Effect of long-term cultivation on soil organic carbon fractions and metal distribution in humic and fulvic acid in black soil, Northeast China

Soil Research ◽  
2012 ◽  
Vol 50 (7) ◽  
pp. 562 ◽  
Author(s):  
C. Y. Sun ◽  
J. S. Liu ◽  
Y. Wang ◽  
N. Zheng ◽  
X. Q. Wu ◽  
...  
Keyword(s):  
Organic Matter ◽  
Soil Organic Matter ◽  
Organic Carbon ◽  
Soil Organic Carbon ◽  
Fulvic Acid ◽  
Humic Substances ◽  
Binding Capacity ◽  
Black Soil ◽  
Systematic Change

Cultivation affects soil organic matter and its fractions. Fulvic acid (FA) and humic acid (HA) make up an important part of soil organic matter, and their binding capacity influences heavy metal behaviour in soil. This research studied changes in soil organic components and the distribution of copper (Cu), lead (Pb), and zinc (Zn) in HA and FA affected by long-term cultivation in black soils. Uncultivated sites and their adjacent cultivated sites (18, 50, and >200 years) were selected. Alkaline sodium hydroxide/pyrophosphate extraction of humic substances and precipitation of HA by acidification were used to separate the HA and FA fractions. Concentrations of Cu, Pb, and Zn in HA and FA were determined. The content of soil organic carbon (C) had decreased by 30% after 200 years of cultivation. Cultivation led to a moderate decrease (38%) in HA and a minor decrease (7%) in FA. The CHA/CFA ratio, which is a humification parameter, decreased from 2.05 in the uncultivated soil to 1.38 in the soil cultivated for 200 years, indicating a lower degree of humification of organic matter in cultivated soils. Of the Na4P2O7 + NaOH-extracted Pb and Zn, 47–60% and 63–76%, respectively, was associated with FA, showing that FA has a high affinity for Pb and Zn. Of the Na4P2O7 + NaOH-extracted Cu, 55% was in the HA fraction. The share of Cu and Zn in the HA fraction decreased with cultivation time, but cultivation did not bring about a systematic change in Pb distribution in humic substances. The results show that cultivation can decrease the humified C content and metals bound to the HA fraction, and suggest that cultivation may potentially increase the mobility of heavy metals.

Enhanced Humification of Soil Organic Matter by Microwave Irradiation and Hyperthermal Catalysts

2014 ◽  
Vol 1073-1076 ◽  
pp. 696-699
Author(s):  
Baek Hoon Kim ◽  
Seung Kyun Son ◽  
Hee Jun Lim ◽  
Han Seung Kim
Keyword(s):  
Organic Matter ◽  
Soil Organic Matter ◽  
Organic Carbon ◽  
Carbon Content ◽  
Fulvic Acid ◽  
Organic Contaminants ◽  
Binding Capacity ◽  
Before And After ◽  
Ft Ir ◽  
Mw Irradiation

Soil organic matter (SOM) is derived from dead biomass of animals and plants, and its formation process in which the precursor materials of SOM are transformed into macro organic molecules through geo-chemical and geo-biological reactions in the subsurface environment is referred to as humification. Carbon content increases, but oxygen content decreases along with marked increased in molecular weight and degree of condensation of SOM during humification. It has been known that humus materials evolve in the order of biopolymer, fulvic acid, humic acid, and humin. Humification process takes place in a geological time scale, but it can be accelerated at extremely high temperatures, which can be achieved by microwave (MW) with hyperthermal catalysts (HTCs). Thus, MW was irradiated to the mixture of soil and HTCs to stimulate humification of SOM and to enhance its binding capacity for recalcitrant organic contaminants in this study. MW irradiation with HTCs was optimized, and the characteristic changes of SOMs before and after the irradiation were assessed to confirm humification. Soils were collected from 4 different forest regions in Seoul, Korea (Konkuk University, Yongma Mountain, Surak Mountain, and Bukhan Mountain), and they were screened by wet-sieving. Each component of SOM was isolated by acid-base extraction/selective exchange resin, which was proposed by the International Humic Substance Society. Total organic carbon (TOC) content, specific ultraviolet absorbance (SUVA), E4/E6 ratio, and Fourier transform-infrared spectroscopy (FT-IR) spectrum of SOM before and after MW irradiation were examined. Soil of Surak Mountain exhibited the highest organic carbon content, but Yongma Mountain contained the highest amount of fulvic acid. Soils of Yongma Mountain and Konkuk University were chosen due to their high fulvic acid content, which supported that these soils are relatively geologically-young soils. Powdered and granulated activated carbon (PAC and GAC), graphite, charcoal, and carbon nanotube (CNT) were selected and screened with regard to their hyperthermal activity under MW irradiation. The temperature changes by MW with HTCs were monitored at various MW irradiation intensity and time. Graphite-and CNT-soil mixtures exhibited the optimum heating capacity at 600 W, resulting in heating HTC-soil mixtures to approximately 1,000oC within 10 min. TOCs, SUVAs, E4/E6 ratios, and FT-IR spectra of SOM supported effective humification of SOM after MW irradiation with HTCs, and notable increase in binding capacity with hydrophobic organic contaminants. The results of this study are expected to provide the fundamental information for developing the performance-efficient and cost-effective treatment process for the removal of persistent organic contaminants based on MW and HTC.

