scholarly journals THE STRUCTURE OF THE COLLODION MEMBRANE AND ITS ELECTRICAL BEHAVIOR

1943 ◽  
Vol 27 (2) ◽  
pp. 77-89 ◽  
Author(s):  
Charles W. Carr ◽  
Karl Sollner
Keyword(s):  
Water Uptake ◽  
Pore Space ◽  
Bound Water ◽  
Weight Increase ◽  
Porous Membranes ◽  
Electrical Behavior ◽  
Volume Changes ◽  
Volume Increase ◽  
Considerable Uncertainty ◽  
Strong Electrolytes

1. The assumption, has generally been made that collodion membranes are rigid and non-swelling in water and aqueous solutions of strong electrolytes, and considerable uncertainty exists as to the manner in which water is taken up by "dried" collodion membranes. In approaching these problems experimentally, the weight and volume changes of collodion membranes when placed in water and when transferred from water to solutions of strong electrolytes were determined. 2. Dried collodion membranes swell reversibly to an appreciable extent when placed in water, the swelling varying from 5 to 11 per cent depending on the brand of collodion. The water uptake and swelling of oxidized collodion is the same as the original unoxidized preparation. 3. The water uptake as determined by the weight increase is larger than could be accounted for by the volume increase, swelling accounting for only 60 to 70 per cent of the water taken up by the membranes. 4. When the "water-wetted dried" collodion membranes were transferred from water to solutions of various strong electrolytes, there was no detectable change in volume. Similarly, when the "porous" membranes were transferred from water to solutions of strong electrolytes, there was no significant volume change. 5. When dried collodion membranes swell in water, some of the water becomes "bound" water, and both intramicellar and intermicellar swelling seem to occur. Therefore, neither the weight increase nor the volume increase nor their difference can be taken as a measure of the true pore space of the membrane. It is concluded that the important problem is not the absolute water content, but how much water in the water-wet membranes is available in useful pathways for the different solutes.

Tracking of the effects of the plasticizer on the water uptake and free volume changes of methylcellulose

2007 ◽  
Vol 18 (11) ◽  
pp. 921-924 ◽  
Author(s):  
Klára Pintye-Hódi ◽  
Károly Süvegh ◽  
Tamás Marek ◽  
Romána Zelkó
Keyword(s):  
Free Volume ◽  
Water Uptake ◽  
Volume Changes

scholarly journals A thermodynamic formulation of root water uptake

2016 ◽  
Vol 20 (8) ◽  
pp. 3441-3454 ◽  
Author(s):  
Anke Hildebrandt ◽  
Axel Kleidon ◽  
Marcel Bechmann
Keyword(s):  
Soil Water ◽  
Water Uptake ◽  
Water Distribution ◽  
Bound Water ◽  
Root Water Uptake ◽  
Flow Path ◽  
Thermodynamic Evaluation ◽  
Entire Flow ◽  
Soil Water Distribution

Abstract. By extracting bound water from the soil and lifting it to the canopy, root systems of vegetation perform work. Here we describe how root water uptake can be evaluated thermodynamically and demonstrate that this evaluation provides additional insights into the factors that impede root water uptake. We derive an expression that relates the energy export at the base of the root system to a sum of terms that reflect all fluxes and storage changes along the flow path in thermodynamic terms. We illustrate this thermodynamic formulation using an idealized setup of scenarios with a simple model. In these scenarios, we demonstrate why heterogeneity in soil water distribution and rooting properties affect the impediment of water flow even though the mean soil water content and rooting properties are the same across the scenarios. The effects of heterogeneity can clearly be identified in the thermodynamics of the system in terms of differences in dissipative losses and hydraulic energy, resulting in an earlier start of water limitation in the drying cycle. We conclude that this thermodynamic evaluation of root water uptake conveniently provides insights into the impediments of different processes along the entire flow path, which goes beyond resistances and also accounts for the role of heterogeneity in soil water distribution.

Porosity Volumetrics and Pore Typing

2014 ◽  
Author(s):  
John H. Doveton
Keyword(s):  
Pore Volume ◽  
Pore Space ◽  
Bound Water ◽  
Primary Objective ◽  
Effective Porosity ◽  
Void Space ◽  
Face Centered ◽  
Petrophysical Logs ◽  
Saline Formation ◽  
Many Core

