scholarly journals Crystal Structures of Δ1-Piperideine-2-carboxylate/Δ1-Pyrroline-2-carboxylate Reductase Belonging to a New Family of NAD(P)H-dependent Oxidoreductases

2005 ◽  
Vol 280 (49) ◽  
pp. 40875-40884 ◽  
Author(s):  
Masaru Goto ◽  
Hisashi Muramatsu ◽  
Hisaaki Mihara ◽  
Tatsuo Kurihara ◽  
Nobuyoshi Esaki ◽  
...  
Keyword(s):  
Crystal Structures ◽  
New Family ◽  
Carboxylate Reductase

Halogen-bonding in a new family of tris(haloanilato)metallate(iii) magnetic molecular building blocks

2014 ◽  
Vol 43 (19) ◽  
pp. 7006-7019 ◽  
Author(s):  
Matteo Atzori ◽  
Flavia Artizzu ◽  
Elisa Sessini ◽  
Luciano Marchiò ◽  
Danilo Loche ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Dft Calculations ◽  
Crystal Structures ◽  
General Formula ◽  
Halogen Bonding ◽  
Building Blocks ◽  
New Family ◽  
Molecular Building Blocks

Here we report on new tris(haloanilato)metallate(iii) complexes with general formula [M(X2An)3]3−, their crystal structures, DFT calculations and magnetic properties.

scholarly journals Iron(III) Azadiphenolate Compounds in a New Family of Spin Crossover Iron(II)–Iron(III) Mixed-Valent Complexes

2019 ◽  
Vol 5 (2) ◽  
pp. 37 ◽  
Author(s):  
Wasinee Phonsri ◽  
David S. Macedo ◽  
Barnaby A. I. Lewis ◽  
Declan F. Wain ◽  
Keith S. Murray
Keyword(s):  
Crystal Structures ◽  
Spin Crossover ◽  
Crystal Packing ◽  
Spin Transition ◽  
Double Salt ◽  
Magnetic Studies ◽  
Cationic Precursor ◽  
New Family ◽  
Double Spin ◽  
Crystal Design

A new family of mixed valent, double salt spin crossover compounds containing anionic FeIII and cationic FeII compounds i.e., [FeII{(pz)3CH}2][FeIII(azp)2]2·2H2O (4), [FeII(TPPZ)2][FeIII(azp)2]2]·H2O (5) and [FeII(TPPZ)2][FeIII(azp)2]2]·H2O·3MeCN (6) (where (pz)3CH = tris-pyrazolylmethane, TPPZ = 2,3,5,6, tetrapyridylpyrazine and azp2− = azadiphenolato) has been synthesized and characterised. This is the first time that the rare anionic spin crossover species, [FeIII(azp)2]−, has been used as an anionic component in double salts complexes. Single crystal structures and magnetic studies showed that compound 6 exhibits a spin transition relating to one of the FeIII centres of the constituent FeII and FeIII sites. Crystal structures of the anionic and cationic precursor complexes were also analysed and compared to the double salt products thus providing a clearer picture for future crystal design in double spin crossover materials. We discuss the effects that the solvent and counterion had on the crystal packing and spin crossover properties.

A new family of multinuclear mixed-ligand copper(II) clusters: Crystal structures, magnetic properties and catecholase-like activity

2016 ◽  
Vol 453 ◽  
pp. 104-114 ◽  
Author(s):  
Sergiu Calancea ◽  
Samira G. Reis ◽  
Guilherme P. Guedes ◽  
Rafael A. Allão Cassaro ◽  
Felipe Semaan ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Crystal Structures ◽  
Mixed Ligand ◽  
New Family

Synthesis, Crystal Structures, and Magnetic Properties of a New Family of Heterometallic Cyanide-Bridged FeIII2MII2(M = Mn, Ni, and Co) Square Complexes

2011 ◽  
Vol 50 (13) ◽  
pp. 6250-6262 ◽  
Author(s):  
Emilio Pardo ◽  
Michel Verdaguer ◽  
Patrick Herson ◽  
Helene Rousselière ◽  
Joan Cano ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Crystal Structures ◽  
New Family
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