scholarly journals Chemical composition of soil organic carbon changed by long-term monoculture cropping system in Chinese black soil

2018 ◽  
Vol 64 (No. 11) ◽  
pp. 557-563 ◽  
Author(s):  
Yunfa Qiao ◽  
Shujie Miao ◽  
Yingxue Li ◽  
Xin Zhong
Keyword(s):  
Chemical Composition ◽  
Organic Carbon ◽  
Soil Organic Carbon ◽  
Relative Proportion ◽  
Cropping System ◽  
Black Soil ◽  
Chemical Compositions ◽  
Crop Species ◽  
Rotation System

Monoculture is common to meet commodity grain requirements in Northeast China. The effect of long-term monoculture on chemical composition of soil organic carbon (SOC) remains unclear. This study was done to evaluate how changes in chemical compositions of SOC responded to long-term monoculture. To achieve this objective, the chemical compositions of SOC in maize-soybean rotation, continuous soybean and continuous maize were characterized with the nuclear magnetic resonance technique. Two main components, O-alkyl and aromatic C, showed a wider range of relative proportion in monoculture than rotation system across soil profiles, but no difference was observed between two monoculture systems. Pearson’s analysis showed a significant relationship between plant-C and OCH<sub>3</sub>/NCH, alkyl C or alkyl O-C-O, and the A/O-A was closely related to plant-C. The findings indicated a greater influence of monoculture on the chemical composition of SOC compared to rotation, but lower response to crop species.

Soil Organic Carbon Accumulation under Different Forms of Organo-Mineral Fertilizers and Methods of Their Application on Ukrainian Black Soil

2020 ◽  
Author(s):  
Viktoriia Hetmanenko ◽  
Ievgen Skrylnyk ◽  
Anzhela Kutova
Keyword(s):  
Organic Matter ◽  
Organic Carbon ◽  
Soil Organic Carbon ◽  
Black Soil ◽  
Carbon Accumulation ◽  
Mineral Fertilizers ◽  
Fertilizer Treatment ◽  
Soil C ◽  
Significant Difference ◽  
Humus Composition

