. 379-384 ◽  
Author(s):  
Lijuan Xie ◽  
Yibin Ying ◽  
Tiejin Ying ◽  
Haiyan Yu ◽  
Xiaping Fu
Keyword(s):  
Infrared Spectra ◽  
Near Infrared ◽  
Near Infrared Spectra ◽  
Transgenic Tomatoes

Mid and near Infrared Study of Carbohydrates by Canonical Correlation Analysis

1993 ◽  
Vol 1 (2) ◽  
pp. 99-108 ◽  
Author(s):  
P. Robert ◽  
M.F. Devaux ◽  
A. Qannari ◽  
M. Safar
Keyword(s):  
Correlation Analysis ◽  
Infrared Spectra ◽  
Canonical Correlation ◽  
Near Infrared ◽  
Sugar Content ◽  
Infrared Region ◽  
Total Sugar ◽  
Mid Infrared ◽  
Total Sugar Content ◽  
Near Infrared Spectra

Multivariate data treatments were applied to mid and near infrared spectra of glucose, fructose and sucrose solutions in order to specify near infrared frequencies that characterise each carbohydrate. As a first step, the mid and near infrared regions were separately studied by performing Principal Component Analyses. While glucose, fructose and sucrose could be clearly identified on the similarity maps derived from the mid infrared spectra, only the total sugar content of the solutions was observed when using the near infrared region. Characteristic wavelengths of the total sugar content were found at 2118, 2270 and 2324 nm. In a second step, the mid and near infrared regions were jointly studied by a Canonical Correlation Analysis. As the assignments of frequencies are generally well known in the mid infrared region, it should be useful to study the relationships between the two infrared regions. Thus, the canonical patterns obtained from the near infrared spectra revealed wavelengths that characterised each carbohydrate. The OH and CH combination bands were observed at: 2088 and 2332 nm for glucose, 2134 and 2252 nm for fructose, 2058 and 2278 nm for sucrose. Although a precise assignment of the near infrared bands to chemical groups within the molecules was not possible, the present work showed that near infrared spectra of carbohydrates presented specific features.

Analysis of the near-infrared spectra of C60−

1995 ◽  
Vol 247 (1-2) ◽  
pp. 57-62 ◽  
Author(s):  
Robert D. Bolskar ◽  
Sean H. Gallagher ◽  
Robert S. Armstrong ◽  
Peter A. Lay ◽  
Christopher A. Reed
Keyword(s):  
Infrared Spectra ◽  
Near Infrared ◽  
Near Infrared Spectra
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