Quantitative FE-EPMA measurement of formation and inhibition of carbon contamination on Fe for trace carbon analysis

Microscopy ◽  
2016 ◽  
Author(s):  
Yuji Tanaka ◽  
Takako Yamashita ◽  
Masayasu Nagoshi
Keyword(s):  
Carbon Contamination ◽  
Epma Measurement ◽  
Carbon Analysis

Pengaruh Pendopingan Karbon Terhadap Struktur Kristal dan Morfologi TIO2

2019 ◽  
Vol 2 (2) ◽  
Author(s):  
Frastica Deswardani ◽  
Helga Dwi Fahyuan ◽  
Rimawanto Gultom ◽  
Eif Sparzinanda
Keyword(s):  
Thin Film ◽  
Crystal Structure ◽  
Grain Size ◽  
Tio2 Thin Film ◽  
Crystal Size ◽  
Diffraction Peak ◽  
Carbon Doping ◽  
Tio2 Anatase ◽  
Spray Method ◽  
Carbon Analysis

Telah dilakukan penelitian mengenai pengaruh konsentrasi doping karbon pada lapisan tipis TiO2 yang ditumbuhkan dengan metode spray terhadap struktur kristal dan morfologi TiO2. Hasil karakterisasi SEM menunjukkan bahwa penambahan doping karbon dapat meningkatkan ukuran butir. Lapisan TiO2 doping karbon 8% diperoleh ukuran butir terbesar adalah 1.35 μm, sedangkan ukuran tekecilnya adalah 0.45 μm. Sementara itu, untuk lapisan tipis TiO2 didoping karbon 15% memiliki ukuran butir terbesar yaitu 1.76 μm dan terkecil 0.9 μm. Hasil XRD menunjukkan seluruh puncak difraksi lapisan tipis TiO2 dengan doping karbon 8% dan 15% merupakan TiO2 anatase. Ukuran kristal lapisan TiO2 didoping karbon 8% diperoleh sebesar 638,08 Å dan untuk pendopingan 15% karbon ukuran kristal lapisan tipis TiO2 adalah 638,09 Å, hal ini menunjukkan ukuran kristal kedua sampel tidak mengalami perubahan yang signifikan.   TiO2 thin film with carbon doping has been successfully grown by spray method. The research on the effect of carbon doping on crystal structure and morfology of TiO2 has been prepared by varying carbon concentration (8% and 15% carbon). Analysis of SEM showed that the addition of carbon may increase the grain size. Thin film of TiO2 doped carbon 8% has the largest grain size 1.35 μm, while the smallest grain size is 0.45 μm. Meanwhile, for thin film TiO2 doped carbon 15% has the largest grain size 1.76 μm and smallest 0.9 μm. The XRD results showed the entire diffraction peak of thin film TiO2 doped carbon 8% and 15% were TiO2 anatase. The crystal size of thin film TiO2 doped carbon 8% was obtained at 638.08 Å and for thin film TiO2 doped carbon 15% the crystalline size of TiO2 thin film was 638.09 Å, this shows that the crystal size of both samples did not change significantly.    

scholarly journals Quantification of Carbonic Contamination of Fused Silica Surfaces at Different Stages of Classical Optics Manufacturing

Materials ◽  
2021 ◽  
Vol 14 (7) ◽  
pp. 1620
Author(s):  
Robert Köhler ◽  
Domenico Hellrung ◽  
Daniel Tasche ◽  
Christoph Gerhard
Keyword(s):  
Chemical Composition ◽  
Photoelectron Spectroscopy ◽  
Decisive Role ◽  
Fused Silica ◽  
Process Step ◽  
Carbon Contamination ◽  
Silica Surfaces ◽  
Carbon Impurities ◽  
High Level ◽  
Glass Surfaces

The chemical composition of ground and polished fused silica glass surfaces plays a decisive role in different applications of optics. In particular, a high level of carbon impurities is often undesirable for further processing and especially for gluing or cementing where adhesion failure may be attributed to carbonic surface-adherent contaminants. In this study, the surface carbon content at different stages of classical optics manufacturing was thus investigated. Two different standard processes—grinding and lapping with two final polishing processes using both polyurethane and pitch pads—were considered. After each process step, the chemical composition and roughness of the surface were analysed using X-ray photoelectron spectroscopy and atomic force microscopy. An obvious correlation between surface roughness and effective surface area, respectively, and the proportion of carbon contamination was observed. The lowest carbon contamination was found in case of lapped and pitch polished surfaces.

