The Impact of Molecular Oxygen on Anion Composition in a Hazy Archean Earth Atmosphere

Astrobiology ◽  
2020 ◽  
Vol 20 (5) ◽  
pp. 658-669
Author(s):  
Melissa S. Ugelow ◽  
Jennifer L. Berry ◽  
Eleanor C. Browne ◽  
Margaret A. Tolbert
Keyword(s):  
Molecular Oxygen ◽  
Earth Atmosphere ◽  
Anion Composition ◽  
The Impact

Trends in spectrally resolved OLR from 10 years of IASI measurements

2021 ◽  
Author(s):  
Simon Whitburn ◽  
Lieven Clarisse ◽  
Andy Delcloo ◽  
Steven Dewitte ◽  
Marie Bouillon ◽  
...  
Keyword(s):  
Greenhouse Gases ◽  
Data Retrieval ◽  
Radiation Budget ◽  
Retrieval Algorithm ◽  
Earth Atmosphere ◽  
Clear Sky ◽  
The Earth ◽  
Atmosphere System ◽  
Spectrally Resolved ◽  
The Impact

<p>The Earth's Outgoing Longwave Radiation (OLR) is a key component in the study of climate. As part of the Earth's radiation budget, it reflects how the Earth-atmosphere system compensates the incoming solar radiation at the top of the atmosphere. At equilibrium, the two quantities compensate each other on average. Any variation of the climate drivers (e.g. greenhouse gases) causes an energy imbalance which leads to a climate response (e.g. surface temperature increase), with the effect of bringing the radiation budget back to equilibrium. Considerable improvements in our understanding of the Earth-atmosphere system and of its long-term changes have been achieved in the last four decades through the exploitation of measurements from dedicated broadband instruments. However, such instruments only provide spectrally integrated OLR over a broad spectral range and are therefore not well suited for tracking separately the impact of the different parameters affecting the OLR.</p><p>Better constraints can, in principle, be obtained from spectrally resolved OLR (i.e. the integrand of broadband OLR, in units of W m<sup>-2</sup> cm<sup>-1</sup>) derived from infrared hyperspectral sounders. Recently, a dedicated algorithm was developed to derive clear-sky spectrally resolved OLR from the Infrared Atmospheric Sounding Interferometer (IASI) at the 0.25 cm<sup>-1</sup> native spectral sampling of the L1C spectra (Whitburn et al. 2020).  Here, we analyze the changes in 10 years (2008-2017) of the IASI-derived OLR and we relate them to known changes in greenhouse gases concentrations (CO<sub>2</sub>, CH<sub>4</sub>, H<sub>2</sub>O, …) and climate phenomena activity such as El Niño-Southern Oscillation (ENSO) and the Pacific Decadal Oscillation (PDO).</p><p>Whitburn, S., Clarisse, L., Bauduin, S., George, M., Hurtmans, D., Safieddine, S., Coheur, P. F., and Clerbaux, C. (2020). <strong>Spectrally Resolved Fuxes from IASI Data: Retrieval algorithm for Clear-Sky Measurements</strong>. Journal of Climate. doi: 10.1175/jcli-d-19-0523.1</p>

scholarly journals The evolution of respiratory O 2 /NO reductases: an out-of-the-phylogenetic-box perspective

2014 ◽  
Vol 11 (98) ◽  
pp. 20140196 ◽  
Author(s):  
Anne-Lise Ducluzeau ◽  
Barbara Schoepp-Cothenet ◽  
Robert van Lis ◽  
Frauke Baymann ◽  
Michael J. Russell ◽  
...  
Keyword(s):  
Molecular Oxygen ◽  
Evolutionary History ◽  
Great Oxidation Event ◽  
Evolutionary Innovation ◽  
The Earth ◽  
Enzyme Superfamily ◽  
History Of ◽  
Quinol Oxidases ◽  
The Impact ◽  
Ubiquitous Presence

Complex life on our planet crucially depends on strong redox disequilibria afforded by the almost ubiquitous presence of highly oxidizing molecular oxygen. However, the history of O 2 -levels in the atmosphere is complex and prior to the Great Oxidation Event some 2.3 billion years ago, the amount of O 2 in the biosphere is considered to have been extremely low as compared with present-day values. Therefore the evolutionary histories of life and of O 2 -levels are likely intricately intertwined. The obvious biological proxy for inferring the impact of changing O 2 -levels on life is the evolutionary history of the enzyme allowing organisms to tap into the redox power of molecular oxygen, i.e. the bioenergetic O 2 reductases, alias the cytochrome and quinol oxidases. Consequently, molecular phylogenies reconstructed for this enzyme superfamily have been exploited over the last two decades in attempts to elucidate the interlocking between O 2 levels in the environment and the evolution of respiratory bioenergetic processes. Although based on strictly identical datasets, these phylogenetic approaches have led to diametrically opposite scenarios with respect to the history of both the enzyme superfamily and molecular oxygen on the Earth. In an effort to overcome the deadlock of molecular phylogeny, we here review presently available structural, functional, palaeogeochemical and thermodynamic information pertinent to the evolution of the superfamily (which notably also encompasses the subfamily of nitric oxide reductases). The scenario which, in our eyes, most closely fits the ensemble of these non-phylogenetic data, sees the low O 2 -affinity SoxM- (or A-) type enzymes as the most recent evolutionary innovation and the high-affinity O 2 reductases (SoxB or B and cbb 3 or C) as arising independently from NO-reducing precursor enzymes.