&lt;p&gt;Soil organic carbon management is a key element in solving such urgent global-scale challenges as overcoming degradation of soils and mitigating climate change. Organic fertilizers application has a significant potential for sequestering C in soils, but their efficiency depends on decomposition characteristics. Firstly, it noted the dependence of resynthesis of humic compounds in a soil on a quality of organic inputs, secondly - a need for zonal approach to fertilizers production based on amphiphile properties of macromolecules.&lt;/p&gt;&lt;p&gt;The present study was conducted in long-term field experiment on black soil in Forrest-Steppe zone of Ukraine. The technology of production of organo-mineral fertilizers (OMFs) was based on the regulated processing of livestock waste with mineral components to stabilize it with hydrophobic bonds. OMFs in amorphous and granular form were compared in case of broadcast and band method of incorporation. The dose of OMF input was equivalent 350 C kg ha&lt;sup&gt;-1&lt;/sup&gt; and 80 N, 80 P, 80 K kg ha&lt;sup&gt;-1&lt;/sup&gt;. Organic carbon content in soil was determined by Turin method. Different organic matter fractions were isolated: humic acids (HA), fulvic acids (FA), and humin.&lt;/p&gt;&lt;p&gt;The soil C accumulation rates in OMF treatment was by 15 % higher than in manure treatment and up to 70 % higher than in chemical fertilizer treatment, respectively. The soil C accumulation was strongly influenced by the form of OMF and method of their application. The highest TOC level was found over band application of amorphous OMF, accumulating 6.2 t C ha&lt;sup&gt;&amp;#8211;1&lt;/sup&gt; yr&lt;sup&gt;&amp;#8211;1 &lt;/sup&gt;in 0-20 cm soil layer. Lower efficiency of broadcast incorporation OMFs could be explained by more intensive mineralization due to higher aeration. Taking into account the effect of OMFs on C stock an advantage of amorphous form versus granulated OMF with similar composition was proven. Black soil on control plot (without fertilization) had almost equal ratio between HA, FA and humin in humus composition. The content of humic compound increased in all treatments. Applying OMF significantly increased HA content in black soil compared to applying mineral fertilizer. OMFs application promoted the increase of the degree of condensation of organic matter. The highest HA/FA was found under the effect of broadcast incorporation OMF. That means that low molecular weight compounds were rapidly degraded while more resistant to mineralization HA were formed in soil. There was no significant difference in humus composition between amorphous and granulated OMF.&lt;/p&gt;

scholarly journals Soil organic matter fractions, chemical attributes and aggregation under forestry and agricultural systems

2018 ◽  
Vol 8 (3) ◽  
pp. 459-468
Author(s):  
Cristiane Figueira da Silva ◽  
Marcos Gervasio Pereira ◽  
Júlio César Fernandes Feitosa ◽  
Ariovaldo Machado Fonseca Júnior ◽  
João Henrique Gaia-Gomes ◽  
...  
Keyword(s):  
Organic Matter ◽  
Soil Organic Matter ◽  
Organic Carbon ◽  
Humic Substances ◽  
Secondary Forest ◽  
Agricultural Systems ◽  
Mean Weight Diameter ◽  
P Content ◽  
Chemical Attributes ◽  
Organic Matter Fractions

The aim of this work was to evaluate the influence of the conversion of forest systems to agricultural systems in the organic matter compartments, aggregation and soil chemical attributes, in the Atlantic Forest. The evaluated systems were: annual crop (ACr); perennial agriculture (PAg); pasture; and secondary forest early (SFES), medium (SFMS), and advanced stage (SFAS). Soil samples were collected at the layer of 0-5 cm depth and quantified the total organic carbon (TOC), C of humic substances, oxidizable C, granulometric fractions of soil organic matter (SOM), soil chemical attributes, soil aggregation and glomalin-related soil protein (GRSP-total and GRSP-easily extractable) in different aggregate classes. It was observed a reduction of the TOC, particulate organic carbon (POC), humic substances and oxidizable C in the PAg and ACr areas comparing to pasture and forest systems. Moreover, the pH values increased whereas P content decreased in comparison with SFAS. As for aggregation, the PAg and the ACr decreased by around 35% and 20% the mean weight diameter of aggregates, respectively, compared to the average values found in the forestry systems, and 34% and 45%, respectively in relation to pasture. In general, GRSP-total were reduced by agriculture. Thus, it appears that the agriculture which has been practiced is altering negatively the soil chemical, physical and biological attributes.

Soil organic carbon dynamics under long-term sugarcane monoculture

Soil Research ◽  
1999 ◽  
Vol 37 (1) ◽  
pp. 151 ◽  
Author(s):  
J. O. Skjemstad ◽  
J. A. Taylor ◽  
L. J. Janik ◽  
S. P. Marvanek
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Organic Matter ◽  
Organic Carbon ◽  
Soil Organic Carbon ◽  
Soil Samples ◽  
Resonance Spectroscopy ◽  
13C Nuclear Magnetic Resonance ◽  
Potential Impact ◽  
Soil Organic Carbon Dynamics

