Phosphorus sorption in relation to soil properties for the major soil types of South-Western Australia

Soil Research ◽  
1991 ◽  
Vol 29 (5) ◽  
pp. 603 ◽  
Author(s):  
B Singh ◽  
RJ Gilkes
Keyword(s):  
Regression Analysis ◽  
Western Australia ◽  
Stepwise Regression ◽  
Clay Content ◽  
Soil Types ◽  
Phosphorus Sorption ◽  
P Sorption ◽  
Agricultural Areas ◽  
Langmuir And Freundlich Equations ◽  
Sorption Characteristics

The P sorption characteristics of 97 soils that are representative of the agricultural areas of Western Australia were described using Langmuir and Freundlich equations. The Langmuir P maximum (xm) ranged from 11 to 2132 �g g-1 soil and the Freundlich k coefficient ranged from 1 to 1681. Clay content, DCB Fe and Al, oxalate Fe and AL, and pyrophosphate Al were positively related to xm and k. By using stepwise regression analysis, the combination of DCB and oxalate-soluble A1 predicted more than 75% Of the variation in the P sorption coefficients. Reactive Al compounds may thus be responsible for much of the P sorption by these soils. Soil pH in 1 M NaF (pH 8.2), which is normally used for the detection of allophanic material, was strongly related to the P sorption coefficients and might therefore be used as a quick test for predicting the P sorption capacity of soils.

scholarly journals Phosphorus Sorption Characteristics of Luvisols and Nitisols in North Ethiopian Soils

2021 ◽  
Vol 2021 ◽  
pp. 1-7
Author(s):  
Ashebir Getie ◽  
Alemayehu Kiflu ◽  
Gashaw Meteke
Keyword(s):  
Clay Content ◽  
Fertilizer Application ◽  
Application Rate ◽  
Soil Types ◽  
Phosphorus Sorption ◽  
Sorption Data ◽  
P Sorption ◽  
Fertilizer Application Rate ◽  
P Fertilizer ◽  
Sorption Parameters

Crop response to phosphorus (P) application is often erratic in most acidic soil types. The main processes for P losses from agricultural fields are fixation, crop removal, erosion, surface runoff, and subsurface leaching. The purpose of this experiment was to evaluate adsorption properties of selected soils, determine the external phosphorous requirements (EPRs) of the soils, and identify factors contributing to P sorption in two soils in North Ethiopia. In this experiment, separately weighed 1 g soil samples were equilibrated with KH2PO4 at rates of 0.5, 5, 10, 20, 30, 40, and 50 mg PL−1. The P sorption data were fitted well with both Langmuir and Freundlich models with average r2 values of 0.91 and 0.88, respectively. The adsorption maximum (Xm) of the Langmuir isotherm ranged from 588.20 mg P kg−1 soil in Luvisols to 833.3 mg P kg−1 soil in Nitisols. The EPRL values ranged between 86.20 to 93.28 mg P kg−1 for soils of the study area. Among the soil properties, clay content and Ex. Al were positively correlated with Xm. The path analysis revealed that clay, pH, and Av. P had a direct effect on P sorption parameters. The EPRL of the studied soils was 3.44 to 3.6 times greater than the blanket P fertilizer rate recommendation. It is concluded that P sorption models can effectively be used to discriminate soils based on P fixation ability. The result further indicates that the current P fertilizer application rate of 50 kg P ha−1 being practiced across all soil types should be revised after validating the models and EPR values estimated in this study for each soil both under greenhouse and in-the-field conditions.

Extractable iron and aluminium predict the P sorption capacity of Thai soils

Soil Research ◽  
2005 ◽  
Vol 43 (6) ◽  
pp. 757 ◽  
Author(s):  
W. Wiriyakitnateekul ◽  
A. Suddhiprakarn ◽  
I. Kheuruenromne ◽  
R. J. Gilkes
Keyword(s):  
Sorption Capacity ◽  
Stepwise Regression ◽  
Clay Content ◽  
Langmuir Equation ◽  
Soil Types ◽  
Sorption Data ◽  
P Sorption ◽  
P Sorption Capacity ◽  
Freundlich Equation ◽  
Extractable Iron