scholarly journals ELECTROMAGNETIC EFFECTS OF ACOUSTIC AND ATMOSPHERIC GRAVITY WAVES IN THE NEAR-EARTH ATMOSPHERE

2020 ◽  
Vol 25 (4) ◽  
pp. 290-307
Author(s):  
Y. Luo ◽  
◽  
L. F. Chernogor ◽  
Keyword(s):  
Magnetic Fields ◽  
Electric Field ◽  
Gravity Waves ◽  
Anthropogenic Sources ◽  
Pressure Amplitude ◽  
Earth Atmosphere ◽  
Atmospheric Gravity Waves ◽  
Electric And Magnetic Fields ◽  
Atmospheric Gravity ◽  
The Impact

Purpose: Acoustic and atmospheric gravity waves (AAGW) are generated by many natural and anthropogenic sources. The AAGW propagation at ionospheric heights is accompanied by the generation of disturbances in the magnetic and electric fields. The plasma presence plays a crucial role. The mechanisms for generating electrical and magnetic disturbances in the near-Earth atmosphere by the AAGW have been studied much worse. Therefore, the validation of the capability to generate electromagnetic disturbances in the near-Earth atmosphere by the AAGW is an urgent problem. The purpose of this paper is to describe the mechanism for generating disturbances in the electric and magnetic fields in the near-Earth atmosphere under the action of AAGW and to estimate the amplitudes of these disturbances for various AAGW sources. Design/methodology/approach: The impact of a series of highenergy sources often results in the generation of synchronous disturbances in the acoustic and geoelectric (atmospheric) fields, when an approximate proportionality between the pressure amplitude and the amplitude of the disturbances in the atmospheric electric field is observed to occur. Based on the observational data and making use of the Maxwell equations, the theoretical estimates of the disturbances in the electric and magnetic fields have been obtained. Findings: Simplified expressions have been obtained for estimating the amplitudes of the electric and magnetic fields under the action of the AAGW generated by natural and manmade sources. The amplitudes of the electric and magnetic fields generated by the AAGW of natural and manmade origin, which travel in the near-Earth atmosphere, have been calculated. The amplitudes of the AAGW generated electric and magnetic fields are shown to be large enough to be detected with the existing electrometers and fluxmeter magnetometers. The magnitudes of the amplitudes of the electric and magnetic fields generated in the near-Earth atmosphere under the action of AAGW are large enough to trigger coupling between the subsystems in the Earth–atmosphere–ionosphere–magnetosphere system. Conclusions: The estimates and not numerous observations are in good agreement. Key words: acoustic and atmospheric gravity waves, near-Earth atmosphere, volume charge, atmospheric pressure disturbances, electric field, magnetic field

scholarly journals Understanding and Improving the Activity of Flavin-Dependent Halogenases via Random and Targeted Mutagenesis

2018 ◽  
Vol 87 (1) ◽  
pp. 159-185 ◽  
Author(s):  
Mary C. Andorfer ◽  
Jared C. Lewis
Keyword(s):  
Molecular Oxygen ◽  
Random Mutagenesis ◽  
Targeted Mutagenesis ◽  
Organic Substrates ◽  
Site Selectivity ◽  
Improved Stability ◽  
The Impact ◽  
Enzyme Class

Flavin-dependent halogenases (FDHs) catalyze the halogenation of organic substrates by coordinating reactions of reduced flavin, molecular oxygen, and chloride. Targeted and random mutagenesis of these enzymes have been used to both understand and alter their reactivity. These studies have led to insights into residues essential for catalysis and FDH variants with improved stability, expanded substrate scope, and altered site selectivity. Mutations throughout FDH structures have contributed to all of these advances. More recent studies have sought to rationalize the impact of these mutations on FDH function and to identify new FDHs to deepen our understanding of this enzyme class and to expand their utility for biocatalytic applications.

Formation of Lunar Craters and Bright Rays as a Result of Meteorite Impacts

1962 ◽  
Vol 14 ◽  
pp. 415-418
Author(s):  
K. P. Stanyukovich ◽  
V. A. Bronshten
Keyword(s):  
Explosive Charge ◽  
The Moon ◽  
Meteorite Impacts ◽  
The Earth ◽  
Lunar Craters ◽  
The Impact

The phenomena accompanying the impact of large meteorites on the surface of the Moon or of the Earth can be examined on the basis of the theory of explosive phenomena if we assume that, instead of an exploding meteorite moving inside the rock, we have an explosive charge (equivalent in energy), situated at a certain distance under the surface.