The primary objective of porosity estimations based on measurements made either from petrophysical logs or core is the volume of pore space within the rock, given simply by the equation: . . . Φ = Vp/Vb . . . The Greek letter, phi, is the standard symbol for porosity and is expressed in this equation as the ratio of the volume of void space (Vp) to the bulk volume of the rock (Vb). The simplest concepts of porosity are generally explained in terms of the packing of spheres as the sum of the pore volume of the space between the spheres. There are five basic arrangements of uniform-sized spheres that can be constructed: simple cubic, orthorhombic, double-nested, face-centered cubic, and rhombohedral packing (Hook, 2003). Each has a geometrically defined pore volume that represents an upper limit for granular rocks whose constituent grains have a variety of sizes and shapes and whose pore volumes have been reduced by compaction and diagenetic cements. This intergranular model is a useful starting point for the characterization of pores in clastic rocks and will be considered first, before reviewing the additional complexities of pore geometry introduced by dissolution in carbonate rocks. The solid framework of a sandstone consists of a nonconductive “matrix” dominated by quartz, but commonly with accessory nonconductive minerals, and conductive clay minerals, whose electrical properties are caused by cation exchange with ions in saline formation water. It is important to distinguish between connected and unconnected pores, as well as larger pores that sustain fluid movement in contrast to smaller pores filled with capillary-bound water. A graphic presentation of these components is widely used in the petrophysical literature as a reference basis to disentangle terminology that can be confusing and contradictory. In particular, the term “effective porosity” has different meanings that vary from one technical discipline to another. In their review of porosity terms, Wu and Berg (2003) concluded that many core analysts considered all porosity to be effective, log analysts excluded clay-bound water, while petroleum engineers excluded both clay-bound and capillary-bound from porosity consideration, thereby restricting effective porosity to pores occupied by mobile fluids.

scholarly journals Pressure- and Temperature-Induced Insertion of N2, O2 and CH4 to Ag-Natrolite

Materials ◽  
2020 ◽  
Vol 13 (18) ◽  
pp. 4096
Author(s):  
Donghoon Seoung ◽  
Hyeonsu Kim ◽  
Pyosang Kim ◽  
Yongmoon Lee
Keyword(s):  
Unit Cell Volume ◽  
Molecular Size ◽  
Unit Cell ◽  
Volume Changes ◽  
Volume Increase ◽  
X Ray ◽  
Onset Pressure ◽  
Two Stages ◽  
Cell Volumes

This paper aimed to investigate the structural and chemical changes of Ag-natrolite (Ag16Al16Si24O80·16H2O, Ag-NAT) in the presence of different pressure transmitting mediums (PTMs), such as N2, O2 and CH4, up to ~8 GPa and 250 °C using in situ synchrotron X-ray powder diffraction and Rietveld refinement. Pressure-induced insertion occurs in two stages in the case of N2 and O2 runs, as opposed to the CH4 run. First changes of the unit cell volume in N2, O2 and CH4 runs are observed at 0.88(5) GPa, 1.05(5) GPa and 1.84(5) GPa with increase of 5.7(1)%, 5.5(1)% and 5.7(1)%, respectively. Subsequent volume changes of Ag-natrolite in the presence of N2 and O2 appear at 2.15(5) GPa and 5.24(5) GPa with a volume increase of 0.8(1)% and a decrease of 3.0(1)%, respectively. The bulk moduli of the Ag-NAT change from 42(1) to 49(7), from 38(1) to 227(1) and from 49(3) to 79(2) in the case of N2, O2 and CH4 runs, respectively, revealing that the Ag-NAT becomes more incompressible after each insertion of PTM molecules. The shape of the channel window of the Ag-NAT changes from elliptical to more circular after the uptake of N2, O2 and CH4. Overall, the experimental results of Ag-NAT from our previous data and this work establish that the onset pressure exponentially increases with the molecular size. The unit cell volumes of the expanded (or contracted) phases of the Ag-NAT have a linear relationship and limit to maximally expand and contract upon pressure-induced insertion.

Collagen in the fetal membranes of sheep: changes throughout gestation and effects of dexamethasone at 60 days

1997 ◽  
Vol 9 (4) ◽  
pp. 455 ◽  
Author(s):  
Lynne Shandley ◽  
Karen M. Moritz ◽  
Chrishan S. Samuel ◽  
E. Marelyn Wintour
Keyword(s):  
Gel Electrophoresis ◽  
Normal Development ◽  
Allantoic Fluid ◽  
Dry Weight ◽  
Collagen Content ◽  
Fetal Membranes ◽  
Dexamethasone Treatment ◽  
Collagen Types ◽  
Volume Changes ◽  
Volume Increase

The tensile strength of fetal membranes is largely due to their collagen content. In this study we have examined the changes in collagen in the amniotic and allantoic membranes of the sheep over a wide gestational range (27–142 days of gestation; term, 145–150 days). The results have been correlated with volume changes in normal development, and in particular, the changes in allantois have been studied after a rapid and extensive increase in allantoic volume, as a result of maternal dexamethasone treatment (0·76 mg h-1 for 48 h) from Day 60 of gestation. Electron microscopy and immunohistochemistry were used to delineate collagen distribution, and gel electrophoresis was used to assess the relative proportions of each type. In the amnion, collagen content increased from 37±4% to 50±1% dry weight of the tissue from 41–102 days and declined slightly thereafter. In the allantois, collagen content increased from 20±1% at Day 27 to 50±6% at Day 142, significantly correlated with a volume increase from 253 mL to 813±274 mL. Collagen types I (>85%), III (10%) and small amounts of types IV and V (<5%) were identified in both membranes at all ages. When allantoic fluid volume was increased rapidly by maternal dexamethasone infusion, there was a significant decrease in collagen content from 38±6% to 25±2% (P < 0·05). By immunohistochemistry it was observed that both epithelial cells and fibroblasts were synthesizing collagen.