The objective of this study was to determine if dithionite- and oxalate-extractable Fe and Al can be used to predict the P sorption capacity of Thai soils. Forty-five samples from diverse soil types were taken from surface and subsurface horizons of soils on sandstone, shale/limestone, granite, and basalt. The samples were analysed for P sorption, dithionite- and oxalate-extractable Fe and Al (Fed, Feo, Ald, Alo), specific surface area (SSA), and other soil properties. Generally P sorption data for these soils were slightly better fitted by the Langmuir equation than the Freundlich equation. The Langmuir P sorption maximum ranged from 35 to 1111 μg/g with a median value of 370 μg/g soil. Soils developed on basalt had higher values of P sorption maximum (xm) (range 400–1111 μg/g, median 597 μg/g) than soils on other parent materials. Fed concentrations in soils (4–74 g/kg) were much higher than Feo concentrations (0.2–13.8 g/kg) with values of Feo/Fed ranging from 0.01 to 0.28 (median 0.09), indicating that most of the free iron oxides were crystalline. Amounts of Ald and Alo were about equal with median values of 1.6 and 1.0 g/kg, respectively. About 80% of the samples had SSA values <40 m2/g. Both the P sorption maximum and Freundlich k were linearly related to SSA (R2 = 0.77, 0.74), Ald (R2 = 0.78, 0.79), Alo (R2 = 0.64, 0.74), Fed (R2 = 0.48, 0.41), Feo (R2 = 0.43, 0.72), and clay content (R2 = 0.48, 0.36). Stepwise regression indicated that 81% of the variability in P sorption by these soils could be explained by a combination of dithionite and oxalate Fe and Al, however, Ald alone is almost as effective in predicting the P sorption capacity of Thai soils.

scholarly journals Phosphorus sorption characteristics of some representative soils of south India

2015 ◽  
Vol 13 (1) ◽  
pp. 14-26 ◽  
Author(s):  
I Rashmi ◽  
AK Biswas ◽  
VRR Parama ◽  
AS Rao
Keyword(s):  
Soil Solution ◽  
Management Strategies ◽  
Phosphorus Sorption ◽  
Binding Strength ◽  
P Sorption ◽  
Strength Coefficient ◽  
P Fertilizer ◽  
Phosphorus Buffering Capacity ◽  
Langmuir And Freundlich Equations ◽  
Sorption Characteristics

Studies were conducted to investigate P sorption characteristics of representative soils from ten locations of alfisol and ultisol of India using Langmuir and Freundlich equations. The P sorption maxima (b) of soils derived from Langmuir equation in alfisol varied from 520.6 to 574.7 ?g g-1 and ultisol varied from 561.6 to 678.1 ?g g-1. The maximum phosphorus buffering capacity (MPBC) in alfisol ranged from 80.7 to 180.2 ml ?g-1 and ultisol ranged from 162.1 to 284.4 ml ?g-1. Phosphorus sorption maxima was significantly correlated with clay (r2=0.70), Al (r2= 0.73) and Fe (r2=0.81) forms, MPBC (r2=0.67) and Freundlich constants (r2=0.82). The standard P requirement (SPR) to maintain 0.2 mg l-1 P in soil solution for alfisol ranged from 15.62 to 27.62 mg kg-1 and ultisol from 41.98 to 46.35 mg kg-1. The SPR (0.2 mg l-1) was significantly correlated with binding strength coefficient (r2= 0.97) and binding strength coefficient supporting the fact that energy coefficient of a soil is an important index for planning P management strategies. Among the two soil orders in order to maintain optimum P concentration in soil solution for crop growth, ultisol will be required to supply with more P fertilizer as compared to alfisol.SAARC J. Agri., 13(1): 14-26 (2015)

scholarly journals Phosphorus sorption on tropical soils with relevance to Earth system model needs

Soil Research ◽  
2019 ◽  
Vol 57 (1) ◽  
pp. 17 ◽  
Author(s):  
Julia Brenner ◽  
Wesley Porter ◽  
Jana R. Phillips ◽  
Joanne Childs ◽  
Xiaojuan Yang ◽  
...  
Keyword(s):  
Sorption Isotherms ◽  
Clay Content ◽  
Tropical Soils ◽  
Soil Characteristics ◽  
P Availability ◽  
Earth System ◽  
Phosphorus Sorption ◽  
Soil P ◽  
P Sorption ◽  
Earth System Models

