Far-infrared investigations of a methanol clathrate hydrate - Implications for astronomical observations

1993 ◽  
Vol 404 ◽  
pp. L29 ◽  
Author(s):  
Reggie L. Hudson ◽  
Marla H. Moore
Keyword(s):  
Far Infrared ◽  
Clathrate Hydrate ◽  
Astronomical Observations

The Far Infrared Spectra of Partially Orientationally Ordered Water Molecules: Hexamethylenetetramine Hexahydrate at 95 K

1975 ◽  
Vol 53 (17) ◽  
pp. 2642-2645 ◽  
Author(s):  
John E. Bertie ◽  
Marco Solinas
Keyword(s):  
Infrared Spectrum ◽  
Infrared Spectra ◽  
Far Infrared ◽  
Clathrate Hydrate ◽  
Factor Group ◽  
Water Molecules ◽  
Disordered Solids ◽  
Ordered Water ◽  
Far Infrared Spectra ◽  
Three Phases

The far infrared spectra of four isotopic modifications of the partially orientationally ordered clathrate hydrate hexamethylenetetramine hexahydrate at 95 K are reported. The spectra are assigned to absorption allowed under the diffraction factor group, and to disorder-allowed absorption, following the theory for absorption by translational vibrations in orientationally disordered solids. Three phases formed primarily by hydrogen-bonded water molecules are known to be significantly, but only partially, orientationally ordered, hexamethylenetetramine hexahydrate, ice V, and ice VI. Of these phases, only ice VI fails to show sharp absorption in its far infrared spectrum in addition to the broad, disorder-allowed absorption.

scholarly journals Rotational spectroscopy of methyl mercaptan CH332SH at millimeter and submillimeter wavelengths

2019 ◽  
Vol 629 ◽  
pp. A73 ◽  
Author(s):  
Olena Zakharenko ◽  
Vadim V. Ilyushin ◽  
Frank Lewen ◽  
Holger S. P. Müller ◽  
Stephan Schlemmer ◽  
...  
Keyword(s):  
Far Infrared ◽  
Rotational Spectroscopy ◽  
Methyl Mercaptan ◽  
Mean Square ◽  
Mean Square Deviation ◽  
Astronomical Observations ◽  
Quantum Numbers ◽  
Submillimeter Wavelengths ◽  
Global Study ◽  
Millimeter And Submillimeter Wavelengths

We present a new global study of the millimeter (mm) wave, submillimeter (sub-mm) wave, and terahertz (THz) spectra of the lowest three torsional states of methyl mercaptan (CH3SH). New measurements have been carried out between 50 and 510 GHz using the Kharkiv mm wave and the Cologne sub-mm wave spectrometers whereas THz spectra records were used from our previous study. The new data, involving torsion–rotation transitions with J up to 61 and Ka up to 18, were combined with previously published measurements and fit using the rho-axis-method torsion–rotation Hamiltonian. The final fit used 124 parameters to give an overall weighted root-mean-square deviation of 0.72 for the dataset consisting of 6965 microwave (MW) and 16 345 far-infrared line frequencies sampling transitions within and between the ground, first, and second excited torsional states. This investigation presents a two-fold expansion in the J quantum numbers and a significant improvement in the fit quality, especially for the MW part of the data, thus allowing us to provide more reliable predictions to support astronomical observations.

A 750 mm balloon-borne telescope for far-infrared astronomical observations

1984 ◽  
Vol 17 (2) ◽  
pp. 160-168 ◽  
Author(s):  
R R Daniel ◽  
S K Ghosh ◽  
K V K Iyengar ◽  
D M Patkar ◽  
T N Rengarajan ◽  
...  
Keyword(s):  
Far Infrared ◽  
Astronomical Observations

A 75 cm Balloon-Borne Telescope For Far-Infrared Astronomical Observations

1984 ◽  
Author(s):  
S N. Tandon ◽  
R R. Daniel ◽  
S K. Ghosh ◽  
K V. K. Iyengar ◽  
T N. Rengarajan ◽  
...  
Keyword(s):  
Far Infrared ◽  
Astronomical Observations
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