Synthesis, Crystal Structure and Magnetic Properties of a 1D Mono‐μ1,3‐NCS− Bridged Ni(II) Chain Complex with N1,N3‐bis(4‐methoxylbenzyl)‐diethylenetriamine

Author(s):  
Xue‐Ting Liu ◽  
Yong‐Shu Xie ◽  
Qing‐Liang Liu
Polyhedron ◽  
1997 ◽  
Vol 16 (9) ◽  
pp. 1411-1415 ◽  
Author(s):  
Xiang Shi Tan ◽  
Feng Xiang Dao ◽  
Xia Tang Wen ◽  
Bei Yu Kai

2009 ◽  
Vol 4 (1) ◽  
pp. 90-96
Author(s):  
Hideaki Ishida ◽  
Makoto Handa ◽  
Ichiro Hiromitsu ◽  
Masahiro Mikuriya

A chloro-bridged chain complex constructed from paddlewheel-type dinuclear ruthenium(II,III) carboxylate units, [Ru2{3,4,5-(C2H5O)3C6H2CO2}4Cl]n·1.2nC2H5OH (1·1.2nC2H5OH), was synthesized and characterized by elemental analysis and IR and UV-vis spectroscopies. The single-crystal X-ray analysis showed that the complex forms a zig-zag chain structure, in which the chloroligands bridge the dinuclear units at the axial positions with the Ru1–Cl–Ru2 angle of 120.38(7)°. A broad band around 1144 nm and a band at 475 nm were observed in the diffused reflectance spectra and ascribed to a δ→δ* and a π(RuO, Ru2)→π*(Ru2) transitions, respectively. Temperature dependence of magnetic susceptibility showed that the antiferromagnetic interaction between the dinuclear units is weak (zJ = −0.8 cm−1) with D value of 60 cm−1.


Author(s):  
José Suárez-Varela ◽  
José M. Dominguez-Vera ◽  
Enrique Colacio ◽  
Juan C. Avila-Rosón ◽  
Miguel A. Hidalgo ◽  
...  

2016 ◽  
Vol 1123 ◽  
pp. 400-406 ◽  
Author(s):  
Abdelhakim Laachir ◽  
Salaheddine Guesmi ◽  
Mohamed Saadi ◽  
Lahcen El Ammari ◽  
Olivier Mentré ◽  
...  

1997 ◽  
Vol 255 (1) ◽  
pp. 157-161 ◽  
Author(s):  
Xiang Shi Tan ◽  
Jie Sun ◽  
Dao Feng Xiang ◽  
Wen Xia Tang

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