Remediation of Soils Polluted by Heavy Metals using Salts of Organic Acids and Chelating Agents

1998 ◽  
Vol 19 (4) ◽  
pp. 369-379 ◽  
Author(s):  
S. A. Wasay ◽  
S. F. Barrington ◽  
S. Tokunaga
2021 ◽  
Vol 11 (4) ◽  
pp. 1799
Author(s):  
Claudio Cameselle ◽  
Susana Gouveia ◽  
Adrian Cabo

The electrokinetic remediation of an agricultural soil contaminated with heavy metals was studied using organic acids as facilitating agents. The unenhanced electrokinetic treatment using deionized water as processing fluid did not show any significant mobilization and removal of heavy metals due to the low solubilization of metals and precipitation at high pH conditions close to the cathode. EDTA and citric acid 0.1 M were used as facilitating agents to favor the dissolution and transportation of metals. The organic acids were added to the catholyte and penetrated into the soil specimen by electromigration. EDTA formed negatively charged complexes. Citric acid formed neutral metal complexes in the soil pH conditions (pH = 2–4). Citric acid was much more effective in the dissolution and transportation out of the soil specimen of complexed metals. In order to enhance the removal of metals, the concentration of citric acid was increased up to 0.5 M, resulting in the removal of 78.7% of Cd, 78.6% of Co, 72.5% of Cu, 73.3% of Zn, 11.8% of Cr and 9.8% of Pb.


2007 ◽  
Vol 43 (4) ◽  
pp. 200-206 ◽  
Author(s):  
Alessia Cao ◽  
Alessandra Carucci ◽  
Tiziana Lai ◽  
Paolo La Colla ◽  
Elena Tamburini

1995 ◽  
Vol 41 (2-3) ◽  
pp. 135-145 ◽  
Author(s):  
S.R. Burckhard ◽  
A.P. Schwab ◽  
M.K. Banks

2012 ◽  
Vol 518-523 ◽  
pp. 5040-5046 ◽  
Author(s):  
Li Di Gao ◽  
Naoki Kano ◽  
Yuichi Sato ◽  
Shuang Zhang ◽  
Hiroshi Imaizumi

Effect of EDTA and EDDS on phytoremediation of Pb- and Zn- contaminated soil by Brassica Juncea was investigated in this work. Especially, the effect of the kind and the method of adding chelating agent was investigated during the plant growth. Plants were grown in an environmental control system. The biomass of the whole plant was weighed, and the uptake of Pb and Zn in shoot and root were determined using ICP-AES. Consequently, the following matters have been obtained: (1) Both EDTA and EDDS significantly enhanced the translocation of metals (Pb and Zn) in soil from root to shoot. Furthermore, the two chelating agents resulted in a sharply biomass loss for more than 30% of the control. As a result, the total uptake amount of metals by Brassica Juncea was decreased (except the uptake of Pb with the addition of 3.0 mmol•kg-1 EDTA). (2) EDDS showed the higher inhibition for the growth of Brassica Juncea than EDTA. (3) The method for adding EDTA and EDDS at several times separately did not necessarily increase the uptake of heavy metals.


Author(s):  
Khushboo Chaudhary ◽  
Suphiya Khan ◽  
Pankaj Kumar Saraswat

The heavy metal pollution problem is all over the world. Plant-growth-promoting bacteria (PGPB) has transformed heavy metals present in the soil, which removes and minimizes their toxic effects. This chapter highlights the role of plant-growth-promoting bacteria, chelating agents, and nanoparticles for remediation of heavy metals; their mechanism of action; and their applications approach of hyperaccumulation. Therefore, this chapter focuses on the mechanisms by which microorganisms, chelating agents, and nanoparticles can mobilize or immobilize metals in soils and the nano-phytoremediation strategies are addressed for the improvement of phytoextraction as an innovative process for enhancement of heavy metals removal from soil.


2020 ◽  
Vol 231 (12) ◽  
Author(s):  
Carlos Roberto Irias Zelaya ◽  
Janine Colares Gadelha ◽  
Fernando Felipe Ferreyra Hernandez ◽  
Maria Eugenia Ortiz Escobar

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