scholarly journals THE STRUCTURE OF THE COLLODION MEMBRANE AND ITS ELECTRICAL BEHAVIOR

1941 ◽  
Vol 24 (4) ◽  
pp. 467-482 ◽  
Author(s):  
Karl Sollner ◽  
Irving Abrams ◽  
Charles W. Carr
Keyword(s):  
Sulfuric Acid ◽  
Partial Oxidation ◽  
Electrochemical Behavior ◽  
Ion Adsorption ◽  
Electrical Behavior ◽  
Strong Electrolytes ◽  
Acidic Nature ◽  
A Minor ◽  
Very High ◽  
Acid Esters

1. The electrochemical behavior of membranes prepared from commercial collodion preparations varies widely, some preparations showing very high, other ones very low electrochemical efficiency ("activity"). 2. The electrochemical activity of a collodion membrane depends entirely upon impurities of an acidic nature contained in the collodion used for casting the membrane. 3. The active acidic impurities are substantially due to partial oxidation which occurs in the manufacturing process. Sulfuric acid compounds; e.g., acid sulfuric acid esters play only a minor rôle, if any. 4. The electrochemical behavior of collodion membranes in solutions of strong electrolytes is decisively dependent upon the acidic groups built permanently into the collodion surfaces. Preferential ion adsorption plays only a minor, if any, rôle.

scholarly journals ENZYMATIC SYSTEM SYNTHESIZING SULFURIC ACID ESTERS OF PHENOLS

1955 ◽  
Vol 213 (1) ◽  
pp. 439-443 ◽  
Author(s):  
R.H. De Meio ◽  
Martha Wizerkaniuk ◽  
I. Schreibman
Keyword(s):  
Sulfuric Acid ◽  
Enzymatic System ◽  
Acid Esters

scholarly journals Idiotypic analysis of potential and available repertoires in the arsonate system.

1984 ◽  
Vol 160 (1) ◽  
pp. 1-11 ◽  
Author(s):  
M Slaoui ◽  
O Leo ◽  
J Marvel ◽  
M Moser ◽  
J Hiernaux ◽  
...  
Keyword(s):  
Monoclonal Antibody ◽  
B Cells ◽  
Keyhole Limpet Hemocyanin ◽  
High Frequencies ◽  
Specific Subset ◽  
A Minor ◽  
Very High Frequencies ◽  
Very High ◽  
Limiting Dilution

We have shown that, by suitable idiotypic manipulation, BALB/c mice can express the major cross-reactive idiotype (CRI) of A/J mice in response to azophenylarsonate (Ars). In order to know if the CRIA idiotype is present in the potential repertoire of BALB/c before any intentional selection, we used polyclonal activation in vitro and limiting dilution analysis. The readout was done with two monoclonal anti-CRIA antibodies that recognize distinct idiotopes on a CRIA+ A/J germline-encoded monoclonal antibody. We studied the frequency of CRIA+ lipopolysaccharide (LPS)-reactive cells in the spleens of nonimmune and immune A/J mice and in the spleens of naive and manipulated (i.e., producing CRIA+ antibodies) BALB/c mice. A/J and BALB/c naive individuals presented very high frequencies of Ars-specific B cells while the frequency of CRIA+ B cells was only a minor subset (0.5%) of the total Ars-specific subset in the two strains. When A/J mice were immunized with Ars-keyhole limpet hemocyanin, a clear preferential expansion of the CRIA+ minor subset of A/J mice was observed (100x). No such enhancement was observed in BALB/c mice similarly treated. Manipulated BALB/c mice presented a higher frequency of CRIA+ anti-Ars B cells than naive or antigen-immunized BALB/c individuals.

Electrochemical Behavior of Silicon in Light and Dark Environments in 0.5 M Sulfuric Acid

2015 ◽  
pp. 777-786
Author(s):  
M. Bounoughaz ◽  
H. Boukercha ◽  
A. Khemmari ◽  
M. Allaoua ◽  
E. Salhi
Keyword(s):  
Sulfuric Acid ◽  
Electrochemical Behavior

Prediction and Measurement of Corrosion Rates of Stainless Steel in Concentrated Sulfuric Acid

CORROSION ◽  
10.5006/0709 ◽  
2013 ◽  
Vol 69 (6) ◽  
pp. 543-550 ◽  
Author(s):  
S. Jones ◽  
K. Coley ◽  
J. Kish
Keyword(s):  
Stainless Steel ◽  
Sulfuric Acid ◽  
Corrosion Behavior ◽  
Electrochemical Behavior ◽  
Open Circuit Potential ◽  
Electrochemical Techniques ◽  
Open Circuit ◽  
Corrosion Rates ◽  
Transient Nature ◽  
Concentrated Sulfuric Acid

When exposed to concentrated sulfuric acid, stainless steel exhibits unique electrochemical behavior. This behavior can be observed as an oscillation in open-circuit potential between the active and passive states. The transient nature of the corrosion behavior under these conditions results in a distinct challenge for measuring and predicting corrosion rates. Using a series of commercial alloys with various nickel contents, this paper outlines the utilization of electrochemical experimentation to refine the prediction of corrosion rates. The paper also discusses some of the difficulties associated with many traditional electrochemical techniques such as potentiodynamic scans when used for characterizing systems that undergo oscillations in open-circuit potential.

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