Phosphorus (P) availability critically limits the productivity of tropical forests growing on highly weathered, low-P soils. Although efforts to incorporate P into Earth system models (ESMs) provide an opportunity to better estimate tropical forest response to climate change, P sorption dynamics and controls on soil P availability are not well constrained. Here, we measured P and dissolved organic carbon (DOC) sorption isotherms on 23 soils from tropical Oxisol, Ultisol, Inceptisol, Andisol, and Aridisol soils using P concentrations from 10 to 500mg P L−1, and DOC concentrations from 10 to 100mg DOC L−1. Isotherms were fit to the Langmuir equation and parameters were related to soil characteristics. Maximum P sorption capacity (Qmax) was significantly correlated with clay content (ρ=0.658) and aluminium (Al)- or iron (Fe)-oxide concentrations (ρ=0.470 and 0.461 respectively), and the DOC Qmax was correlated with Fe oxides (ρ=0.491). Readily available soil characteristics could eventually be used to estimate Qmax values. Analysis of literature values demonstrated that the maximum initial P concentration added to soils had a significant impact on the resultant Qmax, suggesting that an insufficiently low initial P range could underestimate Qmax. This study improves methods for measuring P Qmax and estimating Qmax in the absence of isotherm analyses and provides key data for use in ESMs.

Influence of biosolids on phosphorus sorption characteristics of a Vertisol in comparison with manures and fertilizer

2007 ◽  
Vol 87 (5) ◽  
pp. 511-521 ◽  
Author(s):  
Babasola Ajiboye ◽  
Olalekan O Akinremi ◽  
Geza J Racz ◽  
Donald N Flaten
Keyword(s):  
Sorption Isotherm ◽  
Single Point ◽  
Chemical Properties ◽  
Similar Proportion ◽  
Phosphorus Sorption ◽  
P Sorption ◽  
P Loss ◽  
Degree Of P Saturation ◽  
Labile P ◽  
Sorption Characteristics

Regulation of manure application in Manitoba has raised the question of whether or not biosolids application should be regulated in the same way. This study examined the effects of biosolids (BIO) applications on P sorption characteristics of a Vertisol in comparison with dairy cattle (DAIRY) and hog (HOG) manures, and monoammonium phosphate (MAP) fertilizer using the classical sorption isotherm and single point sorption index. Pertinent chemical properties and degree of P saturation (DPS) were also determined. The sorption maximum (Smax) in the control was reduced from 655 mg kg-1, to a range of 536–655 mg kg-1 with BIO, 559–650 mg kg-1 with MAP, 402–568 mg kg-1 with DAIRY, and 350–587 mg kg-1 with HOG depending upon the rate of P added. The lower DPS in the soil amended with BIO suggests a lower risk of P loss with biosolids compared with manures. The higher P sorption capacity of biosolids-amended soils compared with soils amended with manures suggest that Ca added with BIO increased the number of P sorption sites by a similar proportion to the amount of P added. Key words: Biosolids, P sorption isotherm, degree of P saturation, labile P, non-labile P

scholarly journals The Effect of Calcium Silicate on The Phosphorus Sorption Characteristics of Andisols Lembang West Java

2008 ◽  
Vol 10 (1) ◽  
pp. 14-19 ◽  
Author(s):  
Arief Hartono
Keyword(s):  
Calcium Silicate ◽  
Dry Weight ◽  
Phosphorus Sorption ◽  
Sorption Kinetic ◽  
Sorption Data ◽  
Kinetic Experiment ◽  
P Sorption ◽  
Randomized Design ◽  
Set Up ◽  
Sorption Characteristics

The effect of calcium silicate CaSiOJ the phosphorus (P) sorption characteristics were studied in Andisols Lembang.The amount of 0, 2.5 and 5% CaSiOJ (calcium silicate) or 0, 7.5 and 15 g calcium silicate per pot was added to the 300 g(oven-dry weight) soil and incubated for one month. A completely randomized design in double replication was set up. After one month incubation, P sorption and P sorption kinetic experiments were conducted The results of P sorption experiment showed that P sorption data were satisfactorily described by the Langmuir equation. which was used to determine P sorption maxima, bonding energies and P sorbed at 0.2 mg P £"' (standard P requirement). The application of calcium silicate did not affect significantly P sorption maxima but decreased significantly the P bonding energies. Calcium silicate also decreased significantly the standard P requirements. As for P sorption kinetic experiment. the results showed that application of 5% calcium silicate decreased significantly the rate constant of P sorption and P sorbed maximum at given amount of added P. The results suggested that the application of calcium silicate to the Andisols made added P was more available for plant.

