Dynamical Behavior of Liquid Crystals Containing Dispersed Silica Particles Near Sm A - N and N - I Phase Transitions

1999 ◽  
Vol 331 (1) ◽  
pp. 81-87 ◽  
Author(s):  
A. Mertelj ◽  
A. Jákli ◽  
M. Ĉopiĉ
Keyword(s):  
Phase Transitions ◽  
Liquid Crystals ◽  
Dynamical Behavior ◽  
Silica Particles

Optical Properties and Phenomenological Theory of Ferri-Ferri Phase Transitions in Antiferroelectric Liquid Crystals

1997 ◽  
Vol 7 (12) ◽  
pp. 1817-1828 ◽  
Author(s):  
P. Gisse ◽  
M. Sidir ◽  
V. L. Lorman ◽  
R. Farhi ◽  
J. Pavel ◽  
...  
Keyword(s):  
Optical Properties ◽  
Phase Transitions ◽  
Liquid Crystals ◽  
Phenomenological Theory ◽  
Antiferroelectric Liquid Crystals

HIGH RESOLUTION CALORIMETRIC STUDIES AT PHASE TRANSITIONS OF ALKYLCYANOBIPHENYL LIQUID CRYSTALS CONFINED TO SUBMICRON SIZE CYLINDRICAL CAVITIES

1995 ◽  
Vol 09 (18n19) ◽  
pp. 2247-2283 ◽  
Author(s):  
DANIELE FINOTELLO ◽  
GERMANO S. IANNACCHIONE
Keyword(s):  
Phase Transitions ◽  
Liquid Crystals ◽  
High Resolution ◽  
Specific Heat ◽  
Pore Wall ◽  
Isotropic Phase ◽  
First Order ◽  
Smectic A ◽  
Nematic Director ◽  
Scalar Order Parameter

We review results of a high resolution systematic study of the specific heat for alkyl-cyanobiphenyl liquid crystals confined to the 0.2µm diameter cylindrical pores Anopore membranes. The nematic director alignment at the pore wall is varied from homeotropic to tangential by pore surface treatment. Several phenomena are uncovered by these studies which probed the weakly first order nematic to isotropic, the continuous smectic-A to nematic and the first order smectic-A to isotropic phase transitions. The specific heat is strongly dependent on the nematic director configuration, and confinement effects are remarkably distinct according to the order of the phase transition. The influence of elastic distortions and surface ordering and disordering effects are evident. Despite considerable departures from bulk behavior with regards to specific heat peaks size, rounding and width, and transition temperature shifts, a bulk-like critical behavior appears to be retained. The formation of smectic translational order within the pores is hindered for those liquid crystals that also possess a nematic phase. The average scalar order parameter temperature dependence is extracted from the specific heat results using a simplified Landau-de Gennes type of model, and is shown to be consistent with nuclear magnetic resonance results.

scholarly journals Liquid crystal phase transitions in suspensions of mineral colloids: new life from old roots

2013 ◽  
Vol 371 (1988) ◽  
pp. 20120263 ◽  
Author(s):  
H. N. W. Lekkerkerker ◽  
G. J. Vroege
Keyword(s):  
Phase Transitions ◽  
Liquid Crystal ◽  
Liquid Crystals ◽  
Colloidal Suspensions ◽  
Crystal Phase ◽  
Liquid Crystal Phase ◽  
Future Developments ◽  
Mineral Particles ◽  
Crystal Phases ◽  
Liquid Crystal Phases

A review is given of the field of mineral colloidal liquid crystals : liquid crystal phases formed by individual mineral particles within colloidal suspensions. Starting from their discovery in the 1920s, we discuss developments on the levels of both fundamentals and applications. We conclude by highlighting some promising results from recent years, which may point the way towards future developments.

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