Agonist-induced cytoplasmic volume changes in cultured rabbit parietal cells

2000 ◽  
Vol 279 (1) ◽  
pp. G40-G48 ◽  
Author(s):  
Thorsten Sonnentag ◽  
Wolf-Kristian Siegel ◽  
Oliver Bachmann ◽  
Heidi Rossmann ◽  
Andreas Mack ◽  
...  
Keyword(s):  
Volume Regulation ◽  
Parietal Cells ◽  
Cell Swelling ◽  
Secretory Process ◽  
Cell Shrinkage ◽  
Rapid Loss ◽  
Volume Changes ◽  
Volume Increase ◽  
Regulatory Volume Increase ◽  
Stimulation Of

Concomitant Na+/H+ and Cl−/HCO3 − exchange activation occurs during stimulation of acid secretion in cultured rabbit parietal cells, possibly related to a necessity for volume regulation during the secretory process. We investigated whether cytoplasmic volume changes occur during secretagogue stimulation of cultured rabbit parietal cells. Cells were loaded with the fluorescent dye calcein, and the calcein concentration within a defined cytoplasmic volume was recorded by confocal microscopy. Forskolin at 10−5 M, carbachol at 10−4 M, and hyperosmolarity (400 mosmol) resulted in a rapid increase in the cytoplasmic dye concentration by 21 ± 6, 9 ± 4, and 23 ± 5%, respectively, indicative of cell shrinkage, followed by recovery to baseline within several minutes, indicative of regulatory volume increase (RVI). Depolarization by 5 mM barium resulted in a decrease of the cytoplasmic dye concentration by 10 ± 2%, indicative of cell swelling, with recovery within 15 min, and completely prevented forskolin- or carbachol-induced cytoplasmic shrinkage. Na+/H+ exchange inhibitors slightly reduced the initial cell shrinkage and significantly slowed the RVI, whereas 100 μM bumetanide had no significant effect on either parameter. We conclude that acid secretagoguges induce a rapid loss of parietal cell cytoplasmic volume, followed by RVI, which is predominantly mediated by Na+/H+ and Cl−/HCO3 − exchange.

Two-Phase Hygrothermal Diffusion in an Epoxy Adhesive

2006 ◽  
Vol 258-260 ◽  
pp. 453-460
Author(s):  
Sylvain Popineau ◽  
C. Rondeau-Mouro ◽  
Christine Sulpice-Gaillet ◽  
Martin E.R. Shanahan
Keyword(s):  
Water Uptake ◽  
Bound Water ◽  
Epoxy Adhesive ◽  
Mathematical Treatment ◽  
Water Decomposition ◽  
Two Phase ◽  
Gravimetric Data ◽  
Diffusion In Polymers ◽  
Two Phases ◽  
Mass Increase

Water diffusion in polymers can often be approximated by a Fickian description, but a 2- phase model was proposed some years ago by Carter and Kibler (C&K), often referred to as “Langmuirtype” diffusion, by analogy with the Langmuir theory of adsorption. The two phases in question correspond to “mobile” and “bound” diffusant molecules. In this study, we have considered water uptake in an epoxy resin (an adhesive), employing gravimetry. A good, overall, empirical agreement with the C&K mathematical description of total mass increase with time has been obtained. In many applications of the C&K theory when used to quantify diffusion of water in polymers, only total water uptake is considered as a datum. However, a simple mathematical treatment of the theory enables the separate mobile and bound contributions to be isolated. These supplementary data have been used to try to get a better understanding of the meaning of the terms “mobile” and “bound” phases. Deuterium NMR analysis has been employed to study the mobility of the absorbed water. Decomposition of spectra has permitted us to assign two signals to the fractions of “mobile” and “bound” water. Analysis of peak evolution and a comparison with gravimetric data lead us to suggest that the “mobile” phase corresponds to diffusing molecules, whereas the “bound” phase corresponds to “clusters”.

scholarly journals A thermodynamic formulation of root water uptake

2015 ◽  
Vol 12 (12) ◽  
pp. 13383-13413
Author(s):  
A. Hildebrandt ◽  
A. Kleidon ◽  
M. Bechmann
Keyword(s):  
Root System ◽  
Water Uptake ◽  
Water Distribution ◽  
Bound Water ◽  
Root Water Uptake ◽  
Flow Path ◽  
Thermodynamic Evaluation ◽  
Flux Boundary Condition ◽  
Physically Based ◽  
Energy Domain

