Isoperibolic Calorimetric Cell with Electronic Integrator Circuit for Temperature Measurement

2005 ◽  
Vol 33 (1) ◽  
pp. 61-71 ◽  
Author(s):  
Paola Martínez ◽  
Liliana Giraldo ◽  
Edgar Vargas ◽  
Juan Carlos Moreno
2019 ◽  
Author(s):  
Melvin Miles

Equations developed for isoperibolic electrochemical calorimetry were tested for the electrolysis of D2O in an open calorimetric cell. The derivatives of these equations gave correct values within the experimental error range for the important rate of change of the cell temperature with time (dT/dt). In addition, these calorimetric equations were also tested directly in determining the enthalpy change (ΔH) for the D2O electrolysis reaction. The mean experimental value at 298.15 K was ΔH = 294.4 ± 0.3 kJ/mole. This compares favorably (within 0.10%) with the literature value of ΔH = 294.600 kJ/mole. The accuracy of these ΔH measurements could be even further improved by more accurate cell voltage and cell temperature measurement. <br>


2019 ◽  
Author(s):  
Melvin Miles

Equations developed for isoperibolic electrochemical calorimetry were tested for the electrolysis of D2O in an open calorimetric cell. The derivatives of these equations gave correct values within the experimental error range for the important rate of change of the cell temperature with time (dT/dt). In addition, these calorimetric equations were also tested directly in determining the enthalpy change (ΔH) for the D2O electrolysis reaction. The mean experimental value at 298.15 K was ΔH = 294.4 ± 0.3 kJ/mole. This compares favorably (within 0.10%) with the literature value of ΔH = 294.600 kJ/mole. The accuracy of these ΔH measurements could be even further improved by more accurate cell voltage and cell temperature measurement. <br>


1997 ◽  
Vol 7 (9) ◽  
pp. 1893-1898 ◽  
Author(s):  
G. Schirripa Spagnolo ◽  
D. Ambrosini ◽  
A. Ponticiello ◽  
D. Paoletti

2015 ◽  
Vol 135 (10) ◽  
pp. 1205-1209
Author(s):  
Suguru Nakamura ◽  
Masamichi Nakamura ◽  
Eiichi Maeda ◽  
Yoshio Nikawa

Author(s):  
S. Abanades ◽  
J. M. Badie ◽  
Gilles Flamant ◽  
L. Fulcheri ◽  
J. Gonzales-Aguilar ◽  
...  

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