Effects of animal effluents on the phosphorus sorption characteristics of soils

Soil Research ◽  
1997 ◽  
Vol 35 (2) ◽  
pp. 365 ◽  
Author(s):  
I. C. R. Holford ◽  
C. Hird ◽  
R. Lawrie
Keyword(s):  
Sorption Capacity ◽  
Poultry Manure ◽  
Effluent Treatment ◽  
Total Carbon ◽  
Degree Of Saturation ◽  
Phosphorus Sorption ◽  
Soil P ◽  
P Sorption ◽  
P Leaching ◽  
Sorption Characteristics

Two groups of soils were examined to determine the effects of dairy, pig, or sewage effluent and other materials containing phosphorus (P) on their P sorption characteristics, using the Langmuir equation to estimate values of both sorption capacity and sorption strength. There were 19 soils (0-15 cm) from 6 sites in the Williams River catchment and 3 soils (0-100 cm) from Bermagui, all from coastal New South Wales. Effluent usually decreased P sorption capacities of the Williams River soils, and in 3 soils the capacities were reduced to zero. Sorption strength was reduced substantially by effluent treatment in all soils except one, which had received effluent for only 3 years. Sorption strength, but not necessarily capacity, was also lower after treatment with poultry manure or chicken litter than after treatment with superphosphate only. Where effluent did not decrease sorption capacity there was a substantial increase in total carbon and iron, both of which could increase sorption capacities. After 3 years of effluent treatment of the Bermagui soil, sorption capacities had been reduced in the top 70 cm depth, the extent of the reduction varying from 17% at 0-7 · 5 cm depth to 38% at 40-70 cm depth. Sorption strength was reduced in the top 40 cm depth only. After 12 years of effluent treatment, sorption capacities and strength had also decreased at the deeper sampling depths (to 100 cm), and the average reduction in capacity was about 40%. These results suggest that P leaching will begin well before the total sorption capacity has been saturated. There was a direct and significant correlation between the sorption strength of the untreated soil and the percentage saturation reached before leaching began. Further saturation of the sorption complex appears to be slow after this degree of saturation has been reached, and it seems that P leaching exceeds adsorption during this phase. There was also a negative correlation between sorption strength and KCl-soluble P in all soils, suggesting that soil P solubility and potential saturation are both controlled by this characteristic.

scholarly journals Phosphate sorption parameters in relation to soil properties in some major agricultural soils of India

2016 ◽  
Vol 14 (1) ◽  
pp. 1-9 ◽  
Author(s):  
I Rashmi ◽  
VRR Parama ◽  
AK Biswas
Keyword(s):  
Soil Properties ◽  
Agricultural Soils ◽  
Clay Content ◽  
Phosphate Adsorption ◽  
Phosphorus Sorption ◽  
Sorption Data ◽  
K Value ◽  
P Sorption ◽  
Indian Representative ◽  
Sorption Parameters

Phosphorus sorption characteristics of some Indian representative agricultural soils belonging to four soil orders namely Vertisol, Inceptisol, Alfisol and Ultisol were investigated for adsorption behaviour of P and sorption data were fitted to Langmuir and Freundlich equations. The Langmuir constant i.e. adsorption maxima was highest for Vertisol (716.85 ?g g-1), followed by Ultisol (633.3 ?g g-1), Alfisol (501.46 ?g g-1) and Inceptisol (522.93 ?g g-1) respectively. The Freundlich ‘k’ value for Vertisol, Inceptisol, Alfisol and Ultisol were 159.12, 59.41, 110.57 and 181.36 ?g g-1 respectively, whereas the ‘n’ values were 2.05, 1.92, 2.49 and 3.07 g ml-1 respectively. The phosphate adsorption isotherm gave good fit adopting Langmuir (r2 = 0.96 to 0.99) and Freundlich (r2= 0.95 to 0.99) for the four soils. Phosphorus sorption maxima was significantly correlated with clay (r2=0.70), Al (r2= 0.73) and Fe (r2=0.81) forms, MPBC (r2=0.67) and Freundlich constants (r2=0.82). Among the various soil properties which correlated with P sorption maxima of significance was clay content (r2=0.97) was significantly correlated. The study illustrated that P sorption isotherm in relation to soil properties can be used as a tool of P management in sustainable crop production.SAARC J. Agri., 14(1): 1-9 (2016)

scholarly journals Kinetics of phosphorus sorption in soils in the state of Paraíba¹

2011 ◽  
Vol 35 (4) ◽  
pp. 1301-1310 ◽  
Author(s):  
Hemmannuella Costa Santos ◽  
Fábio Henrique Tavares de Oliveira ◽  
Ignácio Hernan Salcedo ◽  
Adailson Pereira de Souza ◽  
Valério Damásio da Mota Silva
Keyword(s):  
Soil Properties ◽  
Clay Content ◽  
The State ◽  
Phosphorus Sorption ◽  
P Adsorption ◽  
Soil P ◽  
P Sorption ◽  
P Concentration ◽  
Elovich Equation ◽  
Kinetics Of

