Crystal Structure and Physical Properties of BEDT-TTF (bis(ethylenedithio)tetrathiafulvalene) Salt Coupled with a Photo-Sensitive Transition Metal Complex

2002 ◽  
Vol 376 (1) ◽  
pp. 147-152 ◽  
Author(s):  
Masashi Ohkubo ◽  
Tokutaro Komatsu ◽  
Nobuyuki Matsushita ◽  
Norimichi Kojima ◽  
Gunzi Saito
Keyword(s):  
Crystal Structure ◽  
Transition Metal ◽  
Metal Complex ◽  
Physical Properties ◽  
Transition Metal Complex

scholarly journals Crystal and molecular structure of the binuclear Rh(I) complex (μ-Cl)(μ-pz) [Rh(CO)2]2 (pz = pyrazolyl, N2C3H3). An example of molecular stacking via weak intermolecular interactions

1985 ◽  
Vol 63 (3) ◽  
pp. 688-691 ◽  
Author(s):  
Brenda M. Louie ◽  
Steven J. Rettig ◽  
Alan Storr ◽  
James Trotter
Keyword(s):  
Molecular Structure ◽  
Transition Metal ◽  
Metal Complex ◽  
Physical Properties ◽  
Transition Metal Complex ◽  
Crystal And Molecular Structure ◽  
Heavy Atom ◽  
Full Matrix ◽  
Weak Intermolecular Interactions ◽  
Molecular Stacking

Details of the synthesis and physical properties of (μ-Cl)(μ-pz)[Rh(CO)2]2 are given. Crystals of (μ-chloro) (μ-pyrazolyl)-bis(dicarbonylrhodiumd(I)) are monoclinic, a = 7.0970(8), b = 20.5184(10), c = 15.808(2) Å, β = 94.695(6)°, Z = 8, space group P21/c. The structure was solved by conventional heavy-atom methods and was refined by full-matrix least-squares procedures to R = 0.035 and Rw = 0.038 for 2949 reflections with I ≥ 3σ(I). The complex provides a rare example of molecular stacking in a binuclear transition metal complex with [Formula: see text] distances of 3.5107(8) and 3.6201(8) Å.

scholarly journals The First Chelate-Free Crystal Structure of a Silicide Transition Metal Complex [K0.28Rb7.72Si9Ni(CO)2]2·16NH3

Crystals ◽  
2015 ◽  
Vol 5 (3) ◽  
pp. 275-282 ◽  
Author(s):  
Stefanie Gärtner ◽  
Markus Hamberger ◽  
Nikolaus Korber
Keyword(s):  
Crystal Structure ◽  
Transition Metal ◽  
Metal Complex ◽  
Transition Metal Complex
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