Comparisons of soil samples from virgin sites or sites recently planted to sugarcane (new) with sites that had been under cane production for many years (old) were made to investigate the potential impact of cane production on soil organic carbon (OC) levels and chemistry. The comparisons showed that very little change had occurred in total OC and in ‘light’ fraction (<1·6 Mg/m3). Increasing pyrophosphate extractability throughout the profile at some sites, as a result of cultivation, however, suggested that the organic matter generally became more ‘humified’ with long-term cane production. Evidence is presented for a redistribution of OC within profiles under cane production. Old, well-established cane sites had soils with lower OC levels in the surface horizons and higher levels in the subsoils relative to new sites. The overall chemistry of the soil organic matter, as indicated by solid state 13C nuclear magnetic resonance spectroscopy, did not change significantly at each site even though between site differences were large. Some soils contained substantial amounts of charcoal which was of pre-cane origin. In some of the coarse-textured soils, smaller amounts of charcoal produced during the burning of cane appeared to accumulate below the A1 horizons in the profiles. It also appeared likely that the redistribution of carbon in the upper horizons of some soils resulted from the movement of charcoal within the profile, probably as a result of tillage.

Maximum soil organic matter decomposition along temperature gradient in Colombian topsoils: Dry Forests

2021 ◽  
Author(s):  
Gerardo Ojeda ◽  
Hernando García ◽  
Susanne Woche ◽  
Jorg Bachmann ◽  
Georg Guggenberger ◽  
...  
Keyword(s):  
Organic Matter ◽  
Soil Organic Matter ◽  
Organic Carbon ◽  
Temperature Gradient ◽  
Soil Organic Carbon ◽  
Soil Respiration ◽  
Maximum Rate ◽  
Field Capacity ◽  
Total Carbon ◽  
Som Decomposition

&lt;p&gt;&lt;strong&gt;Contextualization&lt;/strong&gt;: In 2011, it was published a curious conundrum, which forms the basis of the present study: why, when organic matter is thermodynamically unstable, does it persist in soils, sometimes for thousands of years? The question challenges the idea that the recalcitrant or labile character of soil organic matter (SOM) is a sufficient argument to ensure SOM persistence. Temperature could play an important role in SOM decomposition, especially in tropics. Particularly, tropical dry forest (TDF) represents an important ecosystem with unique biodiversity and fertile soils in Colombia. At present, the increase in population density and consequently, in the demands of energy and arable land, have led to its degradation.&lt;/p&gt;&lt;p&gt;&amp;#160;&lt;/p&gt;&lt;p&gt;&lt;strong&gt;Knowledge gap&lt;/strong&gt;: Although the mentioned question was formulated several years ago, it has still to be answered, hence limiting the development of new soil organic carbon (SOC) models or the quantification of its ecosystem services. A key point, in terms of soil carbon storage, is to determine the maximum rate of CO&lt;sub&gt;2&lt;/sub&gt; emissions from soils (Rmax). Traditionally, it is considered that Rmax occurs at the 50% of field capacity. Unfortunately, information about the environmental conditions under which this maximum occurs is scarce.&lt;/p&gt;&lt;p&gt;&lt;strong&gt;&amp;#160;&lt;/strong&gt;&lt;/p&gt;&lt;p&gt;&lt;strong&gt;Purpose&lt;/strong&gt;: The main objectives of this study were: (a) determine the maximum rate of soil respiration or CO&lt;sub&gt;2&lt;/sub&gt; emissions from soil in TDF soils and (b) to estimate the main environmental drivers of maximum SOM decomposition along a temperature gradient (20&amp;#176;, 30&amp;#176;, 40&amp;#176;C) in incubated soils.&lt;/p&gt;&lt;p&gt;&lt;strong&gt;&amp;#160;&lt;/strong&gt;&lt;/p&gt;&lt;p&gt;&lt;strong&gt;Methodology&lt;/strong&gt;: Soils pertained to permanent plots were sampled in six different TDF of Colombia. The evolution of CO&lt;sub&gt;2&lt;/sub&gt; emissions (monitored by an infrared gas analyser), relative humidity and soil temperature were recorded in time on incubated soils samples. Temperature was maintained constant at 20&amp;#176;C, 30&amp;#176;C and 40&amp;#176;C during soil incubations under soil drying conditions. Additionally, elemental composition (Fe, Ca, O, Al, Si, K, Mg, Na) of SOM and chemical composition of soil organic carbon (SOC: aromatic-C, O-alkyl-C, Aliphatic-C, Phenolic and Ketonic-C) were determined by X-ray photoelectron spectroscopy (XPS).&lt;/p&gt;&lt;p&gt;&lt;strong&gt;&amp;#160;&lt;/strong&gt;&lt;/p&gt;&lt;p&gt;&lt;strong&gt;Results and conclusions&lt;/strong&gt;: The majority of TDF soil samples (90.7%) presented that its peak of CO&lt;sub&gt;2&lt;/sub&gt; emissions occurs at soil-water contents higher than saturation (0 MPa), at 20&amp;#176;, 30&amp;#176; and 40&amp;#176;C. Clearly, to consider that the maximum soil respiration rate could be observed at the 50% of field capacity, underestimated the real maximum value of carbon mineralization (48-68%.) Globally, increases in the Rmax values corresponded to increases in electrical conductivity, soil desorption rates, total carbon and nitrogen contents, and decreases in bulk density (BD) and aggregate stability. Taking into account the temperature gradient, increments in calcium and aromatic carbon contents corresponded to decrements in Rmax values but only at 30&amp;#176;C and 40&amp;#176;C, respectively. Some authors indicated that at high soil moisture contents, iron reduction could be release protected carbon. However, no significant relation between Fe and Rmax was observed. Consequently, physical and chemical properties related to SOM accessibility and decomposability by microbial activity, were the main drivers and controls of maximum SOM decomposition rates.&lt;/p&gt;