Abstract. By extracting bound water from the soil and lifting it to the canopy, root systems of vegetation perform work. Here we describe how the energetics involved in root water uptake can be quantified. The illustration is done using a simple, four-box model of the soil-root system to represent heterogeneity and a parameterization in which root water uptake is driven by the xylem potential of the plant with a fixed flux boundary condition. We use this approach to evaluate the effects of soil moisture heterogeneity and root system properties on the dissipative losses and export of energy involved in root water uptake. For this, we derive an expression that relates the energy export at the root collar to a sum of terms that reflect all fluxes and storage changes along the flow path in thermodynamic terms. We conclude that such a thermodynamic evaluation of root water uptake conveniently provides insights into the impediments of different processes along the entire flow path and explicitly accounting not only for the resistances along the flow path and those imposed by soil drying but especially the role of heterogenous soil water distribution. The results show that least energy needs to be exported and dissipative losses are minimized by a root system if it extracts water uniformly from the soil. This has implications for plant water relations in forests where canopies generate heterogenous input patterns. Our diagnostic in the energy domain should be useful in future model applications for quantifying how plants can evolve towards greater efficiency in their structure and function, particularly in heterogenous soil environments. Generally, this approach may help to better describe heterogeneous processes in the soil in a simple, yet physically-based way.

scholarly journals Mechanisms of consistently disconnected soil water pools over (pore)space and time

2019 ◽  
Author(s):  
Matthias Sprenger ◽  
Pilar Llorens ◽  
Carles Cayuela ◽  
Francesc Gallart ◽  
Jérôme Latron
Keyword(s):  
Soil Water ◽  
Soil Depth ◽  
Stream Water ◽  
Pore Space ◽  
Bound Water ◽  
Subsurface Water ◽  
Data Set ◽  
Silty Loam ◽  
Scots Pine Forest ◽  
Soil Pores

Abstract. Storage and release of water in the soils is critical for sustaining plant transpiration and groundwater recharge. However, the subsurface mixing of water available for plants or quickly flowing to streams and groundwater is not yet understood. Moreover, while water infiltrating into soils was shown to bypass older pore water, the mechanisms leading to a separation between water routed to the streams and water held tightly in smaller pores are unclear. Here we present an extensive data set, for which we sampled fortnightly the isotopic composition (2H and 18O) of mobile and bulk soil water in parallel with groundwater, stream water and rainfall in the Mediterranean long-term research catchment, Vallcebre, in Spain. The data revealed that mobile and tightly bound water of a silty loam soil in a Scots pine forest do not mix, but they constitute two separate subsurface water pools; despite intense rainfall events leading to high soil wetness. We show that the isotopic compartmentation results from rewetting of small soil pores with isotopically depleted winter/spring rain. Thus, stable isotopes, and therefore water residence times too, do not only vary across soil depth, but also across soil pores. Our findings have important implications for stable isotope applications in ecohydrological studies assessing water uptake by plants or process realism of hydrological models, as the observed processes are currently rarely implemented in the simulation of water partitioning into evapotranspiration and recharge in the critical zone.

scholarly journals TRPing on Cell Swelling - TRPV4 Senses It

2021 ◽  
Vol 12 ◽  
Author(s):  
Trine L. Toft-Bertelsen ◽  
Nanna MacAulay
Keyword(s):  
Cell Volume ◽  
Transient Receptor Potential ◽  
Current Knowledge ◽  
Receptor Potential ◽  
Cell Swelling ◽  
Transient Receptor Potential Vanilloid ◽  
Volume Changes ◽  
Channel Activation ◽  
Volume Increase ◽  
Transient Receptor

The transient receptor potential vanilloid 4 channel (TRPV4) is a non-selective cation channel that is widely expressed and activated by a range of stimuli. Amongst these stimuli, changes in cell volume feature as a prominent regulator of TRPV4 activity with cell swelling leading to channel activation. In experimental settings based on abrupt introduction of large osmotic gradients, TRPV4 activation requires co-expression of an aquaporin (AQP) to facilitate such cell swelling. However, TRPV4 readily responds to cell volume increase irrespectively of the molecular mechanism underlying the cell swelling and can, as such, be considered a sensor of increased cell volume. In this review, we will discuss the proposed events underlying the molecular coupling from cell swelling to channel activation and present the evidence of direct versus indirect swelling-activation of TRPV4. With this summary of the current knowledge of TRPV4 and its ability to sense cell volume changes, we hope to stimulate further experimental efforts in this area of research to clarify TRPV4’s role in physiology and pathophysiology.

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