Bridge River tephra: revised distribution and significance for detecting old carbon errors in radiocarbon dates of limnic sediments in southern British Columbia

1980 ◽  
Vol 17 (11) ◽  
pp. 1454-1461 ◽  
Author(s):  
Rolf W. Mathewes ◽  
John A. Westgate
Keyword(s):  
British Columbia ◽  
Sedimentary Rocks ◽  
Lacustrine Sediments ◽  
Igneous Rocks ◽  
The South ◽  
Radiocarbon Dates ◽  
Carbon Contamination ◽  
Horseshoe Lake ◽  
Tephra Beds

Ash-grade Bridge River tephra, identified as such on the basis of shard habit, modal mineralogy, and composition of ilmenite, occurs in sedimentary cores from three lakes located to the south of the previously documented plume and necessitates a significant enlargement of the fallout area of that tephra in southwestern British Columbia.These new, more southerly occurrences are probably equivalent to the ~2350 year old Bridge River tephra, although it can be argued from the evidence at hand that the 14C dates and biotite-rich nature support relationship to a slightly earlier Bridge River event.Large differences exist in the 14C age of sediments immediately adjacent to the Bridge River tephra at these three lake sites; maximum ages of 3950 ± 170 years BP (GX-5549) and 3750 ± 210 years BP (I-10041) were obtained at Phair and Fishblue lakes, respectively, whereas the corresponding age at Horseshoe Lake is only 2685 ± 180 years BP (GX-5757). The two older dates are considered to be significantly affected by old carbon contamination for the bedrock locally consists of calcareous sedimentary rocks and the lacustrine sediments are very calcareous. The 14C date from Horseshoe Lake, which occurs in an area of igneous rocks, appears to be only slightly too old relative to the ~2350 year old Bridge River tephra.Well-dated tephra beds, therefore, can be very useful in assessing the magnitude of old carbon errors associated with radiocarbon dates based on limnic sediments. Calcareous gyttja deposits beneath Bridge River tephra within the study area exhibit old carbon errors of the order of 1350–1550 years.

Carbon contamination reduced for ambient-pressure X-ray spectroscopy

Scilight ◽  
2021 ◽  
Vol 2021 (21) ◽  
pp. 211110
Author(s):  
Mara Johnson-Groh
Keyword(s):  
Ambient Pressure ◽  
Carbon Contamination ◽  
X Ray

scholarly journals Technical note: Accelerate coccolith size separation via repeated centrifugation

2020 ◽  
Author(s):  
Hongrui Zhang ◽  
Chuanlian Liu ◽  
Luz Maria Mejia ◽  
Heather Stoll
Keyword(s):  
Stable Isotopes ◽  
Angular Velocity ◽  
Carbon Cycle ◽  
Marine Sediment ◽  
Size Fraction ◽  
Technical Note ◽  
Bulk Sediment ◽  
Matlab Code ◽  
Clumped Isotope ◽  
Carbon Analysis

Abstract. Coccolithophore play a key role in the marine carbon cycle and ecosystem. The carbonate shells produced by coccolithophore, named as coccolith, could be well preserved in the marine sediment for million years and become an excellent archive for paleoclimate studies. The micro filtering and sinking-decanting method have been successfully designed for coccolith separation and promoted the development of geochemistry studies on coccolith, such as the stable isotopes and Sr / Ca ratio. However, these two methods are still not efficient enough for the sample-consuming methods. In this study, the trajectory of coccoliths movement during a centrifugation process was calculated in theory and carefully tested by separations in practice. We offer a matlab code to estimate the appropriate parameter, angular velocity at a fixed centrifugation duration, for separating certain coccolith size fractions from bulk sediment. This work could improve the efficiency of coccolith separation, especially for the finest size fraction and make it possible to carry the clumped isotope and radio carbon analysis on coccolith in sediment.

scholarly journals Resin Cement–Zirconia Bond Strengthening by Exposure to Low-Temperature Atmospheric Pressure Multi-Gas Plasma

Materials ◽  
2022 ◽  
Vol 15 (2) ◽  
pp. 631
Author(s):  
Nobuhiro Yoda ◽  
Yuri Abe ◽  
Yuma Suenaga ◽  
Yoshiki Matsudate ◽  
Tomohiro Hoshino ◽  
...  
Keyword(s):  
Treatment Group ◽  
Low Temperature ◽  
Bond Strength ◽  
Plasma Treatment ◽  
Atmospheric Pressure ◽  
Untreated Group ◽  
Resin Cement ◽  
Carbon Contamination ◽  
X Ray ◽  
Plasma Irradiation

The purpose of this study was to investigate the effect of gas species used for low-temperature atmospheric pressure plasma surface treatment, using various gas species and different treatment times, on zirconia surface state and the bond strength between zirconia and dental resin cement. Three groups of zirconia specimens with different surface treatments were prepared as follows: untreated group, alumina sandblasting treatment group, and plasma treatment group. Nitrogen (N2), carbon dioxide (CO2), oxygen (O2), argon (Ar), and air were employed for plasma irradiation. The bond strength between each zirconia specimen and resin cement was compared using a tension test. The effect of the gas species for plasma irradiation on the zirconia surface was investigated using a contact angle meter, an optical interferometer, an X-ray diffractometer, and X-ray photoelectric spectroscopy. Plasma irradiation increased the wettability and decreased the carbon contamination on the zirconia surface, whereas it did not affect the surface topography and crystalline phase. The bond strength varied depending on the gas species and irradiation time. Plasma treatment with N2 gas significantly increased bond strength compared to the untreated group and showed a high bond strength equivalent to that of the sandblasting treatment group. The removal of carbon contamination from the zirconia surface and an increase in the percentage of Zr-O2 on the zirconia surface by plasma irradiation might increase bond strength.

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