Modelling dynamic interactions between soil structure and soil organic matter

2020 ◽  
Author(s):  
Nicholas Jarvis ◽  
Elsa Coucheney ◽  
Claire Chenu ◽  
Anke Herrmann ◽  
Thomas Keller ◽  
...  
Keyword(s):  
Organic Matter ◽  
Carbon Sequestration ◽  
Soil Organic Matter ◽  
Organic Carbon ◽  
Physical Properties ◽  
Management Practices ◽  
Animal Manure ◽  
Soil Bulk Density ◽  
Organic Carbon Content

&lt;p&gt;The aggregated structure of soil is known to reduce rates of soil organic matter (SOM) decomposition and therefore influence the potential for long-term carbon sequestration. In turn, the storage and turnover of SOM strongly determines soil aggregation and thus the physical properties of soil. The two-way nature of these interactions has not yet been explicitly considered in soil organic matter models. In this study, we present and describe a new model of these dynamic feedbacks between SOM storage, soil pore structure and soil physical properties. We show the results of a test of the model against measurements made during 61 years in a field trial located near Uppsala (Sweden) in two treatments with different OM inputs (bare fallow, animal manure). The model was able to successfully reproduce long-term trends in soil bulk density and organic carbon content (SOC), as well as match limited data on soil pore size distribution and surface elevation. The results suggest that the model approach presented here could prove useful in analyses of the effects of soil and crop management practices and climate change on the long-term potential for soil organic carbon sequestration.&lt;/p&gt;

scholarly journals From Laboratory to Proximal Sensing Spectroscopy for Soil Organic Carbon Estimation—A Review

2020 ◽  
Vol 12 (2) ◽  
pp. 443 ◽  
Author(s):  
Theodora Angelopoulou ◽  
Athanasios Balafoutis ◽  
George Zalidis ◽  
Dionysis Bochtis
Keyword(s):  
Organic Matter ◽  
Soil Organic Matter ◽  
Organic Carbon ◽  
Soil Organic Carbon ◽  
Management Practices ◽  
Near Infrared ◽  
Wavelength Region ◽  
Soil Condition ◽  
Short Wave ◽  
Proximal Sensing

Rapid and cost-effective soil properties estimations are considered imperative for the monitoring and recording of agricultural soil condition for the implementation of site-specific management practices. Conventional laboratory measurements are costly and time-consuming, and, therefore, cannot be considered appropriate for large datasets. This article reviews laboratory and proximal sensing spectroscopy in the visible and near infrared (VNIR)–short wave infrared (SWIR) wavelength region for soil organic carbon and soil organic matter estimation as an alternative to analytical chemistry measurements. The aim of this work is to report the progress made in the last decade on data preprocessing, calibration approaches, and system configurations used for VNIR-SWIR spectroscopy of soil organic carbon and soil organic matter estimation. We present and compare the results of over fifty selective studies and discuss the factors that affect the accuracy of spectroscopic measurements for both laboratory and in situ applications.

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