The soil P sorption capacity has been studied for many years, but little attention has been paid to the rate of this process, which is relevant in the planning of phosphate fertilization. The purpose of this experiment was to assess kinetics of P sorption in 12 representative soil profiles of the State of Paraíba (Brazil), select the best data fitting among four equations and relate these coefficients to the soil properties. Samples of 12 soils with wide diversity of physical, chemical and mineralogical properties were agitated in a horizontal shaker, with 10 mmo L-1 CaCl2 solution containing 6 and 60 mg L-1 P, for periods of 5, 15, 30, 45, 60, 90, 120, 420, 720, 1,020, and 1,440 min. After each shaking period, the P concentration in the equilibrium solution was measured and three equations were fitted based on the Freundlich equation and one based on the Elovich equation, to determine which soil had the highest sorption rate (kinetics) and which soil properties correlated to this rate. The kinetics of P sorption in soils with high maximum P adsorption capacity (MPAC) was fast for 30 min at the lower initial P concentration (6 mg L-1). No difference was observed between soils at the higher initial P concentration (60 mg L-1). The P adsorption kinetics were positively correlated with clay content, MPAC and the amount of Al extracted with dithionite-citrate-bicarbonate. The data fitted well to Freundlich-based equations equation, whose coefficients can be used to predict P adsorption rates in soils.

Phosphorus sorption by sandy soils from Western Australia: effect of previously sorbed P on P buffer capacity and single-point P sorption indices

Soil Research ◽  
2003 ◽  
Vol 41 (7) ◽  
pp. 1369 ◽  
Author(s):  
M. D. A. Bolland ◽  
D. G. Allen
Keyword(s):  
Retention Index ◽  
Western Australia ◽  
Buffer Capacity ◽  
Field Experiments ◽  
Single Point ◽  
Soil Test ◽  
Phosphorus Sorption ◽  
P Sorption ◽  
Soil Test P ◽  
Sorption Index

Soil samples collected from 8 field experiments in Western Australia to which 5–8 amounts of superphosphate had been applied once only 13–23 years previously were used to measure the phosphorus (P) buffer capacity of soil (PBC) and P sorption by several single-point indices. PBC was estimated from well-defined P sorption curves when several levels of P were added to soil suspensions, and was the amount of P sorbed when the concentration of P in the final solution was raised from 0.25 to 0.35 mg P/L. The single-point P sorption indices were measured by adding one amount of P (10 mg P/L) to soil suspensions (1 : 20, soil : 0.02 M KCl or 0.01 M CaCl2). Three indices were calculated from the amount of P sorbed by soil (S, mg P/kg soil) and the amount of P in solution (c, mg P/L)—(1) the phosphorus retention index (PRI, S/c [L/kg]), (2) the Freundlich retention index (FRI, S/c0.35 [dimensionless]), and (3) the phosphorus sorption index (PSI, S/log10 [c × 1000] [dimensionless])—to provide PRI K & Ca, FRI K & Ca, and PSI K & Ca values. P sorption was also measured by the P buffer index (PBI), the new single-point P sorption index recommended for national use, to provide PBICa values. To estimate the previous P sorbed by soil (native soil P is negligible for these soils, so previously sorbed P originates from fertiliser P applied in a previous year), the amount of P extracted by 0.5 M sodium bicarbonate from soil (Colwell soil test P) was added to the amount of P sorbed by soil to calculate PRI*K & Ca, FRI*K & Ca, PSI*K & Ca, and PBI*Ca values. In addition, previously sorbed P was estimated using the q coefficient of the Freundlich equation; q was added to P sorption to calculate PSI**, FRI**, PSI** and PBI** values to take account of previously sorbed P.For the 8 experiments, PBC values significantly decreased where more fertiliser P had been applied to the soils 13–23 years previously. This indicated that the capacity of the 8 soils to sorb P decreased as more P was applied in a previous year, and a single-point P sorption index would need to reflect this decrease. As the amount of P applied to soil in the field plots increased, the following trends occurred : (1) Colwell soil test P always increased; (2) PRIK & Ca, FRIK & Ca, PSIK & Ca, and PBICa consistently decreased; (3) PRI*K & Ca, FRI*K & Ca, PSI*K & Ca, and PBI*Ca mostly increased, but with some values being unaffected or decreasing; (4) PRI**, FRI**, PSI**, and PBI** values were largely unaffected by the amount of P applied in a previous year. Evidently, either adding Colwell soil test P or q to P sorption to calculate the single-point P sorption indices mostly overestimated P sorption by the sandy, low P sorbing soils used, but the overestimate was larger for Colwell soil test P than for q.

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