The Geosciences Applied to Lunar Exploration

1962 ◽  
Vol 14 ◽  
pp. 169-257 ◽  
Author(s):  
J. Green
Keyword(s):  
Lunar Surface ◽  
Probable Mechanism ◽  
Point Of View ◽  
Lunar Exploration ◽  
Geological Model ◽  
Apply Geophysics ◽  
Surface Features ◽  
The Impact

The term geo-sciences has been used here to include the disciplines geology, geophysics and geochemistry. However, in order to apply geophysics and geochemistry effectively one must begin with a geological model. Therefore, the science of geology should be used as the basis for lunar exploration. From an astronomical point of view, a lunar terrain heavily impacted with meteors appears the more reasonable; although from a geological standpoint, volcanism seems the more probable mechanism. A surface liberally marked with volcanic features has been advocated by such geologists as Bülow, Dana, Suess, von Wolff, Shaler, Spurr, and Kuno. In this paper, both the impact and volcanic hypotheses are considered in the application of the geo-sciences to manned lunar exploration. However, more emphasis is placed on the volcanic, or more correctly the defluidization, hypothesis to account for lunar surface features.

Asteroid and Comet Impact Speeds upon Mars: Significance for Panspermia and the Supply of Organics

1997 ◽  
Vol 161 ◽  
pp. 197-201 ◽  
Author(s):  
Duncan Steel
Keyword(s):  
Probability Distributions ◽  
Regions Of Interest ◽  
Significant Fraction ◽  
Organic Chemicals ◽  
Impact Speed ◽  
The Mean ◽  
The Impact

AbstractWhilst lithopanspermia depends upon massive impacts occurring at a speed above some limit, the intact delivery of organic chemicals or other volatiles to a planet requires the impact speed to be below some other limit such that a significant fraction of that material escapes destruction. Thus the two opposite ends of the impact speed distributions are the regions of interest in the bioastronomical context, whereas much modelling work on impacts delivers, or makes use of, only the mean speed. Here the probability distributions of impact speeds upon Mars are calculated for (i) the orbital distribution of known asteroids; and (ii) the expected distribution of near-parabolic cometary orbits. It is found that cometary impacts are far more likely to eject rocks from Mars (over 99 percent of the cometary impacts are at speeds above 20 km/sec, but at most 5 percent of the asteroidal impacts); paradoxically, the objects impacting at speeds low enough to make organic/volatile survival possible (the asteroids) are those which are depleted in such species.

Organic Syntheses During the Impact of a Comet with a Gaseous Planet

1997 ◽  
Vol 161 ◽  
pp. 189-195
Author(s):  
Cesare Guaita ◽  
Roberto Crippa ◽  
Federico Manzini
Keyword(s):  
Polymeric Material ◽  
Molecular Form ◽  
Parent Compound ◽  
Blue Filter ◽  
Organic Syntheses ◽  
The Impact

AbstractA large amount of CO has been detected above many SL9/Jupiter impacts. This gas was never detected before the collision. So, in our opinion, CO was released from a parent compound during the collision. We identify this compound as POM (polyoxymethylene), a formaldehyde (HCHO) polymer that, when suddenly heated, reformes monomeric HCHO. At temperatures higher than 1200°K HCHO cannot exist in molecular form and the most probable result of its decomposition is the formation of CO. At lower temperatures, HCHO can react with NH3 and/or HCN to form high UV-absorbing polymeric material. In our opinion, this kind of material has also to be taken in to account to explain the complex evolution of some SL9 impacts that we observed in CCD images taken with a blue filter.

Hydrogen Cyanide Polymers from the Impact of Comet P/Shoemaker-Levy 9 on Jupiter

1997 ◽  
Vol 161 ◽  
pp. 179-187
Author(s):  
Clifford N. Matthews ◽  
Rose A. Pesce-Rodriguez ◽  
Shirley A. Liebman
Keyword(s):  
Amino Acids ◽  
Solar System ◽  
Hydrogen Cyanide ◽  
Nitrogen Heterocycles ◽  
Laboratory Studies ◽  
Heterogeneous Solids ◽  
The Many ◽  
Comet Halley ◽  
The Impact ◽  
By Products

AbstractHydrogen cyanide polymers – heterogeneous solids ranging in color from yellow to orange to brown to black – may be among the organic macromolecules most readily formed within the Solar System. The non-volatile black crust of comet Halley, for example, as well as the extensive orangebrown streaks in the atmosphere of Jupiter, might consist largely of such polymers synthesized from HCN formed by photolysis of methane and ammonia, the color observed depending on the concentration of HCN involved. Laboratory studies of these ubiquitous compounds point to the presence of polyamidine structures synthesized directly from hydrogen cyanide. These would be converted by water to polypeptides which can be further hydrolyzed to α-amino acids. Black polymers and multimers with conjugated ladder structures derived from HCN could also be formed and might well be the source of the many nitrogen heterocycles, adenine included, observed after pyrolysis. The dark brown color arising from the impacts of comet P/Shoemaker-Levy 9 on Jupiter might therefore be mainly caused by the presence of HCN polymers, whether originally present, deposited by the impactor or synthesized directly from HCN. Spectroscopic detection of these predicted macromolecules and their hydrolytic and pyrolytic by-products would strengthen significantly the hypothesis that cyanide polymerization is a preferred pathway for prebiotic and extraterrestrial chemistry.

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